B01D53/8628

Phosphorus-doped tubular carbon nitride micro-nano material and application thereof in catalytic treatment of exhaust gas
11577229 · 2023-02-14 · ·

The invention discloses a phosphorus-doped tubular carbon nitride micro-nano material and application thereof in waste gas treatment. Melamine is partially hydrolyzed into cyanuric acid through a phosphorous acid-assisted hydrothermal method to form a melamine-cyanuric acid super molecular precursor; the center of the precursor starts to be pyrolyzed under heating calcination, and thus phosphorus-doped tubular carbon nitride is obtained; the phosphorus-doped tubular carbon nitride and sodium borohydride are mixed and subjected to low-temperature calcination in an inert gas atmosphere, and defect-modified phosphorus-doped tubular carbon nitride is obtained. The defect-modified phosphorus-doped tubular carbon nitride micro-nano material has a good photocatalytic effect on catalytic degradation of waste gas; besides, the production raw materials are abundant and easy to obtain, and the phosphorus-doped tubular carbon nitride micro-nano material is good in stability and recyclable and has application prospects in waste gas treatment.

CERIUM-TIN-BASED COMPOSITE OXIDE CATALYST FOR CATALYZING PURIFICATION OF NITROGEN OXIDE, PREPARATION METHOD AND APPLICATION THEREOF
20230042287 · 2023-02-09 ·

The present application relates to a cerium-tin-based composite oxide catalyst for catalyzing purification of a nitrogen oxide, a preparation method and an application thereof. The catalyst has the following chemical composition: a cerium-tin oxide and an M oxide, wherein the M is selected from any one of or a combination of at least two of P, Ti, Zr, V, Mn, Fe, Cu, Al, Si, Ni, Hf, Nb, Ta, Cr, Mo, W, or Re. According to the present application, a cerium-tin-based composite oxide catalyst having the characteristics such as high catalytic activity, high hydrothermal stability, excellent N.sub.2 generation selectivity, a wide operation temperature window, and adaptation to high space velocity reaction conditions is prepared by means of a non-toxic and harmless raw material and a simple method, and the present application is applicable to a device for catalyzing purification of a mobile source nitrogen oxide represented by diesel vehicle exhaust gas and a fixed source nitrogen oxide represented by flue gas from a coal-fired power plant.

Selective catalytic reduction catalyst composition

A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).

TRANSITION METAL/ZEOLITE SCR CATALYSTS

A method of converting nitrogen oxides in a gas to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a zeolite catalyst containing at least one transition metal, wherein the zeolite is a small pore zeolite containing a maximum ring size of eight tetrahedral atoms, wherein the at least one transition metal is selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Jr and Pt.

Method for in-situ generation of nanoflower-like manganese dioxide catalyst on filter material
11565241 · 2023-01-31 · ·

A method for in-situ generation of nanoflower-like manganese dioxide catalyst on filter material is provided. The method comprises: immersing a filter material in a solution containing sodium lauryl sulfate and nitric acid; first modifying the surface of the filter material by using the sodium lauryl sulfate so that a charge layer is wound around the surface of the filter material and tightly absorbs H.sup.+ in an acid solution; and then adding potassium permanganate as an oxidant to react with H.sup.30 on the surface of the filter material to generate nano flower-like manganese dioxide in situ on the surface of the filter material, so as to obtain a composite filter material having a denitration function.

VANADIUM PENTOXIDE-TUNGSTEN TRIOXIDE CATALYST SUPPORTED ON IRON ION-EXCHANGED TITANIUM DIOXIDE AND METHOD FOR REMOVING NITROGEN OXIDES USING THE SAME

The present invention pertains to: a vanadium pentoxide-tungsten trioxide catalyst supported on an iron ion-exchanged titanium dioxide; and a method for removing nitrogen oxides using the same. More specifically, the present invention pertains to: a deNO.sub.xing catalyst in which the iron ion-exchanged titanium dioxide is utilized as a support for the vanadium pentoxide and tungsten trioxide to drastically reduce the generation and emission of nitrous oxide; and a method for removing nitrogen oxides using the same.

Exhaust gas purifying catalyst

This exhaust gas purifying catalyst is provided with a substrate and a catalyst layer formed on a surface of the substrate. The catalyst layer contains zeolite particles that support a metal, and a rare earth element-containing compound that contains a rare earth element. The rare earth element-containing compound is added in such an amount that the molar ratio of the rare earth element relative to Si contained in the zeolite is 0.001 to 0.014 in terms of oxides.

Methods to produce zeolites with the GME topology and compositions derived therefrom

The present disclosure is directed to microporous crystalline aluminosilicate structures with GME topologies having pores containing organic structure directing agents (OSDAs) comprising at least one piperidinium cation, the compositions useful for making these structures, and methods of using these structures. In some embodiments, the crystalline zeolite structures have a molar ratio of Si:Al that is greater than 3.5.

Carbon-coated Nickel Oxide Nanocomposite Material, Preparation Method Therefor and Use Thereof

A carbon-coated nickel oxide nanocomposite material, its preparation, and application thereof are provided. The nanocomposite material contains carbon-coated nickel oxide nanoparticles having a core-shell structure including an outer shell that is a graphitized carbon film optionally doped with nitrogen and an inner core comprising nickel oxide nanoparticle(s). The nanocomposite material has a carbon content of from greater than 0 wt % to not greater than about 5 wt %, based on the weight of the nanocomposite material.

EXHAUST GAS PURIFICATION CATALYST COMPOSITION AND EXHAUST GAS PURIFICATION CATALYST
20220401923 · 2022-12-22 ·

An object of the present invention is to provide an exhaust gas purification catalyst composition and an exhaust gas purification catalyst, each of which includes a pyrochlore-type CeO.sub.2—ZrO.sub.2-based complex oxide having an improved oxygen storage capacity (particularly, an improved oxygen storage capacity after being exposed to a high temperature environment), and, in order to achieve the above-mentioned object, the present invention provides an exhaust gas purification catalyst composition and an exhaust gas purification catalyst, each of which contains a pyrochlore-type CeO.sub.2—ZrO.sub.2-based complex oxide that contains Y and Mg and thus exhibits an excellent oxygen storage capacity (particularly, an excellent oxygen storage capacity after being exposed to a high temperature environment).