Patent classifications
B01D2323/14
COMPOSITE MOLECULAR SIEVE MEMBRANE, PREPARATION PROCESS AND USE THEREOF
A composite molecular sieve membrane, preparation method and use thereof are provided in the embodiments. The composite molecular sieve membrane includes a support layer and a molecular sieve membrane layer, wherein the support layer is a high-porosity and porous ceramic which is made of nano- or submicron ceramic powder materials or ceramic material precursors prepared through an electrospinning process. The high-porosity and porous ceramic, is adjustable from 40% to 83%. The composite molecular sieve membrane of the embodiments uses the porous ceramic prepared through an electrospinning process as the support layer, and the support layer has a flat and continuous surface, high porosity, uniform and adjustable pore sizes, low-tortuosity pore channels, and high mechanical strength; the flux of the composite molecular sieve membrane is increased, besides, the seed crystals can attach effectively due to the fibrous pore channels of the support layer, ensuring the adhesion amount of seed crystals.
Membrane bundle layout having spacers
A membrane module comprising a hollow fiber membrane bundle with a longitudinal extent, a membrane bundle cross section and a first and a second bundle end, the bundle comprising a multitude of hollow fiber membranes extending between the first and the second bundle end, and also comprising, within the membrane bundle cross section, a proportion of threads which are arranged between the hollow fiber membranes and which keep the hollow fiber membranes apart. The arrangement of the threads between the hollow fiber membranes is such that at the first bundle end and/or at the second bundle end the hollow fiber membranes protrude beyond at least some of the threads, such that the hollow fiber membrane bundle has a smaller proportion of threads in a first and/or second end region, extending from the first and/or the second bundle end, than in a bundle region, located between the first and the second bundle end, which has a maximal proportion of threads, the length of the first end region and/or the length of the second end region being 1% to 45% of the bundle length.
Virus removal membrane and method for manufacturing virus removal membrane
A virus removal membrane includes cellulose, and a primary-side surface through which the protein-containing solution is to be applied and a secondary-side surface from which a permeate that has permeated the virus removal membrane is to be flowed, wherein a bubble point is 0.5 MPa or more and 1.0 MPa or less; and when a solution containing gold colloids having a diameter of 30 nm is applied through the primary-side surface to the virus removal membrane to allow the virus removal membrane to capture the gold colloids for measurement of brightness in a cross section of the virus removal membrane, a value obtained by dividing a standard deviation of a value of an area of a spectrum of variation in the brightness by an average of the value of the area of the spectrum of variation in the brightness is 0.01 or more and 0.30 or less.
LIGHT-DRIVEN FILTRATION ANTIBACTERIAL COMPOSITE MEMBRANE AND PREPARATION METHOD AND USE THEREOF
Disclosed are a light-driven filtration antibacterial composite membrane and a preparation method and use thereof. The method for preparing the light-driven filtration antibacterial composite membrane includes: mixing dichloromethane and N,N-dimethylformamide to obtain a first solution; adding PCL particles to the first solution, and stirring until being uniform to obtain an electrospinning solution; adding a ZIF-8 powder to the electrospinning solution, and ultrasonically dispersing for at least 1 hour to obtain a PCL/ZIF-8 spinning solution; spraying the PCL/ZIF-8 spinning solution onto a PPCL@PDA/TAEG men-blown membrane to obtain the light-driven filtration antibacterial composite membrane.
MEMBRANES FOR CONTAMINANT REMOVAL FROM NATURAL GAS AND METHODS FOR USE THEREOF
Disclosed is a method for removing hydrogen sulfide from natural gas. The method includes passing a natural gas feed including methane and hydrogen sulfide (H2S) through a membrane at normal operating conditions. The membrane is an asymmetric hollow fiber membrane or an asymmetric film composite membrane including a porous layer and a nonporous skin layer. The asymmetric hollow fiber membrane or the nonporous skin layer of the asymmetric film composite membrane plasticizes during the method by exposure to condensable gases with high critical temperature under the operating conditions. The membrane preferentially removes H2S over methane from the natural gas feed at a H2S/methane selectivity of from 7 to 40 when measured at 35° C. and 45 bar.
Separation Membrane and Methods of Preparation Thereof
A membrane for fluid species transport includes a porous substrate and a selective-transport layer comprising 2-D-material flakes. The porous substrate defines surface pores with dimensions larger than 2 microns, and the selective-transport layer coats the porous substrate and spans across the surface pores. The porous substrate can be contacted with a liquid or coating to fill or coat the surface pores of the porous substrate. Next, a 2-D-material-flake solution is deposited on the porous substrate. Evaporation of solvent from the deposited 2-D-material-flake solution forms the selective-transport layer.
HOLLOW-FIBER MEMBRANE AND HOLLOW-FIBER MEMBRANE MODULE
A hollow-fiber membrane according to an aspect of the present disclosure contains a polytetrafluoroethylene or a modified polytetrafluoroethylene as a main component and has an average outer diameter of 1 mm or less and an average inner diameter of 0.5 mm or less. In a measurement of a heat of fusion of the polytetrafluoroethylene or the modified polytetrafluoroethylene with a differential scanning calorimeter, when the polytetrafluoroethylene or modified polytetrafluoroethylene is subjected to a first step of heating from room temperature to 365° C., a second step of cooling from 365° C. to 350° C., maintaining the temperature, subsequently cooling from 350° C. to 330° C., and further cooling from 330° C. to 305° C., and a third step of cooling from 305° C. to 245° C. at a rate of −50° C./min and subsequently heating from 245° C. to 365° C. at a rate of 10° C./min, a heat of fusion from 296° C. to 343° C. in the third step is 30.0 J/g or more and 45.0 J/g or less.
ASYMMETRIC HYDROPHOBIC POLYOLEFIN HOLLOW FIBER MEMBRANE, PREPARING METHOD, AND USE OF THE SAME
An asymmetric hydrophobic polyolefin hollow fiber membrane includes a support layer and a separation layer, the separation layer including an outer surface, the outer surface including a quantity of first pores with a certain pore size; presence of the first pores facilitates an anesthetic gas such as sevoflurane and remifentanil to permeate through the hollow fiber membrane into the human blood, allowing for the patient to maintain sedated throughout a surgical process; meanwhile, the first pores facilitate reduction of dosage of the anesthetic in the surgery, thereby reducing surgical costs and avoid overdosage of the anesthetic causing secondary impairment to the patient; in addition, the hollow fiber membrane offers a long plasma permeation duration, a high tensile strength and a high elongation at break to satisfy application needs, particularly suitable for human blood oxygenation including anesthetic gas and the gas-liquid separation areas.
METHOD FOR SYNTHESIZING SUPPORTED MOLECULAR SIEVE MEMBRANE BY MICROWAVES
A method for synthesizing a supported molecular sieve membrane by microwaves includes the steps of aging, heating and synthesizing. The aging step is to make a support in contact with a synthetic liquid at 25° C. to 70° C. for 10 hours to 24 hours; the heating step is to raise a temperature of an aged system from an aging temperature to a synthesis temperature within 1 minute to 10 minutes; and the synthesizing step is to synthesize at 80° C. to 120° C. for 2 minutes to 15 minutes. The steps of heating and synthesizing are powered by microwaves.
MEMBRANES FOR MEMBRANE DISTILLATION DESALINATION TECHNOLOGY
The invention provides a method of producing multi-walled carbon nanotube blended polyvinylidene fluoride (MWCNTs/PVDF) membranes for membrane distillation (MD) treatment of saline water using non-solvent induced phase separation (NIPS), said method including mixing two solvents with different solubility parameters and the use of a dual coagulation bath system to control the formation of membrane pore structures and enhance surface hydrophobicity whereby blended PVDF membranes are produced for application in MD processes.