Detergent compositions are disclosed which provide superior cleaning and removal of proteinaceous and starchy soils. Applicants have discovered a surfactant package which acts to enhance and improve the performance of enzymes such as proteases and/or amylases. Compositions for pot and pan warewash detergents and soaks are disclosed, as well as their use in manual or dish machine cleaning.

Multi-surfactant systems where two or more surfactant molecules are coupled to control the spatial distribution of polar groups of the combined surfactant molecules are disclosed. The system can be implemented by an aqueous medium including an associate charge constant surfactant and charge variable surfactant. The charge variable surfactant has at least one neutral end group at one pH value of the medium and at least one either an anionic polar group or a cationic polar group at a different pH value of the medium. The charge constant surfactant has at least one, and preferably two or more groups that does not change charge at the one or different pH values of the aqueous medium. The multi-surfactant system can be coupled or connected to the surface of a substrate where the arrangement of the two or more coupled surfactant molecules control the polarity of the substrate surface.

Multi-surfactant systems where two or more surfactant molecules are coupled to control the spatial distribution of polar groups of the combined surfactant molecules are disclosed. The system can be implemented by an aqueous medium including an associate charge constant surfactant and charge variable surfactant. The charge variable surfactant has at least one neutral end group at one pH value of the medium and at least one either an anionic polar group or a cationic polar group at a different pH value of the medium. The charge constant surfactant has at least one, and preferably two or more groups that does not change charge at the one or different pH values of the aqueous medium. The multi-surfactant system can be coupled or connected to the surface of a substrate where the arrangement of the two or more coupled surfactant molecules control the polarity of the substrate surface.

A flowable washing agent preparation containing, based on its total weight, a) 2 to 7 wt. % quaternized ethoxysulfated hexamethylenediamine; b) 2 to 7 wt. % polyalkoxylated polyalkyleneimine obtainable by reacting polyalkyleneimines with alkylene oxides; c) 5 to 15 wt. % alkyl ether sulfate; and d) less than 20 wt. % water, wherein the weight ratio of quaternized ethoxysulfated hexamethylenediamine to polyalkoxylated polyalkyleneimine is 2:1 to 1:2, and a textile washing method using these washing agent preparations.

A flowable washing agent preparation containing, based on its total weight, a) 2 to 7 wt. % quaternized ethoxysulfated hexamethylenediamine; b) 2 to 7 wt. % polyalkoxylated polyalkyleneimine obtainable by reacting polyalkyleneimines with alkylene oxides; c) 5 to 15 wt. % alkyl ether sulfate; and d) less than 20 wt. % water, wherein the weight ratio of quaternized ethoxysulfated hexamethylenediamine to polyalkoxylated polyalkyleneimine is 2:1 to 1:2, and a textile washing method using these washing agent preparations.