The present disclosure provides a control method for a rectification and purification system of electronic-grade chlorine trifluoride. A rectification device of electronic-grade chlorine trifluoride includes a two-stage cryogenic rectification device including a low-boiling column and a high-boiling column. An extraction agent is arranged in the two-stage cryogenic rectification device for further dissociating associated molecules of hydrogen fluoride and chlorine trifluoride to meet the requirements of electronic-grade chlorine trifluoride. The reflux ratio parameter stability of a vapor-liquid (chlorine trifluoride-hydrogen fluoride) phase equilibrium system can be effectively improved by a column plate temperature control method, thus realizing wide dynamic smooth running under various working conditions. The column plate temperature control method can achieve an effective separation of chlorine trifluoride and various impurity components by deep rectification technology, yielding electronic-grade chlorine trifluoride through purification.

A system and method for reducing a vapor temperature in a packed distillation column. Liquid is collected from a packed section of the packed distillation column in a liquid collector disposed below the packed section. A super-heated vapor is distributed from a vapor feed disposed below the packed section such that the super-heated vapor contacts the liquid of the liquid collector and reduces a temperature of the super-heated vapor.

The present disclosure discloses a multi-bubbling region column tray and a corresponding plate column. The multi-bubbling region column tray includes: at least two bubbling regions, provided with first openings for liquid and gas to be mixed and in contact with each other; and at least one non-side downcomer, including at least one hanging downcomer, where the hanging downcomer has a bottom part which includes one or more second openings allowing the liquid to flow toward a lower left side, and one or more third openings allowing the liquid to flow toward a lower right side; and the bottom part of the hanging downcomer is designed to separate the liquid flowing out from the one or more second openings and the liquid flowing out from the one or more third openings.

A distillation column including a plurality of alternating plates and spacers stacked in a z-direction is provided. The plates include a respective liquid channeling network on a top surface thereof, a respective vapor opening, and a respective descending ramp. The respective descending ramps abut a respective liquid feed location of the plate immediately below to form a continuous liquid channeling network. The respective vapor openings of adjacent plates are located on opposite sides of the distillation column and form a continuous S-shaped vapor channel defined by the plurality of alternating plates and spacers, and the respective vapor openings. Systems including such distillation columns and processes of distilling a fluid mixture are also provided.

A contact tray for use in a mass transfer or heat exchange column and having multiple baffles walls that cause the liquid flowing on an upper surface of a tray deck tray to change its direction of flow and narrow its flow path width and extend the length of the flow path when the liquid flows from an inlet area to an outlet on the tray deck. By narrowing the flow path, the volumetric flow rate of the liquid at any portion of the deck increases and reduces the opportunity for vapor entrainment of the liquid at low liquid flow rates. A downcomer extends downwardly from the outlet to receive liquid when it enters the outlet and then convey it downwardly to a discharge outlet located at a lower end of the downcomer. The downcomer includes an inclined or horizontal portion that causes the discharge outlet to be positioned beneath and in vertical alignment with the inlet area on the tray deck.

A system for producing ethanol comprises a rectifier column that receives a first process stream comprising from about 42% to about 60% ethanol, wherein the rectifier column purifies the first process stream to provide an ethanol product stream that is at least about 90% ethanol, and one or more evaporators configured to evaporate water from a second process stream, wherein the one or more evaporators generate vapor, and wherein at least a portion of the vapor supplies heat energy for separation of ethanol from water in the rectifier column.

The present disclosure discloses a multi-bubbling region column tray and a corresponding plate column. The multi-bubbling region column tray includes: at least two bubbling regions, provided with first openings for liquid and gas to be mixed and in contact with each other; and at least one non-side downcomer, including at least one hanging downcomer, where the hanging downcomer has a bottom part which includes one or more second openings allowing the liquid to flow toward a lower left side, and one or more third openings allowing the liquid to flow toward a lower right side; and the bottom part of the hanging downcomer is designed to separate the liquid flowing out from the one or more second openings and the liquid flowing out from the one or more third openings.

A method and system for membrane-assisted production of high purity concentrated dimethyl carbonate by the reaction of carbon dioxide and methanol is provided. Carbon dioxide is recovered from flue gas or other dilute streams from industrial processes by a membrane and subsequent conversion takes place to an intermediate methyl carbamate by reacting of carbon dioxide with ammonia and methanol. For high-purity carbon dioxide obtained by one of the carbon capture technologies or by a process (such as, for example, ethanol fermentation process) the membrane reactor is replaced with a catalytic reactor for direct conversion of carbon dioxide to methyl carbamate by reacting with ammonia and methanol. The methyl carbamate is further reacted with methanol for conversion to dimethyl carbonate. An integrated reactive distillation process using side reactors is used for facilitating the catalytic reaction in the subject method for producing high purity dimethyl carbonate.

A distillation column including a plurality of alternating plates and spacers stacked in a z-direction is provided. The plates include a respective liquid channeling network on a top surface thereof, a respective vapor opening, and a respective descending ramp. The respective descending ramps abut a respective liquid feed location of the plate immediately below to form a continuous liquid channeling network. The respective vapor openings of adjacent plates are located on opposite sides of the distillation column and form a continuous S-shaped vapor channel defined by the plurality of alternating plates and spacers, and the respective vapor openings. Systems including such distillation columns and processes of distilling a fluid mixture are also provided.

Distillation trays having improved efficiency and capacity are described. The improvement is accomplished with unique downcomer spout arrangements and bubble promoters which provide equal liquid distribution to all areas of the tray. The ratio of the open area of a contacting zone including part of a bubble promoter and associated deck zone over the open area of the downcomer spout zone on the adjacent tray for distributing liquid to the zone is essentially the same across the tray.