In a golf ball having a core composed of one or more layer, the outermost layer of the core is formed of a rubber composition containing an α,β-unsaturated metal carboxylate, and an envelope layer directly encasing the core is formed of a resin composition containing a thermoplastic resin having a structure that includes α,β-ethylenically unsaturated carboxylic acid copolymerization units. The infrared absorption spectra at surface sites on the outermost layer of the core, as measured by ATR FT-IR spectroscopy, satisfy a specific condition. The ball has an enhanced adhesion between the rubber-based core and the adjacent cover layer that is formed of an ionomer resin or other α,β-ethylenically unsaturated carboxylic acid copolymer-containing resin material.

Multi-piece golf balls containing a multi-layered core structure are provided. The core structure includes a small, heavy inner core (center) having a relatively high specific gravity, an intermediate core layer, and a surrounding outer core layer. The layers of the core structure may have different hardness gradients. In one preferred embodiment, each core layer has a positive hardness gradient. The center of the core comprises a metal material such as copper, steel, brass, tungsten, titanium, aluminum, and alloys thereof. The intermediate core layer is preferably formed from a thermoset composition such as polybutadiene rubber, and the outer core layer is preferably formed from a thermoplastic composition such as an ethylene acid copolymer. The resulting ball has high resiliency and good spin control.

The present invention is a modified resin for a molded article obtained by modifying an ethylene/unsaturated carboxylic acid copolymer with guanidine carbonate, wherein a melt flow rate of the ethylene/unsaturated carboxylic acid copolymer is 20 (g/10 minutes) or more and 600 (g/10 minutes) or less.

Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

A golf ball comprising layers that have from 0.05% to 70% by weight of a radio-opaque filler, and wherein the concentration of the radio-opaque filler is measurably different in each layer is disclosed herein. The radio-opaque filler is preferably a compound based on barium, bismuth, tungsten, iodine, or reduced iron.

A golf ball according to the present invention comprises: a core having a diameter of 37-39 mm and a first density; a mantle which surrounds the core, includes amorphous alloy powder, and has a thickness of 0.8-1.2 mm and a second density; and a cover which surrounds the mantle and has a thickness of 1-1.4 mm and a third density.

Golf ball comprising a core, an outer layer and at least one adhesion promoting coating disposed between each of the core and the outer layer; the core comprising a rubber composition comprising at least one zinc-containing and/or magnesium-containing component; the outer layer comprising at least one ionomer; and the adhesion promoting coating comprising a waterborne dispersion comprised of at least one ethylene acid copolymer having an acid content of at least 15% by weight wherein the copolymer is at least partially neutralized with one or more neutralizing agent; wherein at least one neutralizing agent is selected from ammonia compounds and/or amine compounds. In a specific embodiment, the at least one neutralizing agent comprises i) mono and/or divalent metal compounds and ii) ammonia compounds and/or amine compounds.

A method of producing a golf ball applies ultrasonic welding on two half shells to form at least one intermediate layer, at least one cover layer, or at least one intermediate layer and at least one cover layer. The ultrasonic welding may include pressing the two half shells together, delivering a high power electrical signal to a welding stack, and converting the high power electrical signal at the welding stack to ultrasonic energy. The converting may include converting the high power electrical signal into a mechanical vibration, modifying an amplitude of the mechanical vibration to generate a modified mechanical vibration, and applying the modified mechanical vibration to an interface of the two half shells to weld them together ultrasonically. Aspects also relate to golf balls, or one or more layers thereof, made using ultrasonic welding.

Golf ball molds and methods for molding golf balls, particularly golf balls having thermoplastic polyurethane covers, are provided. The molds and methods are particularly suitable for manufacturing covers for golf balls. Multi-piece golf balls having inner cores, outer cores, inner covers, and intermediate layers can be made. Retractable pins are used for holding the golf ball within the mold, wherein each retractable pin has a primary vent section, secondary vent section, and tertiary vent section for removing air and other gasses from the interior spherical cavity of the mold.

In a golf ball having a two-layer core which includes an inner core layer and an outer core layer and having a cover of one or more layer, the outer core layer is formed of an elastomer composition that includes specific amounts of (A) polybutadiene having a 1,2-bond content of 50 to 95%, (B) a photocurable monomer, oligomer or polymer, and (C) a photopolymerizable initiator. The outer core layer has a thickness of from 1.0 to 4.0 mm, and the two-layer core has a surface hardness on the JIS-C scale of from 75 to 95. The ball is provided with a hardness gradient at the core interior, which lowers the spin rate of the ball, has an improved durability to cracking, and production costs for the outer core layer are kept relatively low.