Multi-piece golf balls containing a multi-layered core structure are provided. The core structure includes a small, heavy inner core (center) having a relatively high specific gravity, an intermediate core layer, and a surrounding outer core layer. The layers of the core structure may have different hardness gradients. In one preferred embodiment, each core layer has a positive hardness gradient. The center of the core comprises a metal material such as copper, steel, brass, tungsten, titanium, aluminum, and alloys thereof. The intermediate core layer is preferably formed from a thermoset composition such as polybutadiene rubber, and the outer core layer is preferably formed from a thermoplastic composition such as an ethylene acid copolymer. The resulting ball has high resiliency and good spin control.

Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

In a golf ball having a core, a cover and a coating layer, the coating layer is formed of a urethane coating that includes an organic solvent having a boiling point of 80° C. or less, a silicone-based additive and, as a curing agent, a polyisocyanate which contains an adduct and an isocyanurate of hexamethylene diisocyanate. Although the golf ball includes a silicone-based additive in the outer surface (coating layer) of the ball, it has a good spin performance on approach shots not only when wet but also when normally dry, and is capable of exhibiting both a good water-repelling performance and a good friction performance.

In a golf ball having a core of at least one layer and a cover of at least one layer encasing the core, at least one layer of the cover is formed of a resin composition which includes (I) a polyurethane or a polyurea, (II) a thermoplastic polyester elastomer and (III) an aromatic vinyl elastomer. The thermoplastic polyester elastomer serving as component (II) and the aromatic vinyl elastomer serving component (III) have specific respective contents and properties, including Shore D hardnesses and rebound resiliences. The golf ball has an excellent controllability on approach shots without a loss of distance on driver shots. In addition, the scuff resistance and moldability are good.

Multi-layered golf balls having at least one layer made of a foamed silicone composition are provided. Multi-layered golf balls having at least one layer made of non-foamed silicone elastomer composition also are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core and cover structures can be made. The foamed silicones have good thermal stability and durability without sacrificing resiliency. The non-foamed silicone elastomers have high elongation, tensile strength, chemical/fluid-resistance, and weatherability properties. These compositions can be used to form any layer, for example, core, intermediate, or cover, in the golf ball.

In a golf ball having a rubber core of at least one layer and a cover of at least one layer encasing the core, at least one layer of the cover is formed of a resin composition that includes (I) a polyurethane or a polyurea and (II) a (meth)acrylic block copolymer, the (meth)acrylic block copolymer serving as component (II) being included in an amount of 20 parts by weight or less per 100 parts by weight of component (I). The golf ball has an excellent controllability on approach shots and is able to maintain a good scuff resistance and moldability.

Multi-layered golf balls having at least one layer made of a foamed silicone composition are provided. Multi-layered golf balls having at least one layer made of non-foamed silicone elastomer composition also are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core and cover structures can be made. The foamed silicones have good thermal stability and durability without sacrificing resiliency. The non-foamed silicone elastomers have high elongation, tensile strength, chemical/fluid-resistance, and weatherability properties. These compositions can be used to form any layer, for example, core, intermediate, or cover, in the golf ball.

Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

A golf ball includes a core having an outer surface and a geometric center; an inner cover layer, and an outer cover layer. The inner cover layer includes an ionomeric material and has a material hardness of about 60 Shore D or greater. The outer cover layer is formed from a polyurea or polyurethane and has a material hardness of about 60 Shore M or greater. The outer surface of the core has a hardness of about 68 to 92 Shore C. The geometric center of the core has a hardness of about 45 to 85 Shore C. The core outer surface hardness is greater than the geometric center hardness by about 5 to 21 Shore C to define a positive hardness gradient. The core also has a volume weighted average hardness, H.sub.V, of about 70 to 80, where

[00001]${\stackrel{\_}{H}}_V=\frac{I_V}{V_c}.$

Multi-layer golf balls comprising a single- or dual-layer core, an intermediate layer, and an outer cover layer are disclosed. The intermediate layer is formed from a thermoplastic elastomer composition and has a surface hardness which is greater than the center hardness of the core and less than the outer surface hardness of the core. The outer surface hardness of the outer cover layer is greater than the outer surface hardness of the core.