The invention belongs to the technical field of agricultural chemicals, and particularly relates to an N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compound or a salt thereof, a preparation method, a herbicidal composition and a use thereof. The compound is as shown in the following Formula I:

##STR00001## wherein X represents O, S, SO, SO.sub.2 or NR.sub.1; Y represents halogen, cyano, cyanoalkyl, carboxyl, nitro, etc.; or —X—Y represents unsubstituted or substituted five- or six-membered heterocyclyl or heteroaryl; Z represents hydrogen, halogen, cyano, OR.sub.4, -alkyl-OR.sub.4, —O-alkyl-N(R.sub.5).sub.2, etc., M represents hydrogen, OR.sub.6, SR.sub.6, COR.sub.6, COOR.sub.6, CON(R.sub.7).sub.2, etc. The compound has advantages of a low dosage for use, excellent herbicidal activity, and higher crop safety, especially good selectivity for key crops such as rice.

The invention belongs to the technical field of agricultural chemicals, and particularly relates to an N-(1,3,4-oxadiazol-2-yl)arylcarboxamide compound or a salt thereof, a preparation method, a herbicidal composition and a use thereof. The compound is as shown in the following Formula I:

##STR00001## wherein X represents O, S, SO, SO.sub.2 or NR.sub.1; Y represents halogen, cyano, cyanoalkyl, carboxyl, nitro, etc.; or —X—Y represents unsubstituted or substituted five- or six-membered heterocyclyl or heteroaryl; Z represents hydrogen, halogen, cyano, OR.sub.4, -alkyl-OR.sub.4, —O-alkyl-N(R.sub.5).sub.2, etc., M represents hydrogen, OR.sub.6, SR.sub.6, COR.sub.6, COOR.sub.6, CON(R.sub.7).sub.2, etc. The compound has advantages of a low dosage for use, excellent herbicidal activity, and higher crop safety, especially good selectivity for key crops such as rice.

The present invention can provide a method exerting an excellent control effect in the control of glyphosate-resistant weeds. The method includes the step of applying to 200 g per 10000 m.sup.2 of trifludimoxazin to the glyphosate-resistant weed or a habitat of the glyphosate-resistant weed.

The present invention can provide a method exerting an excellent control effect in the control of glyphosate-resistant weeds. The method includes the step of applying to 200 g per 10000 m.sup.2 of trifludimoxazin to the glyphosate-resistant weed or a habitat of the glyphosate-resistant weed.

The present invention can provide a method exerting an excellent control effect in the control of glyphosate-resistant weeds. The method includes the step of applying to 200 g per 10000 m.sup.2 of trifludimoxazin to the glyphosate-resistant weed or a habitat of the glyphosate-resistant weed.

Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) an acetolactate synthase (ALS) inhibitor or an agriculturally acceptable salt or ester thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) an ALS inhibitor or an agriculturally acceptable salt or ester thereof.

Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) an acetolactate synthase (ALS) inhibitor or an agriculturally acceptable salt or ester thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) an ALS inhibitor or an agriculturally acceptable salt or ester thereof.

Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) an acetolactate synthase (ALS) inhibitor or an agriculturally acceptable salt or ester thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) an ALS inhibitor or an agriculturally acceptable salt or ester thereof.

The object of the present invention is to find out a component which improves effects of agriculturally active ingredients, which is effective to contribute to reduction of the environmental load even in a small amount, in addition to bringing benefits to the health and/or growth of useful plants, by maximizing the effects of nicosulfuron, reducing phytotoxicity which is an undesired effect on the useful plants, etc.

When nicosulfuron and isoxadifen-ethyl are used in combination, by adding a specific surfactant, benefits can be brought to the health and/or growth of useful plants even if the addition amount is remarkably smaller than the amount of the conventional adjuvant used.

The object of the present invention is to find out a component which improves effects of agriculturally active ingredients, which is effective to contribute to reduction of the environmental load even in a small amount, in addition to bringing benefits to the health and/or growth of useful plants, by maximizing the effects of nicosulfuron, reducing phytotoxicity which is an undesired effect on the useful plants, etc.

When nicosulfuron and isoxadifen-ethyl are used in combination, by adding a specific surfactant, benefits can be brought to the health and/or growth of useful plants even if the addition amount is remarkably smaller than the amount of the conventional adjuvant used.