A hydrogen-selective membrane including a metal leaf applied to a substrate. A system and method for fabricating a hydrogen-selective membrane, including applying a metal leaf to a substrate, annealing the metal leaf, applying a hydrogen-permeable metal to the annealed metal leaf on the substrate, and annealing the hydrogen-permeable metal and the annealed metal leaf to give an alloy of the hydrogen-permeable metal and the metal leaf. A system and method for repairing a hydrogen-selective membrane having defects including applying a metal leaf to an external surface of membrane material of the hydrogen-selective membrane, annealing the metal leaf and metal of the membrane material to form an alloy of the metal leaf and the metal to repair the defects.

A hydrogen permeable membrane device is provided that includes a porous ceramic layer having a material that includes zirconia, Yttria-stabilized zirconia (YSZ), /Al.sub.2O.sub.3, and/or YSZ /Al.sub.2O.sub.3, and a porous Pd film or porous Pd-alloy film deposited on the a mesoporous ceramic layer.

The invention relates to a metallic membrane for nitrogen separation, the method of making the membrane and methods of using the membrane. The invention also relates to a metallic membrane for disassociation of nitrogen and subsequent reaction with hydrogen to produce ammonia at moderate conditions compared to a conventional Haber-Bosch process.

Hydrogen generation assemblies, hydrogen purification devices, and their components, and methods of manufacturing those assemblies, devices, and components are disclosed. In some embodiments, the devices may include an insulation base having insulating material and at least one passage that extends through the insulating material. In some embodiments, the at least one passage may be in fluid communication with a combustion region.

Hydrogen generation assemblies, hydrogen purification devices, and their components, and methods of manufacturing those assemblies, devices, and components are disclosed. In some embodiments, the devices may include an insulation base having insulating material and at least one passage that extends through the insulating material. In some embodiments, the at least one passage may be in fluid communication with a combustion region.

A membrane arrangement for the permeative separation of a gas from gas mixtures has a porous, gas-permeable, metallic support substrate, a membrane formed on the support substrate and selectively permeable for the gas to be separated off. A ceramic, gas-permeable, porous, first intermediate layer is formed between the support substrate and the membrane and directly on the support substrate. A gastight, metallic coupling part is joined by a material-to-material bond to the support substrate. The support substrate and the coupling part are separated by a dividing line. The intermediate layer extends towards the coupling part over the gas-permeable surface of the porous support substrate at least to a distance of 2 mm from the dividing line and extends over the gastight surface of the coupling part by not more than 2 mm beyond the dividing line.

A transfer line between the outlet of a steam cracker and the inlet for the quench system has metallic or ceramic inserts having a pore size from about 0.001 to about 0.5 microns inside the line forming a gas tight barrier with the inner surface of the line and having a vent for the resulting gas tight pocket are used to separate H.sub.2, CH.sub.4, CO and CO.sub.2 from cracked gases reducing the load on the down-stream separation train of the steam cracker.

A transfer line between the outlet of a steam cracker and the inlet for the quench system has metallic or ceramic inserts having a pore size from about 0.001 to about 0.5 microns inside the line forming a gas tight barrier with the inner surface of the line and having a vent for the resulting gas tight pocket are used to separate H.sub.2, CH.sub.4, CO and CO.sub.2 from cracked gases reducing the load on the down-stream separation train of the steam cracker.

A transfer line between the outlet of a steam cracker and the inlet for the quench system has metallic or ceramic inserts having a pore size from about 0.001 to about 0.5 microns inside the line forming a gas tight barrier with the inner surface of the line and having a vent for the resulting gas tight pocket are used to separate H.sub.2, CH.sub.4, CO and CO.sub.2 from cracked gases reducing the load on the down-stream separation train of the steam cracker.

A method is provided for preparing a carbon monoxide resistant gold-alloy gas separation membrane system. A palladium layer is provided upon a surface of a tubular porous substrate, wherein the palladium layer has a mean surface roughness (Sa) of less than 2.5 microns, followed by submerging the tubular porous substrate within a solution of chloroauric acid or a salt thereof. A volume of hydrogen peroxide is periodically introduced into the solution while spinning the tubular porous substrate at a set rate and for a time period so as to deposit upon the palladium layer a gold layer of desired uniformity and a desired thickness.