Sulfur-free, ashless, and low phosphorus-containing lubricant compositions for use as engine oil having improved oxidation stability. The lubricant composition can include about 60.0 mass % to about 99.8 mass % of an oil base stock, at least one ashless antiwear additive, at least one ashless detergent, and at least one antioxidant, based on a total mass of the lubricant composition. The oil base stock can include at least one polyalphaolefin and at least one alkyl naphthalene. The lubricant composition can contain less than about 0.05 mass % phosphorus, less than about 0.05 mass % sulfur, and less than about 0.05 mass % ash. The lubricant composition can be made by a process that includes combining the above-mentioned components to provide a lubricant composition.

The present disclosure provides a lubricating composition that includes one or more boron-containing compounds and method of forming the same. The lubricating composition includes one or more boron-containing compounds, one or more metal-based detergents, one or more amine-based antioxidants, one or more phenol-based antioxidants, and a base oil balance. The lubricating composition includes greater than or equal to about 60 ppm to less than or equal to about 300 ppm of boron atoms that define the one or more boron-containing compounds; greater than or equal to about 1,100 ppm of metal atoms that define the one or more metal-based detergents; greater than or equal to about 0.70 wt. % to less than or equal to about 2.00 wt. % of the one or more amine-based antioxidants; and greater than or equal to about 0.30 wt. % to less than or equal to about 2.00 wt. %, of the one or more phenol-based antioxidants.

The present disclosure provides compounds of formula (I), and preparation method thereof,

##STR00001## wherein W is independently selected from the group consisting of H, F, Cl, Br and I; X is independently selected from the group consisting of H, F, Cl, Br, I, CW.sub.3 and OR on the basis that at least one X is OR; R is independently selected from the group consisting of C(O)CH.sub.2).sub.m(CF.sub.2).sub.nY and CW.sub.2C(CW.sub.2OC(O)(CH.sub.2).sub.m(CF.sub.2).sub.nY).sub.3; m is an integer from 0 to 2; 15 n is an integer from 2 to 8; Y is C(Z).sub.3; and Z is independently selected from the group consisting of H, F, Cl, Br and I. Such compounds may be utilised as lubricants, for example in heat transfer compositions.

A method of preventing or reducing the occurrence of Low Speed Pre-Ignition (LSPI) in a direct-injected, boosted, spark-ignited internal combustion engine that, in operation, generates a break mean effective pressure level of greater than about 15 bar, at an engine speed of from about 1500 to about 2500 rotations per minute (rpm), in which the crankcase of the engine is lubricated with a lubricating oil composition containing at least about 0.2 mass % of magnesium sulfated ash.

A lubricant composition is disclosed comprising an antioxidant composition and a lubricating oil. The antioxidant composition comprises a phenolic antioxidant having the following structure (I)

##STR00001##

and
a phosphite antioxidant having the following structure (II)

##STR00002##

wherein, A is a direct bond or an alkylene; X is —C(O)O—, —OC(O)—, —C(O)N(R.sub.7)—, —N(R.sub.7)C(O)—, —C(O)—, —N(R.sub.7)—, —O—, or —S—; R.sub.1 and R.sub.2 are each independently a C.sub.1-C.sub.10 alkyl, a C.sub.2-C.sub.10 alkenyl, a C.sub.2-C.sub.10 alkynyl, or a C.sub.3-C.sub.12 aryl; R.sub.3 includes a C.sub.1-C.sub.80 alkyl, a C.sub.2-C.sub.80 alkenyl, a C.sub.2-C.sub.80 alkynyl, or a C.sub.3-C.sub.12 aryl; R.sub.4, R.sub.5, and R.sub.6 are each independently hydrogen, alkyl, alkenyl, alkynyl, or aryl provided that at least one of R.sub.4, R.sub.5, and R.sub.6 is not hydrogen; R.sub.7 is H or an alkyl; and m, n, and o are each independently from 1 to 3.

The present invention relates to lubricating compositions and particularly gear oil compositions that include a specific class of substituted triazoles, where the substituted triazole includes at least one hydrocarbyl group linked to one of the nitrogen atoms in the triazole ring. Such compositions provide surprisingly good seal compatibility compared to compositions with other triazoles and/or alternative additives.

The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of at least one inhibitor. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.

Disclosed is a cutting oil composition, which is vastly superior in view of layer separation, dispersibility, viscosity, ingot-cleaning time after sawing, and wafer warpage after sawing, compared to conventional cutting oil compositions, and which includes mineral oil that is highly hydrogenated, as represented by Chemical Formulas 1 to 3, bentonite clay as a thickener, and glycerol trioleate as a dispersant. A cutting method using the cutting oil composition is also provided.

A lubricating oil composition contains a base oil and a rust inhibitor, in which the base oil has a gas chromatogram measured by gas chromatography satisfying the particular condition (), and the rust inhibitor is at least one selected from a first rust inhibitor, a second rust inhibitor, a third rust inhibitor, and a fourth rust inhibitor, and satisfies the particular condition ().

The present invention provides compounds of formula (I): wherein W is independently selected from the group consisting of H, F, Cl, Br and I; 10 X is independently selected from the group consisting of H, F, Cl, Br, I, CW.sub.3 and OR on the basis that at least one X is OR; R is independently selected from the group consisting of C(O) (CH.sub.2).sub.m(CF.sub.2).sub.nY and CW.sub.2C(CW.sub.2OC(O)(CH.sub.2)m(CF.sub.2)nY).sub.3; m is an integer from 0 to 2; 15 n is an integer from 2 to 8; Y is C(Z).sub.3; and Z is independently selected from the group consisting of H, F, Cl, Br and I. Such compounds may be utilised as lubricants, for example in heat transfer compositions.