The present invention and embodiments thereof provide a process to separate ethylene products from impurities such as nitrogen, hydrogen, ethane, propane and isobutane without the need for distillation processes.

The present invention addresses to the use of NaY zeolite with a Si/Al ratio >2.6 as a solid adsorbent in the process of removing H.sub.2S from natural gas through a PSA process. The described adsorbent has the capacity of removing H.sub.2S from natural gas from offshore exploration platforms, enabling in situ regeneration. The experimental development proved the high capacity of capturing H.sub.2S by the NaY zeolite in consecutive cycles of pressurization, adsorption, depressurization and purging. This capture capacity remains at 74.2% of the initial capacity, remaining stable in subsequent cycles. The structure of the material maintained crystallinity above 95% in use, in 15 consecutive cycles, allowing the reuse of the adsorbent for a prolonged period of operation, preventing the solid from being constantly changed, which is quite common in a non-regenerative process.

A temperature swing adsorption process for removing a target component from a gaseous mixture containing water and at least one side component, said process comprising: (a) at least one adsorption step, providing a target component-loaded adsorbent and at least one waste stream depleted of the target component; (b) a desorption step, comprising heating of the loaded adsorbent to a desorption temperature and providing a first output stream containing the desorbed target component; (c) a conditioning step; (d) at least one target component-releasing releasing step bringing the solid adsorbent to a temperature lower than said desorption temperature and providing at least one second output stream containing an amount of the target component and containing water; (e) separating water from said second output stream(s) and (f) subjecting the so obtained water-depleted stream(s) to said adsorption step or to at least one of said adsorption steps.

A temperature swing adsorption process for removing a target component from a gaseous mixture, the process being carried out in a plurality of reactors, wherein each reactor performs: (a) adsorption of the target component providing a loaded adsorbent and a waste stream; (b) heating of the loaded adsorbent and desorption of target component, providing an output stream; (c) cooling of the adsorbent; a rinse step (a1) before the heating (b), wherein the loaded adsorbent is contacted with a rinse stream containing the target component, producing a purge stream depleted of the target component; a purge step (b1) before the cooling (c), wherein the adsorbent is contacted with the purge stream provided by another reactor while performing the rinse step (a1), thus producing an output stream containing the target component, wherein the rinse stream comprises at least a portion of the output stream provided by another reactor while performing the purge step (b1).

The present invention and embodiments thereof provide a process to separate ethylene products from impurities such as nitrogen, hydrogen, ethane, propane and isobutane without the need for distillation processes.

Pressure swing adsorption process for reducing fluctuations in the flow rate of tail gas from the adsorption unit. The flow rate of the stream of blowdown gas is regulated responsive signals from a sensor measuring the pressure and/or flow rate of the tail gas comprising the blowdown gas and purge gas effluent before the tail gas is introduced into a surge vessel.

Provided are apparatus and systems for performing a swing adsorption process. In particular, the method and system involves swing adsorption processes and systems designed to lessen the temperature, pressure and product stream composition fluctuations in the adsorption step of a swing adsorption process, particularly involving preparation of the adsorption bed unit using feed stream cooling in conjunction with splitting the cooled feed stream to the adsorption bed units during adsorption steps while staggering the timing of back-to-back adsorption steps in the swing adsorption process. The process may be utilized for swing adsorption processes, such as rapid cycle TSA and/or rapid cycle PSA, which are utilized to remove one or more contaminants from a gaseous feed stream.

A piece of equipment commonly used in many petrochemical and refinery processes is a pressure swing adsorption (PSA) unit. A PSA unit may be used to recover and purify hydrogen process streams, such as from hydrocracking and hydrotreating process streams. Aspects of the present disclosure are directed to monitoring PSA unit processes for potential and existing issues, providing alerts, and/or adjusting operating conditions to optimize PSA unit life. There are many process performance indicators that may be monitored including, but not limited to, flow rates, chemical analyzers, temperature, and/or pressure. In addition, valve operation may be monitored, including opening speed, closing speed, and performance. The system may adjust one or more operating characteristics to decrease the difference between the actual operating performance in the recent and the optimal operating performance.

A temperature swing adsorption (TSA) process for removing a target component from a gaseous mixture, where the process is carried out in a plurality of reactors. Each reactor performs the following steps: an adsorption step wherein an input stream of said gaseous mixture is contacted with a solid adsorbent selective for said target component, producing a first waste stream depleted of the target component; a heating step for regeneration of the loaded adsorbent providing a first output stream containing the target component; and a cooling step of the regenerated adsorbent.

Pressure swing adsorption process for reducing fluctuations in the flow rate of tail gas from the adsorption unit. The flow rate of the stream of blowdown gas is regulated responsive signals from a sensor measuring the pressure and/or flow rate of the tail gas comprising the blowdown gas and purge gas effluent before the tail gas is introduced into a surge vessel.