Patent classifications
C10M2207/262
BORATED DETERGENTS AND THEIR LUBRICATING APPLICATIONS
Disclosed herein is an overbased alkaline earth metal hydrocarbyl-substituted salicylate detergent comprising both carbonate and borate moieties and exhibiting the following characteristics: a basicity index of at least 3.8; a ratio of soap content to mass % boron is greater than 55 mmol/kg; a soap content of at least 330 mmol/kg; a TBN, measured according to ASTM D2896, of at least 220 mg KOH/g; and a mass ratio of borate to carbonate from 0.75 to 6.0, wherein the alkaline earth metal comprises calcium and/or magnesium, and the hydrocarbyl substitution comprises 9 to 30 carbon atoms. Methods of making the boron-containing salicylate detergent, specifically to be package-stable, are also disclosed, as well as package-stable lubricant additive package concentrates and lubricating oil compositions containing same.
BORATED DETERGENTS AND THEIR LUBRICATING APPLICATIONS
Disclosed herein is an overbased alkaline earth metal hydrocarbyl-substituted salicylate detergent comprising both carbonate and borate moieties and exhibiting the following characteristics: a basicity index of at least 3.8; a ratio of soap content to mass % boron is greater than 55 mmol/kg; a soap content of at least 330 mmol/kg; a TBN, measured according to ASTM D2896, of at least 220 mg KOH/g; and a mass ratio of borate to carbonate from 0.75 to 6.0, wherein the alkaline earth metal comprises calcium and/or magnesium, and the hydrocarbyl substitution comprises 9 to 30 carbon atoms. Methods of making the boron-containing salicylate detergent, specifically to be package-stable, are also disclosed, as well as package-stable lubricant additive package concentrates and lubricating oil compositions containing same.
LUBRICATING OIL COMPOSITION FOR INTERNAL COMBUSTION ENGINE
A lubricating oil composition for an internal combustion engine includes: (A) a lubricating base oil including at least one mineral oil-based base oil and having a kinematic viscosity at 100° C. of from 2.0 mm.sup.2/s or more and 4.3 mm.sup.2/s or less, and (B) a calcium borate-containing metallic detergent in an mount of 500 mass ppm or more and less than 1500 mass ppm in terms of calcium, based on a total amount of the composition. The composition has an evaporation loss by NOACK method (250° C., 1 h) of from 10 mass % or more and 40 mass % or less, and the composition has a viscosity index of from 140 or more and 350 or less. The lubricating oil composition is provided, wherein even in the case of using a highly evaporative base oil to make the viscosity low, the friction characteristic of the lubricating oil composition can be kept low.
LUBRICATING OIL COMPOSITION FOR INTERNAL COMBUSTION ENGINE
A lubricating oil composition for an internal combustion engine includes: (A) a lubricating base oil including at least one mineral oil-based base oil and having a kinematic viscosity at 100° C. of from 2.0 mm.sup.2/s or more and 4.3 mm.sup.2/s or less, and (B) a calcium borate-containing metallic detergent in an mount of 500 mass ppm or more and less than 1500 mass ppm in terms of calcium, based on a total amount of the composition. The composition has an evaporation loss by NOACK method (250° C., 1 h) of from 10 mass % or more and 40 mass % or less, and the composition has a viscosity index of from 140 or more and 350 or less. The lubricating oil composition is provided, wherein even in the case of using a highly evaporative base oil to make the viscosity low, the friction characteristic of the lubricating oil composition can be kept low.
Low zinc lubricant composition
The disclosed technology relates to lubricants for compression ignition internal combustion engines, particularly those demonstrating at least one of improved seals performance, reduced deposit formation, and excellent durability. The present invention provides a low zinc lubricating composition comprising (a) an oil of lubricating viscosity, (b) a borated dispersant, and (c) a metal-free organo-phosphorus anti-wear additive, wherein the lubricating composition is substantially free of a metal containing sulfur coupled alkyl phenol compound. Further, the low zinc lubricating composition contains zinc in an amount less than 600 ppm by weight of the composition.
Low zinc lubricant composition
The disclosed technology relates to lubricants for compression ignition internal combustion engines, particularly those demonstrating at least one of improved seals performance, reduced deposit formation, and excellent durability. The present invention provides a low zinc lubricating composition comprising (a) an oil of lubricating viscosity, (b) a borated dispersant, and (c) a metal-free organo-phosphorus anti-wear additive, wherein the lubricating composition is substantially free of a metal containing sulfur coupled alkyl phenol compound. Further, the low zinc lubricating composition contains zinc in an amount less than 600 ppm by weight of the composition.
LUBRICATING COMPOSITION
Lubricating composition comprising (i) base oil and (ii) a metal-free phosphonate compound having the general formula P(═O)(R.sup.1)(OR.sup.2)(OR.sup.3) wherein R.sup.1, R.sup.2 and R.sup.3 are the same or different and each independently selected from a straight chain or branched, saturated or unsaturated, C.sub.4-C.sub.22 alkyl group. The lubricating composition of the present invention provides improved engine durability, improved wear and friction reduction, improved fuel economy and excellent oxidative stability.
LUBRICATING OIL COMPOSITIONS COMPRISING BIOBASED BASE OILS
- Alexander Bowman BOFFA ,
- Ian G. Elliott ,
- John Robert Miller ,
- Jennifer Elizabeth NEWELL ,
- Mark SZTENDEROWICZ ,
- Kevin CARABEL ,
- Ramoun MOURHATCH ,
- Claire CHOMMELOUX ,
- Arash BOHLOUL ,
- Mia Gill ,
- Xiaomin Helen TU ,
- Koichi KUBO ,
- Isao TANAKA ,
- Taiki HATTORI ,
- Gang Chen ,
- Richard Hogendoorn ,
- Peter Kleijwegt ,
- Jeroen VAN LEEUWEN ,
- Wilhelmus Petrus VAN HOUTEN ,
- Cornelis Hendrikus Maria BOONS ,
- Deane S. WALKER ,
- John D. PALAZZOTTO
The present invention generally relates to lubricating oil compositions comprising a biobased base oil, methods of lubricating an engine with said lubricating oil compositions. Also disclosed is the use of said lubricating oil compositions in an engine.
LUBRICATING OIL COMPOSITIONS COMPRISING BIOBASED BASE OILS
- Alexander Bowman BOFFA ,
- Ian G. Elliott ,
- John Robert Miller ,
- Jennifer Elizabeth NEWELL ,
- Mark SZTENDEROWICZ ,
- Kevin CARABEL ,
- Ramoun MOURHATCH ,
- Claire CHOMMELOUX ,
- Arash BOHLOUL ,
- Mia Gill ,
- Xiaomin Helen TU ,
- Koichi KUBO ,
- Isao TANAKA ,
- Taiki HATTORI ,
- Gang Chen ,
- Richard Hogendoorn ,
- Peter Kleijwegt ,
- Jeroen VAN LEEUWEN ,
- Wilhelmus Petrus VAN HOUTEN ,
- Cornelis Hendrikus Maria BOONS ,
- Deane S. WALKER ,
- John D. PALAZZOTTO
The present invention generally relates to lubricating oil compositions comprising a biobased base oil, methods of lubricating an engine with said lubricating oil compositions. Also disclosed is the use of said lubricating oil compositions in an engine.
Lubricating oil composition, and sliding mechanism using lubricating oil composition
Disclosed is a lubricating oil composition for low-friction sliding materials, which is used in a sliding mechanism where a DLC film containing hydrogen in an amount of from 5 atom % to 50 atom % is formed on at least one sliding surface. The lubricating oil composition contains, in the lubricant base oil therein and based on the total amount of the composition, (A) an organic zinc dithiophosphate in an amount of from 0.005% by mass to 0.12% by mass in terms of the phosphorus concentration therein, (B) an amine-based friction-reducing agent in an amount of from 0.05% by mass to 5.0% by mass, and (C) an alkaline earth metal salicylate-based detergent and/or an alkaline earth metal sulfonate-based detergent in an amount of from 0.05% by mass to 0.5% by mass in terms of the alkaline earth metal concentration therein, wherein the component (A) contains, based on the total amount of the composition, a zinc primary dialkyldithiophosphate in an amount of from 0.005% by mass to 0.05% by mass in terms of the phosphorus concentration therein.