An object of the present invention is to provide an exhaust gas purification system including a first exhaust gas treatment section provided upstream in an exhaust pathway of an internal-combustion engine, a second exhaust gas treatment section provided upstream in the exhaust pathway of the internal-combustion engine, wherein the exhaust gas purification system allows rhodium element contained in a catalyst layer of the second exhaust gas treatment section to efficiently exhibit the catalytic activity, and the present invention provides an exhaust gas purification system (1) configured to purify exhaust gas emitted from an internal-combustion engine, the exhaust gas purification system (1) including an exhaust gas path (2) through which exhaust gas flows, a first exhaust gas treatment section (3) provided upstream in the exhaust gas path (2), and a second exhaust gas treatment section (4) provided downstream in the exhaust gas path (2); wherein first catalyst layers of the first exhaust gas treatment section (3) each contain cerium element; wherein a percentage of the mass of the cerium element contained in the first catalyst layers in terms of cerium oxide, to the mass of the first catalyst layers, is 5.0% by mass or more and 13.0% by mass or less; and wherein second catalyst layers of the second exhaust gas treatment section (4) each contain rhodium element.

A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).

An aftertreatment component for use in an exhaust aftertreatment system. The aftertreatment component comprises an aftertreatment substrate and a compressible material. The compressible material may be formed from a plastic thermoset, a rubberized material, or a metal foil which permits for the selective expansion of the substrate within the compressible material, while also reducing cost and manufacturing complexity. In various embodiments, the aftertreatment substrate and the compressible materials may be formed separately and coupled to each other, or they may be formed concurrently via coextrusion.

A selective catalytic reduction catalyst for the treatment of an exhaust gas stream of a passive ignition engine, the catalyst comprising a porous wall-flow filter substrate comprising an inlet end, an outlet end, a substrate axial length (w) extending between the inlet end and the outlet end, and a plurality of passages defined by porous internal walls of the porous wall flow filter substrate; wherein the catalyst further comprises a first coating, said first coating extending over x % of the substrate axial length from the inlet end toward the outlet end of the substrate, x being in the range of from 10 to 100, wherein the first coating comprises copper and an 8-membered ring pore zeolitic material; wherein the catalyst further comprises a second coating, the second coating extending over y % of the substrate axial length from the outlet end toward the inlet end of the substrate, y being in the range of from 20 to 90, wherein the second coating comprises copper, and optionally an 8-membered ring pore zeolitic material; wherein the catalyst optionally further comprises a third coating; wherein x+y is at least 90; wherein y % of w from the outlet end toward the inlet end of the substrate define the outlet zone of the coated substrate and (100−y) % of w from the inlet end toward the outlet end of the substrate define the inlet zone of the coated substrate; wherein the ratio of the loading of copper in the inlet zone, Cu(in), calculated as CuO, relative to the loading of copper in the outlet zone, Cu(out), calculated as CuO, Cu(in):Cu(out), is less than 1:1.

The present invention relates to a catalyst comprising a carrier substrate of length L and at least two washcoat layers A and B wherein washcoat layer A comprises alumina; ceria; an alkaline earth compound and/or an alkali compound; platinum, palladium or platinum and palladium; washcoat layer B comprises a zeolite and palladium, wherein the palladium is present as palladium cation in the zeolite structure or is wholly or partially present as palladium metal and/or as palladium oxide in the zeolite structure and/or on the surface of the zeolite structure; and
wherein washcoat layer A is arranged below washcoat layer B.

An automotive catalytic converter includes a three-way catalyst having Rh as the only precious metal configured as a front zone and a three-way catalyst having a mixture of Rh and Pd, Pt, or both configured as a rear zone, such that an exhaust gas from an internal combustion engine passes through the front zone before passing through the rear zone to minimize sulfur poisoning of the catalytic converter.

A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers.

A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate comprising an inlet end and an outlet end with an axial length L; a first catalytic region comprising a first platinum group metal (PGM) component and a first oxygen storage capacity (OSC) material, wherein the first OSC material has a fresh specific surface area (SSA) of at least 10 m.sup.2/g; and wherein the first OSC material has an SSA difference of no more than 30 m.sup.2/g between the fresh first OSC material and the aged first OSC material.

The present invention relates to a process for preparing a catalyst for the selective catalytic reduction of nitrogen oxide comprising, among other steps, preparing a second aqueous mixture comprising water and an iron salt; and disposing the second mixture on the substrate obtained according to (ii), comprising a coating comprising a zeolitic material comprising copper, over y % of the substrate axial length from the inlet end to the outlet end of the substrate, wherein y is in the range of from 10 to x, obtaining a substrate comprising, in a first zone, the coating comprising a zeolitic material comprising copper and over y % of the substrate axial length an iron salt; and, if x > y, in a second zone extending from y % to x % of the substrate axial length from the inlet end to the outlet end, the coating comprising a zeolitic material comprising copper.

A layered diesel oxidation catalyst for treatment of exhaust gas emissions from a diesel engine comprising: a flow-through monolith substrate having a honeycomb structure and comprising a front zone and a rear zone, wherein the front zone of the substrate comprises a combination of layers, one on top of another and comprising two or more of layers A, B and C; and the rear zone comprises Layer D, wherein: Layer A comprises platinum, palladium, or combinations thereof on a molecular sieve; Layer B comprises 1) platinum, palladium, or combinations thereof on a refractory metal oxide support; and 2) an alkaline earth metal, preferably barium, strontium or combinations thereof; Layer C comprises 1) a platinum group metal, which is platinum or a combination of both platinum and palladium on a refractory metal oxide support; and 2) a promoter metal, which is manganese and/or bismuth; and layer D comprises 1) platinum or a combination of both platinum and palladium on a refractory metal oxide support; and 2) manganese (Mn).