The present invention relates to a method for modifying a textile yarn or fabric by immobilising a cyclodextrin derivative on said yarn or fabric, said process comprising a step (a) of contacting said textile yarn or fabric with said cyclodextrin derivative and with a bridging agent such as 1,2,3,4-butanetetracarboxylic acid, optionally in the presence of a catalyst such as cyanamide,

to obtain a textile yarn or fabric on which the cyclodextrin derivative of formula (I) is immobilised.

A solid particulate reactive sorbent for decontaminating toxic chemical and biological agents and its method of making. The reactive sorbent comprising a plurality of aggregates formed from linked hydrophilic nanoparticles and individual nanoparticles that bind at least one detoxifier, such that the sorbent absorbs the agents, allowing the detoxifier to oxidize and decontaminate the agents for removal. More preferably, the hydrophilic nanoparticles comprise fumed silica and the detoxifier comprises hydrogen peroxide.

The present invention relates to single thread composite fibers comprising at least one binder and at least one active catalyst for the capture and degradation of chemical threats such as chemical warfare agents (CWA), biological warfare agents, and toxic industrial chemicals (TIC) and a method for producing the same. The invention fibers are applicable to the fields of protective garments, filtration materials, and decontamination materials.

Provided are MOF-fabric composites having a crystalline MOF adhered directly to fibers of the fabric and methods of making MOF-fabric composites. A solution is adsorbed onto a fabric. The solution can include a metal salt, a linker, and a solvent. The solution is adsorbed onto the fabric and the fabric suspended over a heated vapor. The vapor releases onto the fabric, causing the metal salt, the linker, and the solvent to diffuse out of the polymer fibers. The linker links metal from the metal salts to form crystals attached to the fabric, and the vapor aids crystallization.

Provided are a catalyst composition with improved processability and chemical warfare agent degradation ability, a film composite manufactured by casting the same, and a preparation method thereof. Specifically, provided are a catalyst composition including a copolymer of a first polymer and a second polymer; and a metal-organic framework (MOF), and a film composite including the same, wherein processability and catalytic activity are improved.

A decontamination paste comprising at least one inorganic viscosifier selected from clays, at least one compound in the form of fibers and optionally further one or more optional components, the remainder being of solvent. A method for decontaminating a substrate made of a solid material using the paste, the substrate being contaminated by at least one contaminant species referred to as the labile contaminant species and/or by at least one contaminant species referred to as the surface contaminant species located on one of the surfaces thereof, and/or by at least one contaminant species referred to as the subsurface contaminating species located just below said surface, and/or by at least one contaminant species located under the surface in the depth of the substrate.

The present application relates to methods for the reduction of halogenated hydrocarbons using compounds of Formula (I): ##STR00001##
wherein the reduction of the halogenated compounds is carried out, for example, under ambient conditions without the need for a transition metal containing co-factor. The present application also relates to methods of recovering precious metals using compounds of Formula (I) that are absorbed onto a support material.

A catalyst includes a bis(2-pyridylmethyl)amine-based ligand. A method of forming a catalyst, may include: reacting bis(2-pyridylmethyl)amine-based compound with a terminal azide and/or a terminal alkyne in the presence of Cu(I) to form a bis(2-pyridylmethyl)amine-based ligand. A method of using such catalysts may include neutralizing toxicity of at least one organophosphorus-based compound by reacting the organophosphorus-based compound with a bis(2-pyridylmethyl)amine-based ligand-metal complex.

A one part, solids containing decontamination blend composition comprises a solid acetyl donor coated with a compound that protects it from hydrolysis, a peroxygen source, optionally a catalyst, optionally a surfactant, and optionally a buffer. The decontamination blend composition is generally in a dry powder, particle, etc. form or in a tablet, pill, etc. form and is complete in and of itself in that no additional compounds are required prior to use and is readily distributed as a one package system. Upon the addition of water, a peroxygen compound such as hydrogen peroxide is formed, and peracetic acid is generated under alkaline conditions. The decontamination blend composition is particularly suitable for oxidizing various chemical and biological compounds thereby eradicating the same in situ as on surfaces, clothes, articles, and the like. Representative contaminants include mustard gas, nerve gas, bacterial toxins, anthrax, bird flu, and the like.

Variants of phosphotriesterase have been created that exhibit enhanced hydrolysis of V-type and G-type nerve agents over wild-type phosphotriesterase. V- and G-type nerve agents have an S.sub.P and R.sub.P enantiomer. The S.sub.P enantiomers are more toxic. V-type nerve agents are among the most toxic substances known. Variants of phosphotriesterase can prefer to hydrolyze one enantiomer of VX over the other enantiomer.