A multi-functional composition of matter that is useful for injection into a flue gas stream to rapidly and efficiently remove mercury from the flue gas stream. The multi-functional composition of matter may include a fixed carbon sorbent and minerals, halogens in the form of halide salts, as well as other physical and chemical properties to enhance (1) the oxidation reaction kinetics for the oxidation of mercury species and (2) the mass diffusion kinetics of the mercury species.

A device for processing waste is described herein that comprises an ion generator, a furnace chamber, a heat exchanger, a pollution control system, and a chimney. The ion generator converts atmospheric air into an ionized gas and the furnace chamber thermally decays the waste by combining the waste with a product of an interaction of the ionized gas and heat generated by the furnace chamber. The heat exchanger cools the excess gas. A wet scrubber system removes heavy metals and/or acid gases from the cooled excess gas to generate scrubbed excess gas, and a fixed bed coke system detoxifies the scrubbed excess gas by converting carbon monoxide, water, and steam in the scrubbed excess gas to carbon dioxide and hydrogen, and removing remaining acid gas, a remaining heavy metal, and/or a remaining dioxin from the scrubbed excess gas. The chimney transfers remaining scrubbed excess gas out of the device.

The present disclose is directed to a method for controlling iodine levels in wet scrubbers, and, in particular, recirculating wet scrubbers by removing the iodine from the scrubbing solution, such as by using ion exchange, absorption, adsorption, precipitation, filtration, solvent extraction, ion pair extraction, and an aqueous two-phase extraction.

Disclosed are a catalyst for synergistic control of oxynitride and mercury and a method for preparing the same. The catalyst includes the following components by mass percentage: a carrier: TiO2 72%-98.6%, active components: V2O5 0.1%-5%, WO3 1%-10%, Cr2O3 0.1%-5% and Nb2O5 0.1%-5%, and a co-catalyst of 0.1%-3%. The present invention can be used for reducing the oxynitrides in a flue gas, meanwhile oxidizing zero-valent mercury into bivalent mercury and then controlling the reactions, has relatively high denitration performance and also has high mercury oxidation performance; compared with current commercial SCR catalysts, the mercury oxidation rate of the catalyst is improved to a great extent, which can adapt to the requirements for mercury removal in China's coal-fired power plants, the conversion rate of SO2/SO3 is relatively low, and the catalyst has a better anti-poisoning ability, and is a new catalyst with a low cost and high performance.

A method and apparatus for cleaning and recycling stack gas from coal-fired power plants, from natural or propane burning heating plants, or from cement kilns by using renewable catalysts of zeolite to separate pollutants into recyclable and reusable materials. The method reduces from the stack gas carbon monoxide (CO), carbon dioxide (CO.sub.2), nitrogen oxide (NOx), sulfur oxide (SOx) as well as halogens such as chloride and fluorides and trace metals particularly, mercury, lead, and zinc. The method and apparatus also result in production of fertilizer products by purging with gaseous or liquid nitrogen the zeolite beds through which the stack gas flows. The oxygen generated may be recycled to the burners in the plant.

The present disclosure relates to the technical field of industrial waste gas purification, in particular to a core-shell structured catalyst, a preparation method and use thereof. The present disclosure provides a core-shell structured catalyst including a metal oxide-molecular sieve as a core and porous silica (SiO.sub.2) as a shell, where the metal oxide-molecular sieve includes a molecular sieve and a metal oxide loaded on the molecular sieve, the metal oxide includes an oxide of a first metal and an oxide of a second metal, the first metal is Fe, Cu, Ti, Ni or Mn, and the second metal is Ce or La. The core-shell structured catalyst of the present disclosure can enable effective removal of HCN and AsH.sub.3 at the same time with a stable effect, and no secondary pollution.

Methods for treating an industrial byproduct, such as spent, granular, activated carbon, dredge spoils, or contaminated soils involve integrated steps to clean, concentrate, separate and/or otherwise collect hazardous and/or desired materials from such industrial byproducts. The cleaned, concentrated, separated, or collected materials may involve sufficient quantities to be useful to subsequent processors, raw materials, additives, and the like. Other treatment methods involve retaining the clean material stream at sufficient temperatures for sufficient time to separate and concentrate desired material for recovery therefrom, such as precious metals and rare earth elements.

A catalyst comprises a mixture of 95% vol. to 30% vol. of an activated carbon catalyst and from 5% vol. to 70% vol. of a filler material as well as a configuration of such a catalyst for the removal of SO.sub.2, heavy metals and/or dioxins form waste gas and liquids.

Chromium particulate emissions in flue gas can be reduced or minimized by incorporating a thin layer bed of a catalyst within the flue gas flow path of a furnace, boiler, or other furnace environment that includes Cr-containing surfaces. The thin layer bed of catalyst can correspond to, for example, a honeycomb monolith with catalyst supported on the monolith surface, so as to provide a high contact area while forcing all of the flue gas to pass through the catalyst bed. The honeycomb monolith structure and the depth of the bed can be selected to provide a reduced or minimized pressure drop across the catalyst bed, such as a pressure drop of 0.25 kPa (1.0 inches of water) or less. Exposing the Cr-containing flue gas to the thin layer catalyst bed can result in a treated flue gas with a lower content of Cr.

A multi-functional composition of matter that is useful for injection into a flue gas stream to rapidly and efficiently remove mercury from the flue gas streams, particularly at above average flue stream temperatures of about 340° F. or higher. The multi-functional composition of matter may include a fixed carbon content of at least about 20 wt. %, a mineral content of from about 20 wt. % to about 50 wt. %, a sum of micropore plus mesopore volume of at least about 0.20 cc/g, a micropore volume to mesopore volume ratio of at least about 0.7, and a tapped density of not greater than about 0.575 g/ml. These compositions may be further characterized by number of particles per gram of the composition of matter such that the composition may have at least about 0.8 billion particles per gram, or even as many as 1.5 billion particles per gram. These physical and chemical properties may enhance (1) the oxidation reaction kinetics for the oxidation of mercury species, (2) frequency of contact events, and (3) capture and sequestration of mercury, to achieve efficient mercury capture by the composition even in high temperature flue gas streams.