The present system reduces the cost of carbon capture by reducing the over-temperature needed to strip CO.sub.2 from a liquid or fluid solution. The system includes structures that enhance the rate of CO.sub.2 bubble nucleation.

The disclosure concerns a process for producing formic acid, having (a) a carbon capture step in which a source of carbon dioxide is contacted with an amine solution in a closed-top scrubber, to obtain an ammonium bicarbonate solution; (b) inducing crystallization in the ammonium bicarbonate solution to obtain a concentrated ammonium bicarbonate solution; (c) subjecting the concentrated ammonium bicarbonate solution to a hydrogenation step to obtain an ammonium formate; and (d) heating the ammonium formate to a temperature in the range of 50-150° C., to obtain a gaseous product containing the amine and a liquid product stream containing formic acid. The source of carbon dioxide has a carbon dioxide content of at least 95 vol % and the amine used in step (a) and reformed in step (d) has a partial vapour pressure above a 40 wt % solution of the amine in water at 20° C. of at least 40 kPa. The disclosure further concerns a system for performing the process.

A system and method for removing hydrogen sulfide from natural gas using a triazine scavenger is described. The system includes a pre-treatment system that can be connected to an existing hydrogen sulfide removal system to more fully utilize the triazine scavenger. The pre-treatment system includes a contactor vessel in which sour natural gas is contacted with fresh and/or partially consumed scavenger to partially sweeten the sour gas by removing H.sub.2S. The partially sweetened gas then flows to the existing hydrogen sulfide removal system where it is fully sweetened.

A pyrazole metal complex for absorption of carbon dioxide, a method for preparing the pyrazole metal complex, and a method for absorbing carbon dioxide are provided; wherein the product produced by reacting pyrazole metal complex and carbon dioxide may be transformed into several economically valuable compounds.

Embodiments provide an amine compound having a large amount of an acid gas to be absorbed and strong oxidation resistance, an absorbent containing the amine compound, a method for removing an acid gas, and an acid gas removal apparatus. The acid gas absorbent includes an amine compound of Formula (1a) or (2b): wherein: R.sup.1 to R.sup.3 are each independently a hydrogen alkyl group, R.sup.2's are each independently an alkyl group, and at least two of R.sup.2's contained in one-CR.sup.2.sub.3 are not hydrogen, a's are each independently 0 or 1, m is a number of 1 to 3; n's are each independently a number of 1 to 4.

Compositions with supramolecular structures for use in oil and gas production and other applications include an H.sub.2S scavenger, a supramolecular host chemical or a supramolecular guest chemical configured to engage in host-guest chemistry with the scavenger, and a solvent. Methods of controlling H.sub.2S at a production site include applying an effective amount of the composition to the production stream.

This disclosure relates to a process for removing acid gases from a gas stream enriched in acid gases, wherein: (a) the gas stream enriched in acid gases is contacted in an absorption zone with an absorption medium, wherein the absorption medium is an aqueous medium comprising an amine, to form a gas stream depleted in acid gases which comprises an entrained amine and an absorption medium enriched in acid gases; and (b) treating the gas stream depleted in acid gases which comprises an entrained amine in a first scrubbing zone with a first scrubbing medium, wherein the first scrubbing medium is an aqueous medium comprising an amine, the amount of amine comprised by the scrubbing medium being about 0.1 to about 50.0 wt. %, wherein the aqueous medium is saturated with carbon dioxide such that at least 75 wt. % of the amine, based on the total amount of amine comprised by the aqueous medium, is in its carbamate or carbonate form, to form a gas stream depleted in acid gases and in amine and a first scrubbing medium enriched in amine.

An H.sub.2S stripper that utilizes random packing material in the center column to greatly increase the conversion of H.sub.2S gas to a solid form of sulfur. A thin film of scrubbing solution coating the packing material allows for a more efficient process of H.sub.2S scrubbing that can reduce the chemical consumption rates of traditional, commercially available sulfide scavengers by 25 to 60%. This unit also allows for an easy clean out and is built to handle the pressure extremes that could be encountered in oil wells and/or gas wells, gas plants, offshore rigs, gas gathering systems, or pipe lines while not having any mechanical parts. This invention improves the H.sub.2S removal process and reduces the amount of H.sub.2S in natural gas streams as well as reducing the amount of treating chemicals.

This disclosure relates to a process for removing acid gases from a gas stream enriched in acid gases, wherein: (a) the gas stream enriched in acid gases is contacted in an absorption zone with an absorption medium, wherein the absorption medium is an aqueous medium comprising an amine, to form a gas stream depleted in acid gases which comprises an entrained amine and an absorption medium enriched in acid gases; and (b) treating the gas stream depleted in acid gases which comprises an entrained amine in a scrubbing zone with a scrubbing medium, wherein the scrubbing medium is an aqueous medium comprising an amine, the amount of amine comprised by the scrubbing medium being about 0 to about 10.0 wt. %, to form a gas stream depleted in acid gases and in amine and a scrubbing medium enriched in amine.

The present invention relates to a carbon dioxide absorbent comprising a triamine, a diamine and a dialkylene glycol dialkyl ether or trialkylene glycol dialkyl ether. The carbon dioxide absorbent according to the present invention can improve the carbon dioxide absorption capacity, absorption rate, and regeneration performance thereof simultaneously by using the triamine as a main absorbent, the diamine as a rate enhancer, the dialkylene glycol dialkyl ether or trialkylene glycol dialkyl ether as a fine disproportionation agent and a regeneration promoter.