A composition having the structure of formula I:
[R—Ar—(COOH).sub.2].sub.x[Ar—(COOH).sub.3].sub.2-xM.sub.3.sup.2+  (I)
is provided where M is Mn, Cu, Co, Fe, Zn, Cd, Ni, or Pt; R is a bromine, nitro, a primary amine, C.sub.1-C.sub.4 alkyl secondary amine, C.sub.1-C.sub.4 alkyl oxy, Br—(C.sub.1-C.sub.4 alkyl), NO.sub.2—(C.sub.1-C.sub.4 alkyl), a mercaptan, and reaction products of any of the aforementioned with acyl chlorides of the formulas: CH.sub.3(CH.sub.2).sub.mC(O)Cl, or CH.sub.3(CH(C.sub.1-C.sub.4 alkyl)CH.sub.2).sub.mC(O)Cl, or CH.sub.3(CH.sub.2).sub.m-Ph-(CH.sub.2).sub.pC(O)Cl, where Ph is a C.sub.6 phenyl or C.sub.6 phenyl with one or more hydrogens replaced with F, C.sub.1-C.sub.4 fluoroalkyl, or C.sub.1-C.sub.4 perfluoroalkyl; m is independently in each occurrence an integer of 0 to 12 inclusive; p is an integer of 0 to 36 inclusive, to form an amide, a thioamide, or an ester; Ar is a 1,3,5-modified phenyl, and 1.4>x>0. A process of synthesis thereof and the use to chemically modify a gaseous reactant are also provided.

A thermal desorption tube for chromatography and mass spectrometry analysis. The thermal desorption tube includes a sorbent and a plurality of focusing agents loaded at known, relative amounts onto the sorbent. Each focusing agent is a compound that chromatographically elutes within a retention time similar to a retention time of a target analyte and has a mass spectrum similar to a mass spectrum of the target analyte. The thermal desorption tube is configured to be further loaded with a sample having the target analyte.

An apparatus for removing a sulfur-containing compound, including: a sulfur-containing compound removing part of bringing a gas to be treated containing a sulfur-containing compound into contact with an oil-soluble sulfur-containing compound absorbing agent, so as to remove the sulfur-containing compound; and a mixing part of mixing a sulfur-containing compound absorbed agent resulted from having the sulfur-containing compound absorbed to the sulfur-containing compound absorbing agent, and a non-aqueous liquid.

An exhaust gas purification device includes an exhaust gas discharge unit having an exhaust gas passage, and a plurality of smoke purifying units. Each smoke purifying unit includes a smoke purifying module disposed outside of the exhaust gas discharge unit and including an elongated smoke purifying holder defining a channel, and at least one water spray pipe for spraying water into the channel. An exhaust gas capture module includes a first exhaust gas capture pipe communicating the exhaust gas passage with the channel and having a first smoke trap extending into the exhaust gas passage.

A composition having the structure of formula I:
[RAr(COOH).sub.2].sub.x[Ar(COOH).sub.3].sub.2-xM.sub.3.sup.2+(I)
is provided where M is Mn, Cu, Co, Fe, Zn, Cd, Ni, or Pt; R is a bromine, nitro, a primary amine, C.sub.1-C.sub.4 alkyl secondary amine, C.sub.1-C.sub.4 alkyl oxy, Br(C.sub.1-C.sub.4 alkyl), NO.sub.2(C.sub.1-C.sub.4 alkyl), a mercaptan, and reaction products of any of the aforementioned with acyl chlorides of the formulas: CH.sub.3(CH.sub.2).sub.mC(O)Cl, or CH.sub.3(CH(C.sub.1-C.sub.4 alkyl)CH.sub.2).sub.mC(O)Cl, or CH.sub.3(CH.sub.2).sub.m-Ph-(CH.sub.2).sub.pC(O)Cl, where Ph is a C.sub.6 phenyl or C.sub.6 phenyl with one or more hydrogens replaced with F, C.sub.1-C.sub.4 fluoroalkyl, or C.sub.1-C.sub.4 perfluoroalkyl; m is independently in each occurrence an integer of 0 to 12 inclusive; p is an integer of 0 to 36 inclusive, to form an amide, a thioamide, or an ester; Ar is a 1,3,5-modified phenyl, and 1.4>x>0. A process of synthesis thereof and the use to chemically modify a gaseous reactant are also provided.

A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.

A composition having the structure of formula I:
[RAr(COOH).sub.2].sub.x[Ar(COOH).sub.3].sub.2-xM.sub.3.sup.2+(I) is provided where M is Mn, Cu, Co, Fe, Zn, Cd, Ni, or Pt; R is a bromine, nitro, a primary amine, C.sub.1-C.sub.4 alkyl secondary amine, C.sub.1-C.sub.4 alkyl oxy, Br(C.sub.1-C.sub.4 alkyl), NO.sub.2(C.sub.1-C.sub.4 alkyl), a mercaptan, and reaction products of any of the aforementioned with acyl chlorides of the formulas: CH.sub.3(CH.sub.2).sub.mC(O)Cl, or CH.sub.3(CH(C.sub.1-C.sub.4 alkyl)CH.sub.2).sub.mC(O)Cl, or CH.sub.3(CH.sub.2).sub.m-Ph-(CH.sub.2).sub.pC(O)Cl, where Ph is a C.sub.6 phenyl or C.sub.6 phenyl with one or more hydrogens replaced with F, C.sub.1-C.sub.4 fluoroalkyl, or C.sub.1-C.sub.4 perfluoroalkyl; m is independently in each occurrence an integer of 0 to 12 inclusive; p is an integer of 0 to 36 inclusive, to form an amide, a thioamide, or an ester; Ar is a 1,3,5-modified phenyl, and 1.4>?>0. A process of synthesis thereof and the use to chemically modify a gaseous reactant are also provided.

The object of the disclosure is a portable oxygen supply device including an oxygen concentrator, at least one air inlet through which ambient air is transported into the oxygen supply device, one oxygen outlet through which enriched oxygen is transported from the oxygen supply device, one exhaust air outlet through which exhaust air is transported from the oxygen supply device, a gas line system which is fluidically connected to the at least one air inlet, the outlet and the oxygen concentrator, a power source, at least one pump and a housing, wherein all components of the oxygen supply device are arranged in or on the housing and wherein the air inlet has an intake nozzle through which the ambient air is sucked into the oxygen supply device. The oxygen supply device has a filter unit.

A thermal desorption tube for chromatography and mass spectrometry analysis. The thermal desorption tube includes a sorbent and a plurality of focusing agents loaded at known, relative amounts onto the sorbent. Each focusing agent is a compound that chromatographically elutes within a retention time similar to a retention time of a target analyte and has a mass spectrum similar to a mass spectrum of the target analyte. The thermal desorption tube is configured to be further loaded with a sample having the target analyte.

A method of using a metal organic framework (MOF) comprising a metal ion and an at least bidendate organic ligand to catalytically detoxify chemical warfare nerve agents including exposing the metal-organic-framework (MOF) to the chemical warfare nerve agent and catalytically decomposing the nerve agent with the MOF.