A method for fractionating a liquid include contacting a liquid comprising at least one type of encapsulating particle with at least one mesoporous isoporous block copolymer material, wherein at least one component of the liquid is separated. A device for fractionating a liquid having encapsulating particles includes at least one mesoporous isoporous block copolymer material. The device can further include an inlet to allow the liquid to contact the mesoporous isoporous block copolymer material, and an outlet to allow passage of the fractionated liquid. In some instances, the device can be a pleated capsule, a flat sheet cassette, a spiral wound module, a hollow fiber module, a syringe filter, a microcentrifuge tube, a centrifuge tube, a spin column, a multiple well plate, a vacuum filter, a flat sheet, or a pipette tip.

Described herein are passive samplers, making of such samplers, and methods of use. In an example embodiment, a passive sampling membrane comprises, for example, a continuous mesoporous sequestration media having a sequestration phase and a support membrane configured to support the sequestration phase. The sequestration phase may include a hydrophobic region and a hydrophilic region. The continuous mesoporous sequestration media may be configured to simultaneously sequester polar and non-polar organic substances.

The present invention discloses stable composite membranes comprising a porous support having one or more thin selective layers coated on a top surface thereof, whereas at least one of said thin selective layers comprises a crosslinked fluorinated silicone polymer, and further wherein the total thickness of said one or more thin selective layers ranges between 0.1 to 10 microns. The use of these membranes in the process of olive oil wastewater treatment and the valorization of polyphenol-rich by-products, are also disclosed.