A porous composite includes a porous base material, and a porous collection layer. The collection layer is provided on the base material. The collection layer contains praseodymium oxide.

Described are catalytic articles comprising a substrate having a washcoat on the substrate, the washcoat containing a catalytic component having a first average (D50) particle size and a functional binder component having a second average (D50) particle size in the range of about 10 nm to about 1000 nm, wherein the ratio of the first average (D50) particle size to the second average (D50) particle size is greater than about 10:1. The catalytic articles are useful in methods and systems to purify exhaust gas streams from an engine.

Disclosed herein are supramolecular porous organic nanocomposites for heterogenous photocatalysis as well as methods of making and using the same. The nanocomposite comprises an admixture of a polymeric matrix and a macrocycle.

An object of the present invention is to provide an exhaust gas purification catalyst including a wall-flow substrate and a catalyst layer, and having an improved exhaust gas purification performance, and, in order to achieve such an object, the present invention provides an exhaust gas purification catalyst including: a wall-flow substrate, first catalyst layers; and second catalyst layers; wherein the first catalyst layers and the second catalyst layers satisfy the following expressions (1) to (3):

L1<L2  (1)

T1<T2  (2)

WC1>WC2  (3)

wherein L1 represents the length of the first catalyst layers, L2 represents the length of the second catalyst layers, T1 represents the thickness of the rising portions of the first catalyst layers, T2 represents the thickness of the rising portions of the second catalyst layers, WC1 represents the mass of the first catalyst layers per unit volume of the portion of the substrate provided with the first catalyst layers, and WC2 represents the mass of the second catalyst layers per unit volume of the portion of the substrate provided with the second catalyst layers.

The present disclosure provides the exhaust gas purification catalyst with the improved purification performance under the high Ga condition and the transient state in which an A/F repeats rich and lean phases. The present disclosure relates to an exhaust gas purification catalyst comprising a catalyst coating layer on a substrate, the catalyst coating layer containing a noble metal, a composite oxide containing cerium oxide and zirconium oxide, and a composite oxide containing aluminum oxide, wherein in the catalyst coating layer: an average thickness of the coating layer is in a range from 20 μm to 100 μm; a porosity measured by a weight-in-water method is in a range from 50% by volume to 80% by volume; and high-aspect-ratio pores having an aspect ratio of 5 or more account for 0.5% by volume to 50% by volume of a whole volume of voids, the high-aspect-ratio pore having an equivalent circle diameter in a range from 2 μm to 50 μm in a cross-sectional image of a catalyst coating layer cross section perpendicular to an exhaust gas flow direction of the substrate and having an average aspect ratio in a range from 10 to 50, and wherein the noble metal is supported on peripheries of the voids, the composite oxide containing the cerium oxide and the zirconium oxide, and the composite oxide containing the aluminum oxide.

A system for removing methane oxidation catalyst (MOC) poisons from an exhaust gas including a methane abatement unit that may receive the exhaust gas having methane (CH.sub.4)and the MOC poisons. The methane abatement unit includes a guard bed that may remove the MOC poisons from the exhaust gas and may generate an intermediate exhaust gas having the CH.sub.4 and devoid of the MOC poisons. The guard bed includes a MOC poisons capturing component having a first transition metal oxide, an aluminum oxide (Al.sub.2O.sub.3) support material, and a dolomite-derived support material. The methane abatement unit also includes a MOC bed fluidly coupled to and positioned downstream from the guard bed. The MOC bed includes a MOC and may remove CH.sub.4 from the intermediate exhaust gas to generate a treated exhaust gas having less than approximately 200 parts per million volume (ppmv) CH.sub.4.

A small-pore zeolite that is modified with phosphorus, is excellent in hydrothermal durability, and has an 8-membered oxygen ring structure. The 8-membered oxygen ring structure is CHA, AEI, and AFX. The small-pore zeolite incudes at least an aluminum element, a silica element, a phosphorus element, wherein the phosphorus element is defined by expression (1), and the small-pore zeolite has an 8-membered oxygen ring structure being of CHA, AEI, or AFX. The phosphorus element that modifies the zeolite is unevenly distributed and richly contained on the surface layer side of the zeolite. A method for producing a phosphorus element-containing zeolite.

A porous carbon material composite formed of a porous carbon material and a functional material and equipped with high functionality. The porous carbon material composite is formed of (A) a porous carbon material obtainable from a plant-derived material having a silicon (Si) content of 5 wt % or higher as a raw material; and (B) a functional material adhered on the porous carbon material, and has a specific surface area of 10 m.sup.2/g or greater as determined by the nitrogen BET method and a pore volume of 0.1 cm.sup.3/g or greater as determined by the BJH method and MP method.

The present invention relates to a selective catalytic reduction catalyst for the treatment of an exhaust gas of a diesel engine comprising: a flow-through substrate comprising an inlet end, an outlet end, a substrate axial length extending from the inlet end to the outlet end and a plurality of passages defined by internal walls of the flow through substrate extending therethrough; a coating disposed on the surface of the internal walls of the substrate, wherein the coating comprises a non-zeolitic oxidic material comprising manganese and one or more of the metals of the groups 4 to 11 and 13 of the periodic table, and further comprises one or more of a vanadium oxide and a zeolitic material comprising one or more of copper and iron.

The structured catalyst for oxidation for exhaust gas purification includes a support having a porous structure constituted by a zeolite-type compound, and at least one type of oxidation catalyst that is present in the support and selected from the group consisting of metal and metal oxide, the support having channels that communicate with each other, and the oxidation catalyst being present in at least the channels of the support.