Described herein are separation articles such as, for example, films, membranes and the like separating at least one component from a gaseous mixture comprising two or more components comprising difluoromethane (HFC-32, CH.sub.2F.sub.2) and pentafluoroethane (HFC-125, C.sub.2F.sub.5H). The disclosed articles include a “selective layer” that is selectively permeable for the desired component to be separated from the gas mixture. The selective layer is composed of an amorphous fluorinated copolymer. Optionally, the article may include other layers which serve various purposes such as, for example, a porous support layer, a “gutter layer,” which allows the permeate gas to pass from the selective layer to the porous layer with minimal flow impedance, and a protective layer, which protects the selective layer from fouling. Each component of the separation articles described herein and methods for making and using the same are provided below.

An object of the present invention is to provide a porous hollow-fiber membrane having high strength while maintaining high pure-water permeation performance. A porous hollow-fiber membrane of the present invention is a porous hollow-fiber membrane including a fluororesin-based polymer, in which the porous hollow-fiber membrane has a columnar texture oriented in a longitudinal direction of the porous hollow-fiber membrane, and a molecular chain of the fluororesin-based polymer is oriented in the longitudinal direction of the porous hollow-fiber membrane.

Disclosed herein are asymmetric multilayer carbon molecular sieve (“CMS”) hollow fiber membranes and processes for preparing the membranes. The processes include simultaneously extruding a core dope containing a polymer and suitable nanoparticles, a sheath dope, and a bore fluid, followed by pyrolysis of the extruded fiber.

A process for producing nitrogen-rich air by feeding high temperature air at 150° C. or more to an air separation membrane module is described. After being placed at 175° C. for two hours, the air separation module exhibits a shape-retention ratio of 95% or more in one embodiment. The nitrogen-rich air can be fed to a fuel tank for an aircraft, for example.

A method of separating gas and a method of making a gas separation membrane. The method of separating gas includes flowing a gas stream through a membrane, in which the membrane comprises a crosslinked mixture of a poly(ether-b-amide) copolymer and an acrylate-terminated poly(ethylene glycol) according to formula (I) or formula (II); and separating the gas stream via the membrane. ##STR00001##
In formulas (I) and (II), each n is of from 2 to 30; and each R is independently —H or —CH.sub.3.

A fluid control device includes a support structure configured to be deployed to a selected location in a borehole, and a filtration medium disposed at the support structure and configured to filter a fluid, the filtration medium configured to be compacted from an initial shape to a compacted shape prior to deployment in the borehole. The filtration medium includes a first polymeric material configured to withstand a temperature at the selected location, the first polymeric material forming a porous structure including a plurality of fluid passages, and a second polymeric material including a shape memory polymer disposed within the fluid passages, the shape memory polymer configured to expand in the plurality of fluid passages and cause the filtration medium to expand in the borehole.

A polymer composite membrane, a method for fabricating same, and a lithium-ion battery including same are provided. The polymer composite membrane includes a porous base membrane and a heat-resistant layer covering at least one side surface of the porous base membrane, the heat-resistant layer includes a plurality of heat-resistant sub-layers sequentially stacked, and pore-blocking temperatures of the heat-resistant sub-layers are sequentially increased from inside to outside; each of the heat-resistant sub-layers includes at least one of a first heat-resistant polymer material and a second heat-resistant polymer material, and each of the heat-resistant sub-layers is separately configured as a fiber network structure; the melting point of the first heat-resistant polymer material is not less than 200° C.; and the melting point of the second heat-resistant polymer material is not less than 100° C.

The present disclosure relates to a micro or nano porous membrane composed of a stretched membrane of a fluororesin membrane, wherein the fluororesin membrane contains sintered bodies of a plurality of core-shell particles containing fluororesins, wherein the core-shell particles include cores and shells covering outer surfaces of the cores, wherein an average particle size of the core-shell particles before being sintered is greater than or equal to 100 nm and less than or equal to 1,000 nm, wherein a ratio of a volume of the shells to a volume of the cores in the core-shell particles before being sintered is greater than or equal to 2/98 and less than or equal to 50/50, wherein a fluororesin of the cores is a tetrafluoroethylene-hexafluoropropylene copolymer, a tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer or a combination thereof, and a fluororesin of the shells is polytetrafluoroethylene, and wherein a first heat of fusion of the fluororesins in the core-shell particles is less than or equal to 68 J/g.

The present invention relates to a nonwoven fabric for cabin air filter including a low melting point polyester fiber, in which the nonwoven fabric for cabin air filter includes a first polyester fiber containing a polyester resin having a melting point higher than 250° C. and a second polyester fiber containing a low melting point polyester resin having a softening point of 100 to 150° C., the first polyester fiber is a modified cross-sectional yarn having a roundness of 50 to 80%, the second polyester fiber includes a low melting point polyester resin which is formed from an acid component included of terephthalic acid or ester-forming derivatives thereof, and a diol component included of 2-methyl-1,3-propanediol, 2-methyl-1,3-pentanediol, and ethylene glycol, and the second polyester fiber contains illite particles, i.e., micaceous mineral, or a mixture of the illite particles and sericite particles, and silver-based inorganic antibacterial agent particles.

The present disclosure relates to an electrode system for measuring the concentration of an analyte under in-vivo conditions, comprising an electrode with immobilized enzyme molecules and a diffusion barrier that controls diffusion of the analyte from body fluid surrounding the electrode system to the enzyme molecules.