Patent classifications
C10N2040/255
Lubricant additive composition, lubricating composition containing same and engine oil composition consisting of lubricating composition
A lubricating composition including: a base oil, a lubricant additive composition including, as a component (A), an organic molybdenum compound of the formula (1) described in the specification, and as a component (B), an amine compound of the formula (2) described in the specification, and a specific metal-based cleaner, wherein a content of the component (B) is 2.9 to 18.6 parts by mass relative to 100 parts by mass of molybdenum atoms of the component (A), and a content of the metal-based cleaner is 0.1% to 10% by mass relative to a total amount of the lubricating composition, wherein the lubricating composition does not include tetraalkyl thiuram disulphide, and wherein the component (A) in terms of the amount of molybdenum atoms is 400 to 1200 ppm by mass relative to a total amount of the lubricating composition.
Magnetic resin compound, method for preparing the same, and use thereof
Disclosed is a magnetic dendrimer compound and a method for preparing the magnetic dendrimer compound, the molecular formula of which is shown in formula (I): Γ(CH.sub.2).sub.3N.sub.(2.sup.n+1.sub.−1)R.sup.1.sub.(2.sup.n+2.sub.−2)R.sup.2.sub.(2.sup.n+1.sub.)(I). In this formula, Γ indicates magnetic particles coated with SiO.sub.2 on a surface thereof, the magnetic particles having been modified by a silane coupling agent; (CH.sub.2).sub.3N.sub.(2.sup.n+1.sub.−1)R.sup.1.sub.(2.sup.n+2.sub.−2) is a dendritic group, and R.sup.2.sub.(2.sup.n+1.sub.) is a lipophilic group, with 0≤n≤100. Further disclosed is a lubricant comprising the magnetic dendrimer compound.
LUBRICATING COMPOSITION CONTAINING AN OXYALKYLATED HYDROCARBYL PHENOL
The disclosed technology provides lubricating composition comprising: an oil of lubricating viscosity, a p-dodecyl-phenol-free detergent and an oxyalkylated hydrocarbyl phenol, wherein the oxyalkylated hydrocarbyl phenol is substituted with at least one aliphatic hydrocarbyl group of 1 to 250 carbon atoms (or 20 to 220, or 30 to 150 carbon atoms), and wherein the oxyalkylated hydrocarbyl phenol is substantially free of aromatic hydrocarbyl groups. The disclosed technology further relates to a method of lubricating a mechanical device (such as an internal combustion engine) with the lubricating composition. The disclosed technology further relates to the use of the of the lubricating composition in a passenger car internal combustion engine to improve control of at least one of the following (i) fuel economy, (ii) corrosion, (iii) cleanliness, and (iv) bore wear.
Lubricant Compositions For Reducing Timing Chain Stretch
A method for reducing timing chain stretch in an engine comprising a step of lubricating said timing chain with a lubricating oil composition that includes a major amount of a base oil; and a minor amount of an additive package including (a) at least one overbased calcium detergent, (b) at least one borated dispersant, (c) a metal dialkyl dithiophosphate, and (d) at least one molybdenum compound. The lubricating oil composition has a TBN value of at least 7.5 mg KOH/g of the lubricating oil composition, at least 80 ppm of molybdenum, based on the total weight of the lubricating oil composition, a weight ratio of total calcium in the lubricating oil composition to total molybdenum in the lubricating oil composition of less than 8.4; and a weight ratio of nitrogen from the dispersant in the lubricating composition to total boron in the lubricating oil composition of from 2.6 to 3.0.
Lubricants for Use in Boosted Engines
A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition includes greater than 50 wt. % of a base oil of lubricating viscosity, calcium, nitrogen, molybdenum and boron. The weight ratio of Ca:N (ppm/ppm) in the lubricating oil composition is greater than 1.3 to less than 3.0, the weight ratio of Ca:Mo (ppm/ppm) in the lubricating oil composition is greater than 6.7 to less than 56.3, and the weight ratio of Ca:B (ppm/ppm) in the lubricating oil composition is greater than 5.0 to less than 9.8. The lubricating oil composition does not contain added magnesium from a magnesium-containing detergent. The lubricating oil composition is resistant to deposit formation in the boosted internal combustion engine, as shown by its ability to ensure a TCO Temperature Increase of less than 9.0% as measured using the 2015 version of the General Motors dexos1® Turbocharger Coking Test.
Lubricating oil additives
A lubricating oil composition comprising at least 50 percent by mass, based on the mass of the composition of an oil of lubricating viscosity and 0.01 to 25 percent by mass, based on the mass of the composition of a polymer comprising units (a) and one or both units (b) and (c):
—N(COR.sup.1)(CH.sub.2).sub.x— (a)
—NH(CH.sub.2).sub.y— (b)
—N(CH.sub.2CH.sub.2-k(CH.sub.3).sub.kCOOR.sup.2)(CH.sub.2).sub.z (c) where the total number (n) of units (a), (b) and (c) is an integer between 4 and 500; wherein x, y and z are independently 2 or 3; wherein k is zero or 1. The polymer shows good solubility in the lubricating oil and provides friction modification. A method of synthesising a polymer is also disclosed.
Oil Compositions
An oil composition comprises at least 50 percent by mass, based on the mass of the composition, of an oil and 0.01 to 25 percent by mass, based on the mass of the composition, of a polymer comprising at least one poly(lactone) segment. The at least one poly(lactone) segment is derived from a lactone substituted by one or two hydrocarbyl groups, or substituted hydrocarbyl groups, at least one such group having at least 4 carbon atoms. The oil compositions are suitable for use in the lubrication of the crankcase of internal combustion engines.
Lubricating oil composition
The present invention relates to a lubricating oil composition containing a base oil (A), a molybdenum dithiocarbamate (B), an ester-based ashless friction modifier (C), and a metal salicylate (D), wherein the content of a molybdenum atom derived from the molybdenum dithiocarbamate (B) is 650 ppm by mass or more on the basis of the whole amount of the lubricating oil composition; a content ratio [C/B.sub.Mo] of the ester-based ashless friction modifier (C) to a molybdenum atom derived from the molybdenum dithiocarbamate (B) is 5.0 to 10 in terms of a mass ratio; the content of a salicylate soap group derived from the metal salicylate (D) is 0.50% by mass or more on the basis of the whole amount of the lubricating oil composition; and a kinematic viscosity at 100° C. is 4.0 mm.sup.2/s or more and less than 9.3 mm.sup.2/s, and a high-temperature high-shear viscosity at 150° C. is 1.7 mPa.Math.s or more and less than 2.9 mPa.Math.s. In accordance with the present invention, a viscosity-reduced lubricating oil composition in which nonetheless a molybdenum dithiocarbamate and an ashless friction modifier are jointly used, not only friction can be reduced early after commencement of lubrication, but also such a state can be maintained, is provided.
LUBRICANT OIL COMPOSITION FOR INTERNAL COMBUSTION ENGINES AND METHOD FOR PRODUCING SAME, AND METHOD FOR PREVENTING PRE-IGNITION
A lubricating oil composition for internal combustion engines containing a base oil (A), a metal-based detergent (B) containing a calcium-based detergent (B1), a zinc dialkyldithiophosphate (C), and a molybdenum-containing compound (D), wherein a calcium atom-equivalent content of the calcium-based detergent (B1) is more than 100 ppm by mass and 600 ppm by mass or less, based on a total amount of the composition, a magnesium atom-equivalent content of a magnesium-based detergent (B2) is less than 200 ppm by mass, based on the total amount of the composition, a sodium atom-equivalent content of a sodium-based detergent (B3) is less than 200 ppm by mass, based on the total amount of the composition, a content ratio of phosphorus derived from the zinc dialkyldithiophosphate (C) to calcium derived from the calcium-based detergent (B1) [P/Ca] is 0.25 or more by mass, and a sulfated ash content is 0.7% by mass or less; and a method for producing the composition.
Lubricating composition for and method of lubricating an internal combustion engine
The invention provides a lubricating composition comprising a low viscosity base oil and a synergistic mixture of a functionalized ethylene-α-olefin copolymer, a poly(meth)acrylate polymer, and a metal-free anti-wear agent. The invention also provides a method of lubricating an internal combustion engine using such a lubricating composition.