A process for treating effluent streams in a renewable transportation fuel production process is described. One or more of the sour water stream and an acid gas stream are treated directly in thermal oxidation section. The process allows the elimination or size reduction of a sour water stripper unit, waste water treatment plant, and sulfur recovery unit.

The present invention and embodiments thereof provide a process to separate ethylene products from impurities such as nitrogen, hydrogen, ethane, propane and isobutane without the need for distillation processes.

A method to purify a hydrocarbon gas with hydrogen sulfide as an impurity comprises: (a) charging a chamber with a bed of active-metal carbide of a predetermined mesh-size range; (b) conducting the hydrocarbon gas through the bed of active-metal carbide, forming additional hydrocarbon gas by reaction of the active-metal carbide and the hydrogen sulfide; and (c) filtering from the chamber the hydrocarbon gas without the hydrogen sulfide.

New formulation for pyrite scale removal from oil and gas wells and a method of pyrite scale removal are disclosed. The chemical formulation is composed of K.sub.2B.sub.4O.sub.7-4H.sub.2O, in a concentration of about 9-20 wt. % of the composition, preferably about 14 wt. % of the composition. The new formulation has the ability to dissolve pyrite without generation of the toxic H.sub.2S. Furthermore, the new formulation is cheaper and has very low corrosion rate compare to 15 wt. % HCl with corrosion inhibitor. The disclose method uses the disclosed new formulation to dissolve iron sulphide scale, performed at about 100-150° C. and about 500-2000 psi.

A subsea fluid processing system which receives a wellstream flow. The subsea fluid processing system includes a pressure control device which regulates a pressure of the wellstream flow, a gas-liquid separator unit which receives the wellstream flow downstream of the pressure control device and which provides a liquid stream and a gas stream, a first membrane separator which receives the gas stream and which provides a retentate stream and a permeate stream, a compressor which receives the permeate stream and which provides a compressed permeate stream, and a discharge cooler which receives the compressed permeate stream and which provides a cooled compressed permeate stream for injection into a subsurface reservoir. A density of the cooled compressed permeate stream is higher than a density of the compressed permeate stream.

Methods of preparing and using a metal-organic framework (MOF) are provided herein, including methods of using an MOF comprising a repeat unit of the formula [ML].sub.n, wherein M is a divalent metal ion and L is a ligand of the formula: ##STR00001##
The MOFs provided herein may be used in the separation of two or more molecules from each other. In some embodiments, the molecules are ethylene and ethane. In some embodiments, UTSA-280 may be synthesized from calcium oxide (CaO) or calcium hydroxide (Ca(OH).sub.2) and squaric acid (SA) through mechanochemical synthesis.

In some embodiments, the present disclosure pertains to methods of capturing CO.sub.2 from an environment by hydrating a porous material with water molecules to the extent thereby to define a preselected region of a plurality of hydrated pores and yet to the extent to allow the preselected region of a plurality of pores of the porous material to uptake gas molecules; positioning the porous material within a CO.sub.2 associated environment; and capturing CO.sub.2 by the hydrated porous material. In some embodiments, the pore volume of the hydrated porous material includes between 90% and 20% of the pre-hydrated pore volume to provide unhydrated pore volume within the porous material for enhanced selective uptake of CO.sub.2 in the CO.sub.2 associated environment. In some embodiments, the step of capturing includes forming CO.sub.2-hydrates within the pores of the porous material, where the CO.sub.2.Math.n/H.sub.2O ratio is n<4.

A method and system for manufacturing and using a self-supporting structure in processing unit for adsorption or catalytic processes. The self-supporting structure has greater than 50% by weight of the active material in the self-supporting structure to provide an open-celled structure providing access to the active material. The self-supporting structures, which may be disposed in a processing unit, may be used in swing adsorption processes and other processes to enhance the recovery of hydrocarbons.

There is an absorbent mixture usable for the removal of sour gases from gas mixtures. The mixture has at least one organic base having a pK.sub.b (in water) less than or equal to 3.2; at least one alcoholic solvent of general formula R(OH).sub.n having a boiling temperature above or equal to 100° C. at ambient pressure, wherein R is a linear or branched saturated alkyl group having a number of carbon atoms between 2 and 20 and n is a whole number varying between 1 and 20; an aprotic polar solvent having a dielectric constant ε at 25° C. greater than or equal to 30, a viscosity μ at 25° C. less than or equal to 14 cP, preferably less than or equal to 12 cP; and a boiling temperature at normal pressure equal to or above 130° C. There is also a process for the removal of sour gases using the absorbent mixture.

Disclosed are a heterogeneous zeolite membrane and a method of preparing the same, and more particularly a heterogeneous zeolite membrane that has CHA and DDR zeolite structures by growing seed particles into a crystal structure different from that of the zeolite membrane and can thus separate CO.sub.2/N.sub.2 and CO.sub.2/CH.sub.4 even under wet conditions, a method of preparing the same, and a method of capturing and removing carbon dioxide using the membrane.