The use of a composition including at least one acido-basic neutralising agent for decontaminating an atmosphere contaminated by a corrosive gas, the acido-basic neutralising agent having at least 2 pKa's and being characterised by: pKa 1≤pKa 2, pKa 1>2, pKa 2<12, 4<½ (pKa 1+pKa 2)<10 pKa 1, representing the smallest of the basic pKa's and pKa 2 representing the largest of the acidic pKa's. Also, a method for decontaminating an atmosphere contaminated by a corrosive gas comprising the spraying of the neutralising agent, and to a decontamination device.

Capture of hydrogen sulfide from a gas mixture may be accomplished using an aqueous solution comprising an amine. Certain sterically hindered amines may selectively form a reaction product with hydrogen sulfide under kinetically controlled contacting conditions and afford a light phase and a heavy phase above a critical solution temperature, wherein the hydrogen sulfide may be present in either phase. Upon separation of the light phase from the heavy phase, processing of one of the phases may take place to remove hydrogen sulfide therefrom. Recycling of the amine to an absorber tower may then take place to promote capture of additional hydrogen sulfide.

The present invention discloses a method for ammonium-enhanced flue gas desulfurization (FGD) by using red mud slurry. The method specifically includes: crushing red mud, sieving the crushed red mud, slurrying the red mud, conducting aeration treatment, adding an ammonium salt and/or ammonia, and conducting natural sedimentation to obtain pretreated red mud slurry and pretreated red mud liquor; adding an ammonium salt and/or ammonia to the slurry, adding water and conducting uniform mixing, conducting pre-FGD, conducting deep desulfurization on treated flue gas by using the pretreated red mud liquor, and directly discharging desulfurized flue gas; and charging the pretreated red mud slurry and the pretreated red mud liquor obtained after the treatment to a replacement tank below, adding lime milk to the replacement tank, conducting stirring and natural sedimentation, conducting soilization on subnatant thick red mud slurry, and refluxing the supernatant to a red mud aeration tank.

A fossil fuel fired power plant exhaust gas clean-up and recovery system is provided to remove detrimental exhaust gases from the power plant exhaust and to produce and reclaim various commercial byproducts. A process includes mixing one liquid solution with a solubilizer in a mixing tank containing water to create a chemical reaction therein to produce an ionic solid compound and an alkaline liquid solution. Simultaneously directing the flue gases and the alkaline liquid solution into the wet scrubber to create a chemical reaction therein. The chemical reaction removes various detrimental exhaust gases from the flue gases and captures CO.sub.2 gases therefrom, which are chemically transferred into a newly formed sodium bicarbonate solution. The sodium bicarbonate solution exiting the wet scrubber is stored for resale or reuse in the subject process. The process uses various pathways to distribute the sodium bicarbonate for producing other byproducts.

A composite comprising a hydroxyapatite and at least one additive which is present during hydroxyapatite synthesis. The additive may be embedded or incorporated into or coated onto the hydroxyapatite. The additive preferably increases the hydroxyapatite porosity, e.g., providing a higher pore volume and/or BET surface area than a hydroxyapatite material without additive. The additive preferably comprises an activated carbon, chitosan, hopcalite, clays, zeolites, sulfur, and/or a metal such as Al, Sn, Ti, Fe, Cu, Zn, Ni, Cu, Zr, La, Ce, in the form of metal, salt, oxide, oxyhydroxide, and/or hydroxide. The hydroxyapatite may be calcium-deficient. The composite is in the form of particles having a D50 of at least 20 μm, a BET surface area of at least 120 m.sup.2/g; and/or a total pore volume of at least 0.3 cm.sup.3/g. An adsorbent material comprising a composite or a blend of composite with a hydroxyapatite without additive, and its use for removal of contaminants such as Hg, Se, As, and/or B from an effluent.

An emissions clean-up process is provided to remove detrimental exhaust gases from a fossil fuel power plant and to produce and/or reclaim various useful commercial byproducts. The process includes mixing a blended liquid solution with a solubilizer in a mixing tank to create a chemical reaction therein to produce an ionic solid and an alkaline liquid solution. By mixing various blended solutions with desired solubilizers, alkaline liquids are produced which may be chemically combined to create other byproducts or sold commercially. Likewise, the alkaline liquids may be passed through a wet scrubber to create a byproduct that when chemically mixed with an acid creates desired byproducts. Other byproducts such as a sodium bicarbonate liquid solution exits the wet scrubber and is sold or used in the subject process to produce various other byproducts.

The invention relates to a process for dehumidifying a moist gas mixture in which the moist gas mixtures are brought into contact with an absorbent comprising dialkylimidazolium salts and trialkyl phosphate. In addition, the invention also relates to an absorption heat pump comprising the absorbent according to the invention and to the absorbent according to the invention itself.

The invention relates to a process for dehumidifying a moist gas mixture. The invention further relates to an apparatus for dehumidifying a moist gas mixture and to the use of said apparatus in the process according to the invention.

A method for production of ammonium phosphate from phosphate rock slurry. The method includes: introducing flue gas containing SO.sub.2 into a phosphate rock slurry, to yield an absorption solution; evaporating waste ammonia water containing 10-20 wt. % ammonia to yield ammonia gas; introducing the ammonia gas into the absorption solution at a temperature of 110-135° C. until a neutralization degree of the absorption solution reaches 1.5-1.6, thus yielding an ammonium phosphate solution and calcium sulfate; separating the calcium sulfate from the ammonium phosphate solution; and introducing the ammonium phosphate solution to a granulator for granulation to yield ammonium phosphate granules; drying and sieving the ammonium phosphate granules, thereby yielding ammonium phosphate.

Materials and methods for mitigating the effects of halide species contained in process streams are provided. A halide-containing process stream can be contacted with mitigation materials comprising active metal oxides and a non-acidic high surface area carrier combined with a solid, porous substrate. The halide species in the process stream can be reacted with the mitigation material to produce neutralized halide salts and a process stream that is essentially halide-free. The neutralized salts can be attracted and retained on the solid, porous substrate.