Compositions and methods for increasing the efficacy of pesticidal compositions are described herein, including synergistic pesticidal complex compositions and methods for delivery of pesticidal active ingredients. Some pesticidal compositions and methods as described are directed to compositions and methods for increasing the efficacy of fungicides. Some pesticidal compositions and methods as described are directed to compositions and methods for increasing the efficacy of nematicides. Some pesticidal compositions and methods as described are directed to compositions and methods for increasing the efficacy of insecticides. Methods for enhancing the activity pesticidal active ingredients in pesticidal complex compositions in use are also described.

##STR00001##

Compositions and methods for increasing the efficacy of pesticidal compositions are described herein, including synergistic pesticidal complex compositions and methods for delivery of pesticidal active ingredients. Some pesticidal compositions and methods as described are directed to compositions and methods for increasing the efficacy of fungicides. Some pesticidal compositions and methods as described are directed to compositions and methods for increasing the efficacy of nematicides. Some pesticidal compositions and methods as described are directed to compositions and methods for increasing the efficacy of insecticides. Methods for enhancing the activity pesticidal active ingredients in pesticidal complex compositions in use are also described.

##STR00001##

Provided herein is a liquid pesticidal composition, comprising: (a) 3 to 10 mass% of a pesticidal active ingredient having a water solubility at 25° C. of 15 mass ppm or less and a melting point of 10° C. or more; (b) 3.6 to 60 mass% of a first solvent that is ε-caprolactone; (c) 19.5 to 85 mass% of a second solvent having a water solubility at 25° C. of 1 mass% or less; and (d) 1 to 30 mass% of a surfactant, wherein a total content of the pesticidal active ingredient, the first solvent, the second solvent, and the surfactant is 60 mass% or more, a content of the first solvent relative to a content of the pesticidal active ingredient is from 1.2 to 15.0 times by mass, and a content of the second solvent relative to the content of the pesticidal active ingredient is from 6.5 to 25.0 times by mass.

Provided herein is a liquid pesticidal composition, comprising: (a) 3 to 10 mass% of a pesticidal active ingredient having a water solubility at 25° C. of 15 mass ppm or less and a melting point of 10° C. or more; (b) 3.6 to 60 mass% of a first solvent that is ε-caprolactone; (c) 19.5 to 85 mass% of a second solvent having a water solubility at 25° C. of 1 mass% or less; and (d) 1 to 30 mass% of a surfactant, wherein a total content of the pesticidal active ingredient, the first solvent, the second solvent, and the surfactant is 60 mass% or more, a content of the first solvent relative to a content of the pesticidal active ingredient is from 1.2 to 15.0 times by mass, and a content of the second solvent relative to the content of the pesticidal active ingredient is from 6.5 to 25.0 times by mass.

This disclosure relates to macrocyclic picolinamides of Formula I and their use as fungicides.

##STR00001##

This disclosure relates to macrocyclic picolinamides of Formula I and their use as fungicides.

##STR00001##

Compositions and methods for increasing the efficacy of pesticidal compositions are described herein, including synergistic pesticidal compositions comprising: benzovindiflupyr, bixafen, boscalid, cyproconazole, fenpicoxamid, fenpyrazimine, florylpicoxamid, flutriafol, fluxapyroxad, isopyrazam, isotianil, kresoxim-methyl, metrafenone, oxathiapiprolin, penflufen, penthiopyrad, picoxystrobin, prothioconazole, pydiflumetofen, revysol, sedaxane, trifloxystrobin, pyraclostrobin, azoxystrobin, chlorothalonil, cyprodinil, metalaxyl, epoxiconazole, propiconazole, difenoconazole, fludioxonil, mancozeb, tebuconazole, valifenalate, in combination with a C4-C10 saturated or unsaturated aliphatic acid and methods for delivery of pesticidal active ingredients. Some pesticidal compositions and methods as described are directed to compositions and methods for increasing the efficacy of fungicides. Some pesticidal compositions and methods as described are directed to compositions and methods for increasing the efficacy of nematicides. Some pesticidal compositions and methods as described are directed to compositions and methods for increasing the efficacy of insecticides. Methods for enhancing the activity pesticidal active ingredients in pesticidal compositions in use are also described.

Compositions and methods for increasing the efficacy of pesticidal compositions are described herein, including synergistic pesticidal compositions comprising: benzovindiflupyr, bixafen, boscalid, cyproconazole, fenpicoxamid, fenpyrazimine, florylpicoxamid, flutriafol, fluxapyroxad, isopyrazam, isotianil, kresoxim-methyl, metrafenone, oxathiapiprolin, penflufen, penthiopyrad, picoxystrobin, prothioconazole, pydiflumetofen, revysol, sedaxane, trifloxystrobin, pyraclostrobin, azoxystrobin, chlorothalonil, cyprodinil, metalaxyl, epoxiconazole, propiconazole, difenoconazole, fludioxonil, mancozeb, tebuconazole, valifenalate, in combination with a C4-C10 saturated or unsaturated aliphatic acid and methods for delivery of pesticidal active ingredients. Some pesticidal compositions and methods as described are directed to compositions and methods for increasing the efficacy of fungicides. Some pesticidal compositions and methods as described are directed to compositions and methods for increasing the efficacy of nematicides. Some pesticidal compositions and methods as described are directed to compositions and methods for increasing the efficacy of insecticides. Methods for enhancing the activity pesticidal active ingredients in pesticidal compositions in use are also described.

The invention provides a composition and smart packaging methods for extending the shelf life of the agricultural produces. The composition comprising active ingredients, which act as a signal molecule to activate a defense mechanism with a flower, greens, fruit, or vegetable. The product is designed in the desired form (like sachet, Spray, crate, covering paper, etc.), which includes the encapsulated powder of the active ingredient which is released in a sustained manner near the farm/agricultural produce. When the volatile active ingredient is released it slows down the ethylene biosynthesis pathway and restricts microbial growth of fresh produce without any expensive technologies (refrigeration) and harmful chemicals (toxic). It can be adopted to any stage of the fruits and vegetable supply chain.

The invention provides a composition and smart packaging methods for extending the shelf life of the agricultural produces. The composition comprising active ingredients, which act as a signal molecule to activate a defense mechanism with a flower, greens, fruit, or vegetable. The product is designed in the desired form (like sachet, Spray, crate, covering paper, etc.), which includes the encapsulated powder of the active ingredient which is released in a sustained manner near the farm/agricultural produce. When the volatile active ingredient is released it slows down the ethylene biosynthesis pathway and restricts microbial growth of fresh produce without any expensive technologies (refrigeration) and harmful chemicals (toxic). It can be adopted to any stage of the fruits and vegetable supply chain.