The present disclosure provides compounds of formula (I), and preparation method thereof,

##STR00001## wherein W is independently selected from the group consisting of H, F, Cl, Br and I; X is independently selected from the group consisting of H, F, Cl, Br, I, CW.sub.3 and OR on the basis that at least one X is OR; R is independently selected from the group consisting of C(O)CH.sub.2).sub.m(CF.sub.2).sub.nY and CW.sub.2C(CW.sub.2OC(O)(CH.sub.2).sub.m(CF.sub.2).sub.nY).sub.3; m is an integer from 0 to 2; 15 n is an integer from 2 to 8; Y is C(Z).sub.3; and Z is independently selected from the group consisting of H, F, Cl, Br and I. Such compounds may be utilised as lubricants, for example in heat transfer compositions.

Provided is a lubricating oil composition for a refrigerator which uses a base oil including as the main component at least one kind of oxygen-containing compounds selected from polyoxyalkylene glycols, polyvinyl ethers, copolymers of poly(oxy)alkylene glycols or monoethers thereof and polyvinyl ethers, polyol esters, and polycarbonates. The lubricating oil composition for a refrigerator is used for a refrigerator that uses, as a refrigerant, a fluorine-containing organic compound, which is a refrigerant applicable to current car air conditioner systems or the like and has a specific polar structure, and has favorable sealing property, a low coefficient of friction factor in a sliding part, and excellent stability as well as excellent compatibility with the refrigerant.

A refrigerator oil composition containing an epoxy compound (X) having at least one of an olefin skeleton and a terpene skeleton, and a base oil (Y).

A refrigerator oil composition containing an epoxy compound (X) having at least one of an olefin skeleton and a terpene skeleton, and a base oil (Y).

The present invention, in one aspect, provides a refrigerating machine oil including a lubricating base oil and a compound represented by the following formula (A): ##STR00001##
wherein R.sup.1 and R.sup.2 each independently represent a monovalent hydrocarbon group, and R.sup.3 and R.sup.4 each independently represent a hydrogen atom or an alkyl group, the refrigerating machine oil being used with a refrigerant including an unsaturated hydrofluorocarbon.

The present invention provides a refrigerating machine oil comprising a hydrocarbon-based base oil having a viscosity index of 120 or less, and the refrigerating machine oil being used with a 1-chloro-2,3,3,3-tetrafluoropropene refrigerant.

The present invention provides compounds of formula (I): wherein W is independently selected from the group consisting of H, F, Cl, Br and I; 10 X is independently selected from the group consisting of H, F, Cl, Br, I, CW.sub.3 and OR on the basis that at least one X is OR; R is independently selected from the group consisting of C(O) (CH.sub.2).sub.m(CF.sub.2).sub.nY and CW.sub.2C(CW.sub.2OC(O)(CH.sub.2)m(CF.sub.2)nY).sub.3; m is an integer from 0 to 2; 15 n is an integer from 2 to 8; Y is C(Z).sub.3; and Z is independently selected from the group consisting of H, F, Cl, Br and I. Such compounds may be utilised as lubricants, for example in heat transfer compositions.

The present invention provides a refrigerating machine oil comprising: a base oil; a compound represented by the following formula (1): ##STR00001##
wherein R.sup.1 and R.sup.2 each independently represent a monovalent hydrocarbon group, R.sup.3 represents a divalent hydrocarbon group and R.sup.4 represents a hydrogen atom or a monovalent hydrocarbon group; and an epoxy compound.

The present invention provides stable water-in-oil emulsions suitable for use as fire-resistant aerosol multipurpose lubricants. The water-in-oil emulsion comprises a synthetic ester base oil, compatible invert emulsifier, water, and a preservative. The aerosol apparatus employs a larger than standard stem orifice to produce a non-flammable aerosol.

It is to provide a lubricating oil composition for a compression refrigerator, which is excellent in the thermal/chemical stability even when used in a compression refrigerator that uses a saturated fluorinated hydrocarbon refrigerant having a lower global warming potential and a fewer carbon atoms, by including in a base oil an organic compound having a double bond in a molecule, which is at least one kind selected from an organic compound having at least two non-conjugated double bonds in the molecule, a terpene compound having a double bond in the molecule, and C.sub.12 to C.sub.30 aliphatic unsaturated hydrocarbon having one double bond in the molecule.