The present disclosure relates to substituted thiophene carboxamides derivatives of formula (I) and (II), their use for controlling phytopathogenic microorganisms and compositions comprising thereof.

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The present disclosure relates to substituted thiophene carboxamides derivatives of formula (I) and (II), their use for controlling phytopathogenic microorganisms and compositions comprising thereof.

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The present invention provides a thiophene carboxamide compound of the following General Formula (I), which is a novel fluorine-substituted biphenyl carboxamide-based compound, and provides a useful compound, as an agricultural and horticultural plant disease control agent, exhibiting an excellent control effect at a low dose. ##STR00001## wherein, R, R1, R2, R3, Xm, and Y are each as defined in the specification.

The present invention provides a thiophene carboxamide compound of the following General Formula (I), which is a novel fluorine-substituted biphenyl carboxamide-based compound, and provides a useful compound, as an agricultural and horticultural plant disease control agent, exhibiting an excellent control effect at a low dose. ##STR00001## wherein, R, R1, R2, R3, Xm, and Y are each as defined in the specification.

It is an object of the present invention to provide an agricultural and horticultural fungicide composition that exhibits an excellent control effect on plant diseases even in a small dose and causes no fear of phytotoxicity to useful plants. The agricultural and horticultural fungicide composition of the present invention comprises at least one compound A selected from the group consisting of a compound of formula (1) {wherein each X independently is a halogeno group or a C1-6 alkyl group; n is the number of X and is any integer of 0 to 5; X′ is a halogeno group; R.sup.1, R.sup.2 and R.sup.3 each independently are a C1-6 alkyl group, a C1-6 alkoxy group or a hydroxyl group; and A.sup.1 and A.sup.2 each independently are a nitrogen atom or a carbon atom}, and the like, and at least one compound B selected from the group consisting of silthiofam, an antibiotic, propineb and chinomethionat. ##STR00001##

It is an object of the present invention to provide an agricultural and horticultural fungicide composition that exhibits an excellent control effect on plant diseases even in a small dose and causes no fear of phytotoxicity to useful plants. The agricultural and horticultural fungicide composition of the present invention comprises at least one compound A selected from the group consisting of a compound of formula (1) {wherein each X independently is a halogeno group or a C1-6 alkyl group; n is the number of X and is any integer of 0 to 5; X′ is a halogeno group; R.sup.1, R.sup.2 and R.sup.3 each independently are a C1-6 alkyl group, a C1-6 alkoxy group or a hydroxyl group; and A.sup.1 and A.sup.2 each independently are a nitrogen atom or a carbon atom}, and the like, and at least one compound B selected from the group consisting of silthiofam, an antibiotic, propineb and chinomethionat. ##STR00001##

The present invention relates to a herbicidal combination which comprises: a) a herbicide A which is 2-chloro-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1-(2H)-pyrimidinyl]-4-fluoro-N-[[methyl-(1-methylethyl)-amino]sulfonyl]benzamide, b) a herbicide B which is glufosinate or one of its salts, and c) at least one herbicide C different from herbicides A and B which is selected from C.1) herbicides of the group of acetolactate synthase inhibitors which are selected from the group of triazolopyrimidine herbicides, sulfonylamino-carbonyl-triazolinone herbicides and pyrimidinyl(thio) benzoate herbicides, C.2) herbicides of the group of protoporphyrinogen oxidase inhibitors, C.3) herbicides of the group of synthetic auxins, C.4) herbicides of the group of microtubule inhibitors, C.5) herbicides of the group of acetyl-CoA carboxylase inhibitors, C.6) herbicides of the group of photosystem II inhibitors, C.7) herbicides of the group of pigment synthesis inhibitors, and C.8) herbicides of the group of VLCFA inhibitors which are selected from the group of oxyacetamide herbicides and chloroacetamide herbicides.

The present invention relates to a herbicidal combination which comprises: a) a herbicide A which is 2-chloro-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1-(2H)-pyrimidinyl]-4-fluoro-N-[[methyl-(1-methylethyl)-amino]sulfonyl]benzamide, b) a herbicide B which is glufosinate or one of its salts, and c) at least one herbicide C different from herbicides A and B which is selected from C.1) herbicides of the group of acetolactate synthase inhibitors which are selected from the group of triazolopyrimidine herbicides, sulfonylamino-carbonyl-triazolinone herbicides and pyrimidinyl(thio) benzoate herbicides, C.2) herbicides of the group of protoporphyrinogen oxidase inhibitors, C.3) herbicides of the group of synthetic auxins, C.4) herbicides of the group of microtubule inhibitors, C.5) herbicides of the group of acetyl-CoA carboxylase inhibitors, C.6) herbicides of the group of photosystem II inhibitors, C.7) herbicides of the group of pigment synthesis inhibitors, and C.8) herbicides of the group of VLCFA inhibitors which are selected from the group of oxyacetamide herbicides and chloroacetamide herbicides.

The present invention relates to a herbicidal combination which comprises: a) a herbicide A which is 2-chloro-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1-(2H)-pyrimidinyl]-4-fluoro-N-[[methyl-(1-methylethyl)-amino]sulfonyl]benzamide, b) a herbicide B which is glufosinate or one of its salts, and c) at least one herbicide C different from herbicides A and B which is selected from C.1) herbicides of the group of acetolactate synthase inhibitors which are selected from the group of triazolopyrimidine herbicides, sulfonylamino-carbonyl-triazolinone herbicides and pyrimidinyl(thio) benzoate herbicides, C.2) herbicides of the group of protoporphyrinogen oxidase inhibitors, C.3) herbicides of the group of synthetic auxins, C.4) herbicides of the group of microtubule inhibitors, C.5) herbicides of the group of acetyl-CoA carboxylase inhibitors, C.6) herbicides of the group of photosystem II inhibitors, C.7) herbicides of the group of pigment synthesis inhibitors, and C.8) herbicides of the group of VLCFA inhibitors which are selected from the group of oxyacetamide herbicides and chloroacetamide herbicides.

Granular compositions comprising at least one herbicide that inhibits microtubule assembly, at least one herbicide that inhibits cell wall synthesis, and a surfactant, and methods for making and using such compositions, are generally described.