The present invention relates to compounds according to formula (Ia) or formula (Ib);

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wherein each W is independently selected from the group consisting of H, F, Cl, Br, I and (CY.sub.2).sub.mCY.sub.3; each Y is independently selected from the group consisting of F, Cl, Br and I; each Z is independently selected from the group consisting of H, OH, (CW.sub.2).sub.pCW.sub.3, CY.sub.3, OCW.sub.3, O(CW.sub.2).sub.pCW.sub.3, OCW((CY.sub.2).sub.mCY.sub.3)CWCW.sub.2, (CW.sub.2).sub.pOH, polyalkylene glycol and 15 polyolester; n is an integer from 2 to 49; m is an integer from 0 to 3; p is an integer from 0 to 9; the molecular weight average (Mw) is ≤5500; and the polydispersity index is ≤1.45; compositions comprising these compounds and methods for their production.

The present invention relates to a lubricating composition, intended for a refrigerant system comprising a gas compression circuit, comprising: at least one first polyalkylene glycol exhibiting a hydroxyl number strictly of greater than 50 mg KOH/g and a kinematic viscosity, measured at 100° C. according to the standard ASTM D445, ranging from 5 to 10 mm.sup.2/s, and at least one second polyalkylene glycol with a kinematic viscosity, measured at 100° C., ranging from 100 to 500 mm.sup.2/s, said polyalkylene glycols A and B being present in a PAG(s) A/PAG(s) B ratio by weight of between 60/40 and 99/1. It also relates to the employment of such a lubricating composition in a refrigerant system comprising a gas compression circuit, in particular for an automobile air conditioning system, in combination with a coolant based on hydrocarbon compounds, such as R134a and/or HFO-1234yf.

The invention is directed to a method for reducing low speed pre-ignition events in a spark-ignited direct injection internal combustion engine by supplying to the sump a lubricant composition which contains an oil of lubricating viscosity and a metal overbased detergent. The metal overbased detergent may be selected from sulfonate detergents, phenate detergents, and salicylate detergents, especially sulfonate detergents with a metal ratio of at least 5.

This disclosure describes blends of detergent and antiwear lubricating additives and lubricants including such additive blends effective to reduce high-temperature deposits, and in particular, high-temperature deposits in low ash compositions.

An industrial oil composition contains a mineral or a synthetic oil as a base oil, and a neutral phosphite ester derivative represented by the following formula (B) and a 2,6-di-t-butylphenol derivative represented by the following formula (C) as antioxidants. In the formula (B), R.sup.b21 to R.sup.b24 each independently represent an aliphatic hydrocarbon group of 10 to 16 carbon atoms. In the formula (C), R.sup.c1 represents a straight-chain or a branched alkyl group of 1 to 12 carbon atoms.

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A compressor including a housing, a shaft configured to be rotated relative to the housing to compress a refrigerant, a motor configured to drive the shaft, a lubrication system configured to supply lubricant to the compressor, and a bearing configured to support the shaft. The shaft includes a wear-resistant sleeve-like treatment on at least a portion of an outer surface of the shaft adjacent the bearing. The lubricant is a lubricant blend composition that includes two or more lubricants, the two or more lubricants including a first lubricant and a second lubricant. The first lubricant is present at a higher volume percentage than the second lubricant, and the first lubricant includes a higher viscosity than the second lubricant.

The present disclosure provides A lubricant composition comprises an antioxidant; and an esterified polyalkylene glycol: R.sup.1[O(R.sup.2O).sub.n(R.sup.3O).sub.m(C═O)R.sup.4].sub.p, wherein R.sup.1 is a linear alkyl having 1 to 18 carbon atoms, a branched alkyl having 4 to 18 carbon atoms or an aryl with 6 to 30 carbon atoms; R.sup.2O is an oxypropylene moiety derived from 1,2-propylene oxide; R.sup.3O is an oxybutylene moiety derived from butylene oxide, wherein R.sup.2O and R.sup.3O are in a block or a random distribution; R.sup.4 is a linear alkyl with 1 to 18 carbon atoms, a branched alkyl with 4 to 18 carbon atoms or an aryl with 6 to 18 carbon atoms; n and m are each independently integers ranging from 0 to 20 wherein n+m is greater than 0, and p is an integer from 1 to 4, wherein the antioxidant is present in an amount by weight of at least 0.5% to 20% based upon the weight of the antioxidant and the esterified polyalkylene glycol and the antioxidant is soluble in the esterified polyalkylene glycol in an amount of at least 0.5% by weight. The lubricant composition may be used as an additive to form a hydrocarbon lubricant composition.

To provide a composition for a heat cycle system, which comprises a working fluid for heat cycle which has a low global warming potential and high stability, and which can replace R410A, and a heat cycle system employing the composition. A composition for a heat cycle system, which comprises a working fluid for heat cycle containing trifluoroethylene, and a stabilizer for preventing deterioration of the working fluid for heat cycle, such as an oxidation resistance-improving agent, a heat resistance-improving agent or a metal deactivator, and a heat cycle system employing the composition for a heat cycle system.

The disclosed technology relates to a lubricant composition for automotive gears, axles and bearings, the lubricant composition containing an oil of lubricating viscosity and an oil-soluble titanium compound in place of boron compounds, as well as a method of obtaining thermal stability performance in automotive gears, axles and bearings without the boron content that is typical, by lubricating such automotive gears, axles and bearings with a lubricant composition containing an oil-soluble titanium compound and an amine-containing phosphorus rainwear agent.

The disclosed technology relates to a lubricant composition for automotive gears, axles and bearings, the lubricant composition containing an oil of lubricating viscosity and an oil-soluble titanium compound in place of boron compounds, as well as a method of obtaining thermal stability performance in automotive gears, axles and bearings without the boron content that is typical, by lubricating such automotive gears, axles and bearings with a lubricant composition containing an oil-soluble titanium compound and an amine-containing phosphorus rainwear agent.