Systems and methods are provided for separation of CO.sub.2 from dilute source streams. The systems and methods for the separation can include use of contactors that correspond radial flow adsorbent modules that can allow for efficient contact of CO.sub.2-containing gas with adsorbent beds while also facilitating use of heat transfer fluids in the vicinity of the adsorbent beds to reduce or minimize temperature variations. In particular, the radial flow adsorbent beds can be alternated with regions of axial flow heat transfer conduits to provide thermal management. The radial flow structure for the adsorbent beds combined with axial flow conduits for heat transfer fluids can allow for sufficient temperature control to either a) reduce or minimize temperature variations within the adsorbent beds or b) facilitate performing the separation using temperature as a swing variable for controlling the working capacity of the adsorbent.

Systems and methods are provided for separation of CO.sub.2 from dilute source streams. The systems and methods for the separation can include use of contactors that correspond radial flow adsorbent modules that can allow for efficient contact of CO.sub.2-containing gas with adsorbent beds while also facilitating use of heat transfer fluids in the vicinity of the adsorbent beds to reduce or minimize temperature variations. In particular, the radial flow adsorbent beds can be alternated with regions of axial flow heat transfer conduits to provide thermal management. The radial flow structure for the adsorbent beds combined with axial flow conduits for heat transfer fluids can allow for sufficient temperature control to either a) reduce or minimize temperature variations within the adsorbent beds or b) facilitate performing the separation using temperature as a swing variable for controlling the working capacity of the adsorbent.

The present disclosure relates to a solid adsorbent for capturing carbon dioxide (CO.sub.2) from a gas stream comprising CO.sub.2, the solid adsorbent comprising an amine covalently bonded to a polymer resin (e.g., a polystyrene resin), wherein the solid adsorbent has a CO.sub.2 uptake capacity of greater than about 7 wt. % at a temperature of about 40° C., and wherein the solid adsorbent has a CO.sub.2 uptake capacity of less than about 1.5 wt. % at a temperature of about 100° C., as measured when the gas stream further comprises a concentration of the CO.sub.2 of about 4 vol. %, by volume of the gas stream.

The present disclosure relates to a solid adsorbent for capturing carbon dioxide (CO.sub.2) from a gas stream comprising CO.sub.2, the solid adsorbent comprising an amine covalently bonded to a polymer resin (e.g., a polystyrene resin), wherein the solid adsorbent has a CO.sub.2 uptake capacity of greater than about 7 wt. % at a temperature of about 40° C., and wherein the solid adsorbent has a CO.sub.2 uptake capacity of less than about 1.5 wt. % at a temperature of about 100° C., as measured when the gas stream further comprises a concentration of the CO.sub.2 of about 4 vol. %, by volume of the gas stream.

Disclosed are an activated carbon adsorption tower and a gas purification device. An activated carbon adsorption tower comprises an adsorption tower body (1), a gas inlet (2) and a gas outlet (3) arranged on the adsorption tower body (1); the adsorption tower body (1) is provided with an activated carbon passage (11), a swash plate (12) and a gas passage in communication with the gas inlet (2) and the gas outlet (3); the gas passage is separated by the swash plate (12) into a U shape or serpentine shape, making the gas passage pass through the same activated carbon passage (11) from the opposite direction at least once; and the activated carbon passage (11) is provided with flowing activated carbon inside and gas holes on the passage wall for communicating with the gas passages on both sides.

Disclosed are an activated carbon adsorption tower and a gas purification device. An activated carbon adsorption tower comprises an adsorption tower body (1), a gas inlet (2) and a gas outlet (3) arranged on the adsorption tower body (1); the adsorption tower body (1) is provided with an activated carbon passage (11), a swash plate (12) and a gas passage in communication with the gas inlet (2) and the gas outlet (3); the gas passage is separated by the swash plate (12) into a U shape or serpentine shape, making the gas passage pass through the same activated carbon passage (11) from the opposite direction at least once; and the activated carbon passage (11) is provided with flowing activated carbon inside and gas holes on the passage wall for communicating with the gas passages on both sides.

An apparatus includes a housing that defines a first zone, a second zone, a third zone, and a fourth zone. The apparatus includes an inlet, a first outlet, a second outlet, and a conveyor belt. The inlet is configured to receive a carbon dioxide-containing fluid in the first zone. The first outlet is configured to discharge a carbon dioxide-depleted fluid from the first zone. The second outlet is configured to discharge a carbon dioxide-rich fluid from the third zone. The conveyor belt passes through each of the zones. The conveyor belt includes a carbon dioxide sorbent. Within the first zone, the carbon dioxide sorbent is configured to adsorb carbon dioxide from the carbon dioxide-containing fluid to produce the carbon dioxide-depleted fluid. Within the third zone, the carbon dioxide sorbent is configured to desorb the captured carbon dioxide to produce the carbon dioxide-rich fluid.

An apparatus includes a housing that defines a first zone, a second zone, a third zone, and a fourth zone. The apparatus includes an inlet, a first outlet, a second outlet, and a conveyor belt. The inlet is configured to receive a carbon dioxide-containing fluid in the first zone. The first outlet is configured to discharge a carbon dioxide-depleted fluid from the first zone. The second outlet is configured to discharge a carbon dioxide-rich fluid from the third zone. The conveyor belt passes through each of the zones. The conveyor belt includes a carbon dioxide sorbent. Within the first zone, the carbon dioxide sorbent is configured to adsorb carbon dioxide from the carbon dioxide-containing fluid to produce the carbon dioxide-depleted fluid. Within the third zone, the carbon dioxide sorbent is configured to desorb the captured carbon dioxide to produce the carbon dioxide-rich fluid.

The direct air capture (DAC) systems and methods efficiently and economically regenerate a desiccant bed without adding any thermal energy and without requiring any pressurization or depressurization of the desiccant reactors. The methods leverage water concentration differences in stream flows, the water concentration profile across a desiccant bed, and, optionally, exothermic water adsorption. These three elements, working in combination, are referred to as “reverse dry flow regeneration” or a “reverse dry air swing” regeneration process. Systems and methods for reverse flow regeneration include those for CO.sub.2 DAC applications, but they are also applicable to point source carbon capture and other similar technologies that require initial gas dehydration before exposure to a hydrophilic material.

The direct air capture (DAC) systems and methods efficiently and economically regenerate a desiccant bed without adding any thermal energy and without requiring any pressurization or depressurization of the desiccant reactors. The methods leverage water concentration differences in stream flows, the water concentration profile across a desiccant bed, and, optionally, exothermic water adsorption. These three elements, working in combination, are referred to as “reverse dry flow regeneration” or a “reverse dry air swing” regeneration process. Systems and methods for reverse flow regeneration include those for CO.sub.2 DAC applications, but they are also applicable to point source carbon capture and other similar technologies that require initial gas dehydration before exposure to a hydrophilic material.