The disclosure provides a bifunctional composite membrane, a preparation method and use thereof, and a method for removing a plasticizer in liquor. The bifunctional composite membrane includes a supporting membrane and a dense layer which covers a surface of the supporting membrane, wherein the supporting membrane includes a filtering membrane and an adsorbent, and the adsorbent is dispersed in a pore structure of the filtering membrane.

There is provided a semi-permeable membrane comprising: at least two two-dimensional (2D) heterostructure layers of; and a polyelectrolyte layer between each 2D heterostructure layer of the at least two 2D heterostructure layers. There is also provided a method of preparing the membrane comprising: mixing a 2D heterostructure solution and a polyelectrolyte solution to form a mixture; and vacuum filtering the mixture onto a substrate to form the membrane.

An ion exchange membrane includes nanoparticulate hydrous manganese oxide, wherein, the ion exchangemembrane is selective for the passage of phosphate ion. Methods of preparing ion exchange membranes and methods of seprating phosate also are described.

A 3D nanopore device for characterizing biopolymer molecules includes a first selecting layer having a first axis of selection. The device also includes a second selecting layer disposed adjacent the first selecting layer and having a second axis of selection orthogonal to the first axis of selection. The device further includes an third electrode layer disposed adjacent the second selecting layer, such that the first selecting layer, the second selecting layer, and the third electrode layer form a stack of layers along a Z axis and define a plurality of nanopore pillars.

A 3D nanopore device for characterizing biopolymer molecules includes a first selecting layer having a first axis of selection. The device also includes a second selecting layer disposed adjacent the first selecting layer and having a second axis of selection orthogonal to the first axis of selection. The device further includes an third electrode layer disposed adjacent the second selecting layer, such that the first selecting layer, the second selecting layer, and the third electrode layer form a stack of layers along a Z axis and define a plurality of nanopore pillars.

A method for making a filter membrane includes: forming a polymer layer; applying a plurality of nanoparticles on the polymer layer, the nanoparticles being self-assembled to form a closed pack arrangement on the polymer layer; heating the nanoparticles such that a portion of the polymer layer contacting the nanoparticles is softened so that the nanoparticles are sunk into the polymer layer; and removing the nanoparticles from the polymer layer so that the polymer layer is formed with a plurality of pores penetrating the polymer layer and being arranged in a honeycomb pattern.

An article having a nanoporous membrane and a nanoporous graphene sheet layered on the nanoporous membrane. A method of: depositing a layer of a diblock copolymer onto a graphene sheet, and etching a minor phase of the diblock copolymer and a portion of the graphene in contact with the minor phase to form a nanoporous article having a nanoporous graphene sheet and a nanoporous layer of a polymer. A method of: depositing a hexaiodo-substituted macrocycle onto a substrate having a Ag(111) surface; coupling the macrocycle to form a nanoporous graphene sheet; layering the graphene sheet and substrate onto a nanoporous membrane with the graphene sheet in contact with the nanoporous membrane; and etching away the substrate.

A 3D nanopore device for characterizing biopolymer molecules includes a first selecting layer having a first axis of selection. The device also includes a second selecting layer disposed adjacent the first selecting layer and having a second axis of selection orthogonal to the first axis of selection. The device further includes an third electrode layer disposed adjacent the second selecting layer, such that the first selecting layer, the second selecting layer, and the third electrode layer form a stack of layers along a Z axis and define a plurality of nanopore pillars.

A method for preparing a SiO.sub.2-polyethersulfone conductive ultrafiltration membrane and the ultrafiltration membrane comprises hydrophilic CF cloth as the conductive membrane base, which provides an effective carrier for the preparation of a stable and efficient conductive membrane. After pretreatment, the silica solution was combined with the membrane via film scraping. Then phase catalysis and polymerization of PES onto the film obtained the final silica dioxide-polyethersulfone conductive ultrafiltration membrane. The silica solution was applied in the form of a coating on the hydrophilic CF cloth, in which silicon dioxide combined with the hydrophilic CF cloth, avoiding electrochemical interference. The modified hydrophilic CF cloth improved the hydrophilicity of the conductive film, with silica firmly attaching to PES and improving the stability of the SiO.sub.2-polyethersulfone conductive ultrafiltration membrane. After 8 cycles of reuse, the performance of the membrane remained stable.

Disclosed herein is a complex generator including a hydrophilic fiber membrane coated with an adsorption material. Electrical energy is generated in such a manner that the adsorption material is adsorbed onto a polar solvent in some region of the hydrophilic fiber membrane by asymmetrical wetting of the polar solvent for the hydrophilic fiber membrane.