A duct can be configured to receive a denuding gas flow. A solid denuding surface that is connected to a drive system can be configured to move the solid denuding surface within the duct while the solid denuding surface is continuously concentrating one or more gas-phase species from the denuding gas flow on the denuding surface. Also, a denuding gas flow can be passed along a denuding surface to concentrate one or more gas phase species from the denuding gas flow onto the denuding surface with a diffusion denuding action. The denuding surface can be moved while continuing to concentrate the one or more gas phase species from the denuding gas flow onto the denuding surface.

The present disclosure provides systems and methods useful in capture of one more moieties (e.g., carbon dioxide) from a gas stream (i.e., direct air capture). In various embodiments, the systems and methods can utilize at least a scrubbing unit, a regeneration unit, and an electrolysis unit whereby an alkali solution can be used to strip the moiety (e.g., carbon dioxide) from the gas stream, the removed moiety can be regenerated and optionally purified for capture or other use, and a formed salt can be subjected to electrolysis to recycle the alkali solution back to the scrubber for re-use with simultaneous production of one or more further chemicals.

Methods related generally to the removal of atmospheric pollutants from the gas phase, are provided, as well as related apparatus, processes and uses thereof. A single-stage air scrubbing apparatus is provided that includes at least one reaction vessel, at least one introduction duct, and a turbulence component, wherein a residence time is sufficient to allow the conversion of at least one atmospheric pollution compound to at least one other compound, molecule or atom. In some embodiments, the at least one atmospheric pollution compound comprises nitrogen oxide, sulfur oxide or a combination thereof. Additionally, methods of removing atmospheric pollution compounds from a waste gas stream are disclosed that include introducing a waste gas stream and at least one additional gas stream, mist stream, liquid stream or combination thereof into a single-stage air scrubbing apparatus at a flow rate sufficient to allow for conversion of the at least one atmospheric pollution compound.

The present invention relates to a systems and methods for improved removal of one or more species in a process stream, such as combustion product stream formed in a power production process. The systems and methods particularly can include contacting the process stream with an advanced oxidant and with water.

The present disclosure relates to systems and methods of making ammonia using stable ammonia absorbents. The system and method for producing ammonia, comprises a reactor comprising a catalyst that converts at least a portion of nitrogen feed gas and at least a portion of hydrogen feed gas to ammonia (NH3) forming a reaction mixture comprising the ammonia, unreacted nitrogen, and unreacted hydrogen. An absorber configured to selectively absorb ammonia from the reaction mixture at a temperature of about 180 deg. C. to 330 deg. C. and a pressure of about 1-20 bar, the absorber comprising a solid absorbent. Preferably the solid absorbent is at least one metal halide and a solid support. The unabsorbed ammonium, the unreacted nitrogen, and unreacted hydrogen gas are recycled to the reactor.

The present disclosure is directed to the use of elemental or speciated iodine and bromine to control total mercury emissions.

The present invention provides a new method for fixing carbon dioxide. The method for fixing carbon dioxide of the present invention, includes: a contact step of bringing a mixed liquid containing sodium hydroxide and further containing at least one of a chloride of a Group 2 element or a chloride of a divalent metal element into contact with a gas containing carbon dioxide, wherein in the contact step, the mixed liquid and the gas are brought into contact with each other by feeding the gas into the mixed liquid, a concentration of the sodium hydroxide in the mixed liquid is 0.01 N or more and 0.2 N or less, and in the contact step, the feeding is performed by a motor-driven pump, and the motor is driven by utilizing power generated by photovoltaic power generation.

In various embodiments, methods of treating a space to reduce a concentration of volatile organic compounds present in the space using chlorine dioxide are provided. A method can include application of aqueous and gaseous chlorine dioxide solutions within the space or to materials located within the space. Treatment of materials that emit volatile organic compounds with chlorine dioxide can reduce the emission rate or shorten the volatile organic compound emission cycle of the material. Soft surface substrates such as carpeting materials can be treated with chlorine dioxide to reduce volatile organic compound emission and/or to reduce the number of microorganisms present in the material.

A process for recovering nitric acid or salts thereof, comprising: contacting, in the presence of water, an water-immiscible ionic liquid of the formula [A.sup.+][X.sup.−], wherein [A.sup.+] represents a phosphonium or ammonium cation and [X.sup.−] represents a counter anion which is NO.sub.3.sup.−, an halide anion displaceable by NO.sub.3.sup.−, or both, with a fluid which contains HNO.sub.3 and at least one more mineral acid, or precursors of said acids, and partition, under mixing, said acids between aqueous and organic phases and form nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 where Z indicates a molar amount of nitrate held in the ionic liquid beyond the positions occupied by the nitrate counter ions; separating the so-formed mixture into an organic phase comprising a nitrate-loaded ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z>0.25 and an aqueous phase consisting of a nitrate-depleted aqueous solution that contains the other mineral acid(s); stripping the nitric acid from said nitrate-loaded ionic liquid to create an aqueous nitrate solution and regenerate ionic liquid of the formula [A.sup.+][NO.sub.3.sup.−].sub.z≥0 with reduced nitrate loading, or unloaded [A.sup.+][NO.sub.3.sup.−].sub.z=0 ionic liquid.

Some aspects of the present disclosure relate to a method comprising obtaining a sorbent polymer composite material, contacting the sorbent polymer composite material with mercury vapor to form a used sorbent polymer composite material; wherein the used sorbent polymer composite material comprises oxidized mercury and wherein the used sorbent polymer composite material emits oxidized mercury vapor; and contacting the used sorbent polymer composite material with a halogen source, so as to result in a treated sorbent polymer composite material. In some embodiments, the treated sorbent polymer composite material emits less than 0.01 μg oxidized mercury vapor per minute per gram of the treated sorbent polymer composite, compared to a used sorbent polymer composite, when measured at 65° C. in air having a relative humidity of 95%.