Patent classifications
A63B37/0048
GOLF BALL
In a golf ball having a core and a cover of at least one layer, the core and/or at least one layer of the cover are formed of a resin composition that includes (A) 100 parts by weight of a thermoplastic resin, and (B) 1 to 30 parts by weight of a compound having a fluorene skeleton, or a derivative thereof. This resin composition for golf balls has an improved injection-moldability and thus enables the ball to achieve both a reduced spin rate and a good durability (scuff resistance).
Golf ball
In a golf ball having a rubber core and an intermediate layer and outermost layer which encase the core, the intermediate layer is formed of a thermoplastic resin composition which has a flexural rigidity of 400 to 500 MPa and a melt flow rate of 15 g/10 min or less and includes 50 to 100 wt % of a magnesium salt of an ethylenically unsaturated carboxylic acid copolymer, the outermost layer is formed of a polyurethane resin composition having a Shore D material hardness of 55 or less, and the golf ball has a deflection within a given range. Compared with conventional golf balls containing the high-rigidity ionomer resins hitherto used as intermediate layer materials, this ball suppresses the spin rate on shots with a driver and long and middle irons, enabling an increased distance to be obtained, and also has a high durability to repeated impact.
GOLF BALL AND METHOD OF MAKING SAME
Golf ball incorporating at least one layer comprised of at least one polyethylene-based vitrimer, which may comprise a blend of polyethylene and dioxaborolane maleimide, and in some embodiments, be blended with thermoplastics such as ionomers and/or polyurethanes.
GOLF BALL
In a golf ball having a rubber core and an intermediate layer and outermost layer which encase the core, the intermediate layer is formed of a thermoplastic resin composition which has a flexural rigidity of 400 to 500 MPa and a melt flow rate of 15 g/10 min or less and includes 50 to 100 wt % of a magnesium salt of an ethylenically unsaturated carboxylic acid copolymer, the outermost layer is formed of a polyurethane resin composition having a Shore D material hardness of 55 or less, and the golf ball has a deflection within a given range. Compared with conventional golf balls containing the high-rigidity ionomer resins hitherto used as intermediate layer materials, this ball suppresses the spin rate on shots with a driver and long and middle irons, enabling an increased distance to be obtained, and also has a high durability to repeated impact.
Golf ball incorporating at least one layer of neutralized acid polymer composition containing low molecular weight acid wax(es) as sole acid polymer component and low molecular weight non-acid wax(es) in the non-acid polymer component
Golf ball comprising layer(s) comprised of a mixture of: (a) low molecular weight acid-containing wax(es); (b) non-acid-polymer(s) including at least one low molecular weight non-acid wax such as high density oxidized polyethylene homopolymers; ethylene maleic anhydride copolymers; polypropylene maleic anhydride copolymers; polypropylene homopolymers; ethylene-vinyl acetate copolymers; high density oxidized homopolymers; oxidized copolymers; polyethylene micronized waxes; polytetrafluoroethylene micronized waxes; emulsifiable low molecular weight non-acid waxes; non-emulsifiable low molecular weight non-acid waxes; and/or chemically modified low molecular weight non-acid waxes; and (c) organic acid(s) or salt thereof. Molecular weight of each low molecular weight acid-containing wax is about 500 to 7000, or up to 30,000. Interactions between components (a), (b), and (c) advantageously produce layer of ionomeric material having heat stability, processability, and well-retained durability, adhesion, CoR, compression and targeted feel without need for blending high and low molecular weight acid-containing polymer(s).
Golf ball incorporating melt processable highly-crosslinked rubber-containing ionomer(s)
Golf ball incorporating layer(s) of a mixture consisting of: i) ionomer(s); ii) ethylene propylene rubber(s)(EPR(s)); iii) polymeric epoxy crosslinker(s); and iv) compatibilizing polymer(s). The ionomer(s) and EPR(s) may be included in a blend in a wt % ratio of from about 85:15 to 55:45; the at least one polymeric epoxy crosslinker and compatibilizing polymer may be included in amounts, based on 100 parts of the blend, of from about 2.0 to about 10.0 parts; and from about 1.0 to about 10.0 parts, respectively. Each ionomer, EPR, polymeric epoxy crosslinker, and compatibilizing polymer has a density less than 1.0 g/cm.sup.3. The mixture is melt processable/moldable without meanwhile sacrificing target CoR, DCM compression, Shore D hardness, and Shore C hardness.
Golf ball incorporating melt processable highly-crosslinked ethylene acid copolymer(s) and/or ionomer(s)
Golf ball comprising layer(s) consisting of a mixture consisting of: i) ethylene acid copolymer(s) and/or ionomer(s); ii) polyethylene(s); iii) polymeric epoxy crosslinker(s); and iv) compatibilizing polymer(s). The ethylene acid copolymer(s)/ionomer(s) and the polyethylene(s) may be included in a blend in a wt % ratio of from about 85:15 to 55:45; the at least one polymeric epoxy crosslinker and compatibilizing polymer may be included in amounts, based on 100 parts of the blend, of from about 2.0 to about 10.0 parts; and from about 1.0 to about 10.0 parts, respectively. The polyethylene may be polyethylene butene; polyethylene hexene; polyethylene octene; and combinations thereof. Each ethylene acid copolymer, polyethylene, polymeric epoxy crosslinker, and compatibilizing polymer has a density less than 1.0 g/cm.sup.3. The mixture is moldable and meanwhile possesses similar desirable CoR, DCM compression, Shore D hardness, and Shore C hardness as a mixture consisting of ingredients i), ii) and iv).
A GOLF BALL COMPRISING A VERY-LOW MELT FLOW INNER COVER LAYER COMPOSITION
A golf ball including a core; an inner cover layer formed from a first thermoplastic composition and having a thickness of about 0.005 inches to 0.40 inches and a surface hardness of about 60 Shore D or greater; and an outer cover layer formed from a thermoplastic polyurethane material and having a thickness of about 0.01 inches to 0.075 inches and a surface hardness of about 60 Shore D or less. The thermoplastic composition has a first melt flow index at 280 C. under a 10-kg load of less than about 35 g/10 min and a second melt flow index at 265 C. under a 5-kg load of less than about 10 g/10 min.
GOLF BALL INCORPORATING AT LEAST ONE LAYER OF NEUTRALIZED ACID POLYMER COMPOSITION CONTAINING LOW MOLECULAR WEIGHT ACID WAX(ES) AS SOLE ACID POLYMER COMPONENT AND LOW MOLECULAR WEIGHT NON-ACID WAX(ES) IN THE NON-ACID POLYMER COMPONENT
Golf ball comprising layer(s) comprised of a mixture of: (a) low molecular weight acid-containing wax(es); (b) non-acid-polymer(s) including at least one low molecular weight non-acid wax such as high density oxidized polyethylene homopolymers; ethylene maleic anhydride copolymers; polypropylene maleic anhydride copolymers; polypropylene homopolymers; ethylene-vinyl acetate copolymers; high density oxidized homopolymers; oxidized copolymers; polyethylene micronized waxes; polytetrafluoroethylene micronized waxes; emulsifiable low molecular weight non-acid waxes; non-emulsifiable low molecular weight non-acid waxes; and/or chemically modified low molecular weight non-acid waxes; and (c) organic acid(s) or salt thereof. Molecular weight of each low molecular weight acid-containing wax is about 500 to 7000, or up to 30,000. Interactions between components (a), (b), and (c) advantageously produce layer of ionomeric material having heat stability, processability, and well-retained durability, adhesion, CoR, compression and targeted feel without need for blending high and low molecular weight acid-containing polymer(s).
Golf ball comprising a very-low melt flow inner cover layer composition
A golf ball including a core; an inner cover layer formed from a thermoplastic composition and having a thickness of about 0.005 inches to 0.40 inches and a surface hardness of about 60 Shore D or greater; and an outer cover layer formed from a thermoset material and having a thickness of about 0.01 inches to 0.05 inches and a surface hardness of about 60 Shore D or less. The thermoplastic composition has a first melt flow index at 280 C. under a 10-kg load of less than about 35 g/10 min and a second melt flow index at 265 C. under a 5-kg load of less than about 10 g/10 min.