Patent classifications
C10M2215/04
QUATERNARY AMMONIUM SULFUR-CONTAINING BINUCLEAR MOLYBDATE SALTS AS LUBRICANT ADDITIVES
The present invention relates to lubricating compositions comprising a compound of Formula I:
##STR00001##
wherein R.sub.1-R.sub.4 and R.sub.5-R.sub.8 are independently selected from the group consisting of hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from counterions Q.sub.1 and Q.sub.2 is from 8 to 76, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo.sub.2S.sub.8O.sub.2].sup.2−, [Mo.sub.2S.sub.9O].sup.2−, [Mo.sub.2S.sub.10].sup.2−, and mixtures thereof, and are present in the lubricating composition in an amount sufficient to provide about 100-15,000 ppm molybdenum.
Total base number boosters for marine diesel engine lubricating compositions
A lubricating composition includes an oil of lubricating viscosity and a low-ash additive system including a low molecular weight amine with a Total Base Number of at least 150, and an N-substituted hydrocarbyl-substituted succinimide dispersant. The low-ash additive system provides the lubricating composition with a significant boost in TBN without substantially lowering the flashpoint. The composition is particularly suited to use as a marine diesel engine lubricant.
Method for lubricating a continuously variable transmission, and a continuously variable transmission
A lubricating oil composition for a continuously variable transmission contains at a specific content: (A) a mineral oil or PAO having a sulfur content of 0.03 mass % or less and a kinematic viscosity at 100 degrees C. from 1.5 mm.sup.2/s to 3 mm.sup.2/s; (B) a mineral oil or PAO having a sulfur content of 0.03 mass % or less and a kinematic viscosity at 100 degrees C. from 5.5 mm.sup.2/s to 8 mm.sup.2/s; (C) PAO having a kinematic viscosity at 100 degrees C. from 30 mm.sup.2/s to 400 mm.sup.2/s; and (D) a polymethacrylate having a mass average molecular weight of 10000 to 40000, in which the total content of the components (C) and (D) is 19 mass % or more and the lubricating oil composition has a kinematic viscosity at 100 degrees C. from 5.5 mm.sup.2/s to 6.5 mm.sup.2/s and a kinematic viscosity at −20 degrees C. of 680 mm.sup.2/s or less.
Method for lubricating a continuously variable transmission, and a continuously variable transmission
A lubricating oil composition for a continuously variable transmission contains at a specific content: (A) a mineral oil or PAO having a sulfur content of 0.03 mass % or less and a kinematic viscosity at 100 degrees C. from 1.5 mm.sup.2/s to 3 mm.sup.2/s; (B) a mineral oil or PAO having a sulfur content of 0.03 mass % or less and a kinematic viscosity at 100 degrees C. from 5.5 mm.sup.2/s to 8 mm.sup.2/s; (C) PAO having a kinematic viscosity at 100 degrees C. from 30 mm.sup.2/s to 400 mm.sup.2/s; and (D) a polymethacrylate having a mass average molecular weight of 10000 to 40000, in which the total content of the components (C) and (D) is 19 mass % or more and the lubricating oil composition has a kinematic viscosity at 100 degrees C. from 5.5 mm.sup.2/s to 6.5 mm.sup.2/s and a kinematic viscosity at −20 degrees C. of 680 mm.sup.2/s or less.
Synergistic mixtures of ionic liquids with other ionic liquids and/or with ashless thiophosphates for antiwear and/or friction reduction applications
Anti-wear and/or friction reducing formulations that include a mixture of at least one first ionic liquid and at least one ashless antiwear compound. The ashless antiwear compound can be a second ionic liquid or an ashless thiophosphate compound. The formulation desirably provides synergistic anti-wear and/or friction reducing properties. The first IL can be a monocationic ionic liquid or a dicationic ionic liquid. The second IL is a dicationic ionic liquid. The ashless thiophosphate is desirably a thiophosphate, such as a fluorothiophosphate (FTP), an alkylphosphorofluoridothiolate, or an alkylthioperoxydithiophosphate. Antiwear and/or friction reduction formulations comprising the above mixtures diluted up to 25% by weight in a base oil.
IONIC LIQUIDS CONTAINING QUATERNARY AMMONIUM AND PHOSPHONIUM CATIONS, AND THEIR USE AS ENVIRONMENTALLY FRIENDLY LUBRICANT ADDITIVES
An ionic liquid composition having the following generic structural formula:
##STR00001##
wherein Z is N or P, and R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently selected from hydrogen atom and hydrocarbon groups having one to four carbon atoms with optional interconnection to form a cyclic group that includes Z, and wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are all hydrocarbon groups when Z is P, and X.sup.− is a phosphorus-containing or carboxylate anion, particularly an organophosphate, organophosphonate, or organophosphinate anion, or a thio-substituted analog thereof containing hydrocarbon groups with at least three carbon atoms. Also described are lubricant compositions comprising the above ionic liquid and a base lubricant, wherein the ionic liquid is dissolved in the base lubricant. Further described are methods for applying the ionic liquid or lubricant composition onto a mechanical device for which lubrication is beneficial, with resulting improvement in friction reduction, wear rate, and/or corrosion inhibition.
CONVEYOR LUBRICANTS INCLUDING EMULSION OF A LIPOPHILIC COMPOUND AND AN EMULSIFIER AND/OR AN ANIONIC SURFACTANT AND METHODS EMPLOYING THEM
The present invention relates to conveyor lubricant compositions including an emulsion of a lipophilic compound and also including an emulsifier and/or an anionic surfactant. The present invention also relates to methods employing such lubricant compositions. In an embodiment, the method includes applying the present lubricant composition to a conveyor with a non-energized nozzle.
QUATERNARY AMMONIUM COMPOUNDS AND THEIR USE AS FUEL OR LUBRICANT ADDITIVES
A quaternary ammonium salt of formula wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is independently selected from an optionally substituted alkyl, alkenyl or aryl group having less than 8 carbon atoms and R.sup.5 is hydrogen or an optionally substituted hydrocarbyl group.
##STR00001##
Corrosion-Inhibiting Compositions
The invention relates to a composition comprising a) at least one N-methyl-N-acylglucamine of formula (I), wherein R.sup.1 represents a linear or branched, saturated or unsaturated hydrocarbon chain with 7 to 21 carbon atoms, one or more organic acids of formula (II) and/or the salts thereof, R.sup.2—COOM, wherein R.sup.2 represents a linear or branched alkyl group or a linear or branched mono- or poly-unsaturated alkenyl group with 5 to 29 carbon atoms, and M represents hydrogen or one or more cations, wherein the cations are present in charge-equalizing amounts, and c) one or more alkanolamines of formula (III), wherein NR.sup.1R.sup.2R.sup.3R.sup.1, R.sup.2 and R.sup.3 represent hydrogen, a linear or branched alkyl group with 1 to 4 carbon atoms, a cycloalkyl group with 5 to 7 carbon atoms, a linear or branched hydroxyalkyl group with 2 to 5 carbon atoms and 1 or 2 hydroxy groups or a hydroxyether group with 2 to 6 carbon atoms, with the provision that at least one of the groups is a hydroxyalkyl group or a hydroxyether group.
##STR00001##
Lubricant additive composition, lubricating composition containing same and engine oil composition consisting of lubricating composition
A lubricating composition including: a base oil, a lubricant additive composition including, as a component (A), an organic molybdenum compound of the formula (1) described in the specification, and as a component (B), an amine compound of the formula (2) described in the specification, and a specific metal-based cleaner, wherein a content of the component (B) is 2.9 to 18.6 parts by mass relative to 100 parts by mass of molybdenum atoms of the component (A), and a content of the metal-based cleaner is 0.1% to 10% by mass relative to a total amount of the lubricating composition, wherein the lubricating composition does not include tetraalkyl thiuram disulphide, and wherein the component (A) in terms of the amount of molybdenum atoms is 400 to 1200 ppm by mass relative to a total amount of the lubricating composition.