Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H.sub.2S, H.sub.2O, and CO.sub.2. Methods include capturing one or more of H.sub.2S, H.sub.2O, and CO.sub.2 from fluid compositions, such as natural gas.

Disclosed in the present invention are a pressure equalizing system for air separation purification, and a control method. The system comprises: a first air main pipe; a pressurizing gas pipeline, which is connected to the first air main pipe and used for receiving a pressurizing gas and delivering same to the first air main pipe; and a control valve, located on the pressurizing gas pipeline, and having a degree of opening regulated by the flow regulator, thereby regulating an air intake amount of the pressurizing gas pipeline. The present invention solves the problem of an air separation rectification process being affected when dry nitrogen is used for pressure equalization of an adsorber; in the switching process of entering an adsorption stage from a regeneration stage, pressurizing dry nitrogen used in a pressure equalizing step previously mixes with damp air from a main air compressor before entering the adsorber, such that the gas components flowing towards an air separation cold box remain substantially unchanged, in order to reduce disturbance in conditions of gas entering a rectification column to take part in rectification due to a gas component gradually changing from dry nitrogen to dry air in the prior art, thus stabilizing the process conditions of the air separation cold box.

A process gas treatment device for a process gas for treating a process material in a process apparatus and a method for treating process gas for the treatment of a process material in a process apparatus during a drying phase and a cooling phase.

Solid sorbents, and especially zeolites, are attractive candidates for CO.sub.2 direct air capture (DAC) and point source capture applications because of their potential for high selectivity, fast kinetics, and low energy CO.sub.2 capture cycles. A common issue with solid sorbents, including zeolites, is their low thermal conductivity, which makes them difficult to heat for regeneration without using complex and expensive heat transfer systems. This invention utilizes a modified TVSA process which utilizes the product CO.sub.2 gas itself as the heating medium for the adsorbent bed, alone or in conjunction with internal or external heaters. The use of CO.sub.2 as a heating medium allows efficient heating of the sorbent bed and enables high purity CO.sub.2 product.

An object of the present invention is to provide a gas refining apparatus which can produce a product gas with high purity and high yield at low cost and can produce a plurality of types of gas as a product gas without changing an adsorbent, and the present invention provides a gas refining apparatus (10) including a first derivation line (L3) connected to the second adsorption towers (2a, 2b) and through which the first gas flows, a second derivation line (L4) connected to the second adsorption towers (2a and 2b) and through which the second gas flows, a regeneration line (L5) connected to the first adsorption towers (1a, 1b), through which a regeneration gas for regenerating a first adsorbent in the first adsorption towers (1a, 1b) flows, and a pump (P) provided in the second derivation line (L4) and configured to desorb the second gas from a second adsorbent in the second adsorption towers (2a and 2b), and the regeneration line (L5) is connected to each of the first derivation line (L3) and the second derivation line (L4).

An information management system provided with a plurality of external devices able to send and receive information and a server configured to be able to communicate with the external devices. The external devices are configured to send to the server the amounts of CO.sub.2 recovery recovered by the vehicles provided with the CO.sub.2 recovery devices. The server is configured to add up and manage the amounts of CO.sub.2 recovery sent from the external device.

A dryer includes a dehumidification filter containing a temperature responsive material with an upper critical solution temperature, a fan sending gas through the dehumidification filter, a heater heating the dehumidification filter, and a controller controlling the fan and the heater and switching an operation mode of the fan and the heater between a drying mode and a regeneration mode, wherein, in the drying mode, an object to be dried is dried with the fan sending the gas through the dehumidification filter that is heated by the heater to temperature higher than or equal to the upper critical solution temperature, and in the regeneration mode, the dehumidification filter is regenerated with the fan sending the gas through the dehumidification filter at temperature lower than the upper critical solution temperature.

The invention relates to a method for regulating a unit for separating a gas stream, having P adsorbers, where P≥2, each following a PSA-type adsorption cycle with a phase time shift, the method involving the steps of operating the unit according to the nominal cycle when the required flow rate is equal to a nominal flow rate or optionally when the required flow rate is higher than the nominal flow rate, and operating the unit according to the reduced cycle when the required flow rate is lower than or equal to a predetermined flow rate, the predetermined flow rate being lower than the nominal flow rate.

A method for separating gaseous carbon dioxide from a gas mixture by cyclic adsorption/desorption using a sorbent material adsorbing said gaseous carbon dioxide, wherein the method comprises the following sequential and in this sequence repeating steps: (a) an adsorption step; (b) and isolating step; (c) injecting a stream of saturated or superheated steam and thereby inducing an increase in internal pressure of the reactor unit and an increase of the temperature of the sorbent from ambient atmospheric temperature to a temperature between 60 and 110° C., starting the desorption of CO2; (d) extracting at least the desorbed gaseous carbon dioxide from the unit and separating gaseous carbon dioxide from water by condensation in or downstream of the unit, while preferably still injecting; (e) bringing the sorbent material to ambient atmospheric pressure conditions and ambient atmospheric temperature conditions

Methods and apparatus may implement controlled generation of oxygen enriched air in an oxygen concentrator while implementing control that reduces pneumatic imbalance between the concentrator's canisters, such as dynamic pressure imbalance or other pneumatic characteristic. One or more controllers may regulate operation of a compressor that feeds a pressurised air stream to the concentrator's canisters. This may regulate speed of the compressor to a speed set point for generating the pressurised stream. The regulating may involve generating a compressor control signal having a characteristic parameter such as a power parameter. The controller(s) may operate valve(s) in a cyclic pattern so as to produce oxygen enriched air in an accumulator. A cycle of the cyclic pattern may include a plurality of phases, where each of the plurality of phases has a duration. The controller(s) may then generate a dynamic adjustment to the duration(s) based on an evaluation of the characteristic parameter.