In accordance with the present invention refrigerant compositions are disclosed. The compositions comprise a refrigerant mixture consisting essentially of HFC-32, HFO-1234yf, and CO.sub.2. The compositions are useful in processes to produce cooling and heating, in methods for replacing refrigerant R-32, and in refrigeration, air conditioning or heat pump systems. These inventive compositions are match cooling performance for R-32 with GWP less than 400 or less than 300.

The invention provides a grease composition for a ball joint which has a low friction coefficient under a load from normal temperatures to high temperatures, a small difference between static friction and dynamic friction, and little change in the friction coefficient even after repeated operation. TO this end, the invention provides a grease composition for a ball joint comprising: (i) a polyisoprene rubber and/or (ii) a polyisoprene rubber viscous material; a specific aliphatic amide and/or a specific aliphatic bisamide; and a specific urea compound.

In accordance with the present invention refrigerant compositions are disclosed. The compositions comprise a refrigerant mixture consisting essentially of HFC-32, HFO-1234yf, and CO.sub.2. The compositions are useful in processes to produce cooling and heating, in methods for replacing refrigerant R-32, and in refrigeration, air conditioning or heat pump systems. These inventive compositions are match cooling performance for R-32 with GWP less than 400 or less than 300.

A VM concentrate comprising: from about 60 to about 95 parts (and at least 50 wt %) of a diluent oil (e.g., having a KV100 of about 2 cSt to about 40 cSt); and from about 5 parts to about 40 parts (and at least 6.0 wt %) of a linear triblock copolymer characterized by the formula: D′-PA-D″; wherein D′ represents a block derived from diene, PA represents a block derived from monoalkenyl arene, D″ represents a block derived from diene, and the linear triblock copolymer is present in an amount effective to modify a lubricating kinematic viscosity at approximately 100° C. (KV100) of the concentrate, and wherein the KV100 of the concentrate is about 3000 cSt or less. The linear triblock copolymer may additionally or alternatively have a thickening efficiency span of at most 0.5.

The present invention relates to a process for preparing a residual base oil from a hydrocarbon feed which is derived from a Fischer-Tropsch process, the process comprises the steps of: (a) providing a hydrocarbon feed which is derived from a Fischer-Tropsch process; (b) subjecting the hydrocarbon feed of step (a) to a hydrocracking/hydroisomerisation step to obtain an at least partially isomerised product; (c) separating at least part of the at least partially isomerised product as obtained in step (b) into one or more lower boiling fractions and a hydrowax residue fraction; (d) catalytic dewaxing of the hydrowax residue fraction of step (c) to obtain a highly isomerised product; (e) separating the highly isomerised product of step (d) into one or more light fractions and a isomerised residual fraction; (f) mixing of the isomerised residual fraction of step (e) with a diluent to obtain a diluted isomerised residual fraction; (g) cooling the diluted isomerised residual fraction of step (f) to a temperature between 0° C. and −60° C.; (i) subjecting the mixture of step (g) to a centrifuging step at a temperature between 0° C. and −60° C. to isolate the wax from the diluted isomerised residual fraction; (j) separating the diluent from the diluted isomerised residual fraction to obtain a residual base oil.

The invention relates to a seal swell agent which is a substituted sulfonyldibenzene compound, and lubricating compositions containing the seal swell agent. The substituents on the benzene rings may be hydrocarbyl groups of 4 to 20 carbon atoms or alkylene groups of 1-2 carbon atoms with further functional groups.

The present invention provides a lubricating oil composition for automatic transmissions which comprises: 55 to 85 mass % of a Fischer-Tropsch synthetic oil with a kinematic viscosity at 100° C. of 2 to 4 mm2/s as a low-viscosity base oil; 1 to 10 mass % of an olefin copolymer 5 with a kinematic viscosity at 100° C. of 150 to 1,000 mm2/s as a high-viscosity base oil; and a polymethacrylate with a weight-average molecular weight of 10,000 to 50,000. This lubricating oil composition is such that the viscosity index of the composition is not 10 less than 190, the Brookfield viscosity is not more than 6,000 mPa.Math.s at low temperature (−40° C.), the kinematic viscosity at 100° C. is 6 to 7 mm2/s, and the rate of reduction of the kinematic viscosity after a KRL shear stability test (60° C., 20 hr) is kept to within not more 15 than 3%.

The invention provides a lubricating oil composition for automatic transmissions is made such that it comprises proportionately as its main constituents: 60 to 98 mass % as low viscosity base oils being base oils belonging to Groups 2 to 4 of the API (American Petroleum Institute) base oil categories wherein the kinematic viscosity at 100° C. is 2 to 5 mm.sup.2/s (Fischer-Tropsch synthetic oil comprising at least 45 to 80 mass %); 1 to 20 mass % as high-viscosity base oils being metallocene/poly-α-olefins with a kinematic viscosity at 100° C. of 100 to 600 mm.sup.2/s; and 1 to 20 mass % being a polymethacrylate with a weight-average molecular weight of 10,000 to 50,000. The viscosity index of this composition is not less than 190, the Brookfield viscosity at −40° C. is not more than 5000 mPa.Math.s, the 100° C. kinematic viscosity is 5 to 7 mm.sup.2/s, and the rate of reduction of the 100° C. kinematic viscosity after a KRL shear stability test (60° C., 20 hr) is not more than 3%.

A VM concentrate comprising: from about 60 to about 95 parts (and at least 50 wt %) of a diluent oil (e.g., having a KV100 of about 2 cSt to about 40 cSt); and from about 5 parts to about 40 parts (and at least 6.0 wt %) of a linear triblock copolymer characterized by the formula: D′-PA-D″; wherein D′ represents a block derived from diene, PA represents a block derived from monoalkenyl arene, D″ represents a block derived from diene, and the linear triblock copolymer is present in an amount effective to modify a lubricating kinematic viscosity at approximately 100° C. (KV100) of the concentrate, and wherein the KV100 of the concentrate is about 3000 cSt or less. The linear triblock copolymer may additionally or alternatively have a thickening efficiency span of at most 0.5.

The present invention relates to drilling fluid comprising one or more linear internal olefin having from 15 to 18 carbon atoms and containing less than 25% branching based on the total amount of the linear internal olefin and a hydrogenated Fischer-Tropsch derived product.