B01D2253/1085

Ethylene separations using small pore zeolite SSZ-45
11571653 · 2023-02-07 · ·

The present invention and embodiments thereof provide a process to separate ethylene products from impurities such as nitrogen, hydrogen, ethane, propane and isobutane without the need for distillation processes.

Ethylene separations using a small pore zeolite with CDO framework

The present invention, and embodiments thereof, provide a process to separate ethylene products from impurities such as nitrogen, hydrogen, ethane, propane and isobutane without the need for distillation processes.

PROCESS FOR THE REMOVAL OF H2S FROM NATURAL GAS AT HIGH PRESSURES BY MEANS OF A PSA PROCESS

The present invention addresses to the use of NaY zeolite with a Si/Al ratio >2.6 as a solid adsorbent in the process of removing H.sub.2S from natural gas through a PSA process. The described adsorbent has the capacity of removing H.sub.2S from natural gas from offshore exploration platforms, enabling in situ regeneration. The experimental development proved the high capacity of capturing H.sub.2S by the NaY zeolite in consecutive cycles of pressurization, adsorption, depressurization and purging. This capture capacity remains at 74.2% of the initial capacity, remaining stable in subsequent cycles. The structure of the material maintained crystallinity above 95% in use, in 15 consecutive cycles, allowing the reuse of the adsorbent for a prolonged period of operation, preventing the solid from being constantly changed, which is quite common in a non-regenerative process.

Systems and methods for gas treatment

A system and process for the recovery of at least one halogenated hydrocarbon from a gas stream. The recovery includes adsorption by exposing the gas stream to an adsorbent with a lattice structure having pore diameters with an average pore opening of between about 5 and about 50 angstroms. The adsorbent is then regenerated by exposing the adsorbent to a purge gas under conditions which efficiently desorb the at least one adsorbed halogenated hydrocarbon from the adsorbent. The at least one halogenated hydrocarbon (and impurities or reaction products) can be condensed from the purge gas and subjected to fractional distillation to provide a recovered halogenated hydrocarbon.

HYDROCARBON ADSORBENT AND METHOD FOR ADSORBING HYDROCARBONS
20230148413 · 2023-05-11 · ·

A hydrocarbon adsorbent having a high hydrocarbon desorption start temperature and a method for adsorbing hydrocarbons that uses the hydrocarbon adsorbent are provided. The hydrocarbon adsorbent includes an alkali metal and a zeolite having a ring structure that includes at least 10 members is used. In the hydrocarbon adsorbent, a content of the alkali metal is 1 to 40 mass % based on a total mass of the hydrocarbon adsorbent, a content of the zeolite having a ring structure that includes at least 10 members is 99 to 60 mass % based on the total mass of the hydrocarbon adsorbent, and at least a portion of the alkali metal is in a state of being ion-exchangeable.

Adsorbent materials and methods of adsorbing carbon dioxide

Methods of designing zeolite materials for adsorption of CO.sub.2. Zeolite materials and processes for CO.sub.2 adsorption using zeolite materials.

PACKAGING MATERIALS

The use of a palladium-doped zeolite for the adsorption of volatile organic compounds is described wherein the zeolite has a CHA framework type and is polymer-bound. Such zeolites have been found to have particular utility as packaging materials for the adsorption of volatile organic compounds, such as those originating from organic matter.

HYDROCARBON ADSORBENT WITH METAL-IMPREGNATED ZEOLITE PARTICLE HAVING REGULAR MESOPORE AND MANUFACTURING METHOD THEREFOR

The present invention relates to a hydrocarbon adsorbent with metal-impregnated zeolite particles having regular mesopores and a manufacturing method therefor. The hydrocarbon adsorbent includes a metal cation and a metal oxide that are impregnated in zeolite particles, in particular, the zeolite particles include regularly formed mesopores having a size of 2 to 10. By adjusting a Si/Al ratio and mesoporosity of the mesopores, a hydrocarbon adsorbent may have increased adsorption capacity for hydrocarbons in a cold-start section and can rapidly oxidize the hydrocarbon upon desorption thereof, thereby reducing the discharge of exhaust gas produced in automobiles and industries.

Hydrocarbon reforming/trapping material and method for removing hydrocarbon

To provide a hydrocarbon reforming/trapping material which is capable of adsorbing and reforming a hydrocarbon. A hydrocarbon reforming/trapping material of the present invention has an SiO.sub.2/Al2O.sub.3 ratio of from 7 to 12, and contains an Fe(II)-substituted beta zeolite which is ion-exchanged by Fe(II) ions. The amount of supported Fe(II) is preferably 0.001-0.5 mmol/g with respect to the Fe(II)-substituted beta zeolite. This Fe(II)-substituted beta zeolite is suitably produced by dispersing and mixing a beta zeolite having an SiO.sub.2/Al.sub.2O.sub.3 ratio of from 7 to 12 in an aqueous solution of a water-soluble compound of divalent iron, and mixing and stirring the solution, so that Fe(II) ions are supported on the beta zeolite.

METHOD FOR GAS SEPARATION

A method for separating at least one hydrocarbon from a feed containing a mixture of at least one hydrocarbon and nitrogen, comprising contacting the feed with an adsorbent comprising a porous support wherein the porous support comprises exchangeable cations and at least a portion of the exchangeable cations are organic cations.