Patent classifications
B01J19/1837
Static mixer element and reactor comprising a static mixer element
A static mixer or a flow reactor comprising a static mixer for mixing streams of fluid transported through or circulated in a flow reactor is provided. A static mixer element reduces the size of gas bubbles in a liquid for installation in a flow channel, and comprises, a first mixer unit and a second and adjacent mixer unit, which mixer units are displaced relative to each other in the flow direction, such that a through opening in the first mixer unit at least partly faces a surface of the second mixer unit thereby forcing the fluid flow to change direction. Adjacent mixer units have substantially the same height or thickness, and are substantially parallel having a distance between them that may be near zero or up to 10 times the thickness of a mixer unit.
System and method for rapid dump tank heating
A method of operating a dump tank of a polymer production process by transferring all or a portion of a content of a polymerization reactor into the dump tank, wherein the reactor contents comprise solid polymer, and liquid and gaseous non-product components, and removing at least a portion of the liquid and gaseous non-product components from the dump tank by: reducing a pressure of the dump tank, subjecting the solid polymer to a first cleaning stage comprising heating the solid polymer by introducing a first heated treatment gas into the dump tank, and subjecting the solid polymer to a second cleaning stage comprising purging the solid polymer by introducing a second heated treatment gas into the dump tank.
Polymerization reactor system comprising at least one withdrawal valve
Described herein is a polymerization reactor system comprising at least one loop reactor and/or at least one transfer line, and further comprising at least one withdrawal valve, wherein the at least one withdrawal valve is mounted to a wall of a lower horizontal segment of the loop reactor and/or to a wall of the transfer line, at an angle a of more than 0° and equal to or less than 85°, determined from perpendicular to a tangent of the wall at the mounting position in flow direction of a slurry in the loop reactor and/or in the transfer line. The valve piston of the at least one withdrawal valve comprises a valve plate at an end directed to the at least one loop reactor and/or at an end directed to the at least one transfer line, the valve plate being shaped according to an inner wall of the at least one loop reactor and/or according to an inner wall of the at least one transfer line such that the valve piston is flush with the inner wall of the at least one loop reactor and/or with the inner wall of the at least one transfer line in a closed position of the withdrawal valve. By using such a withdrawal valve, a limitation of the effective withdrawal area can be avoided or at least be reduced such that the liquid slurry can efficiently be withdrawn and the risk of plugging is reduced. Further disclosed is a method for producing an olefin polymer in the inventive polymerization reactor system.
POLYMERIZATION PROCESS AND REACTOR FOR CONTROLLING MOLECULAR WEIGHT DISTRIBUTION AND COMONOMER COMPOSITION DISTRIBUTION
A reactor for the polymerization of olefins comprising a first inlet for introducing a first stream comprising monomer(s), catalyst(s) and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof, at least one outlet for withdrawing a product stream, characterized in that the reactor further comprises at least one second inlet for introducing a second stream comprising monomer(s), catalyst(s) and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof; and a process for polymerizing olefins in a reactor according to the present invention, comprising the steps of introducing monomer(s), catalyst(s), and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof as the first stream via the first inlet into the reactor forming a reaction mixture; polymerizing a polymer from the reaction mixture; withdrawing the product stream via the at least one outlet from the reactor; characterized in that the process comprises a further step of introducing a second stream comprising monomer(s), catalyst(s), and optionally hydrogen, solvent or comonomer(s) and/or mixtures thereof into the reactor via the at least one second inlet into the reactor.
Ethylene polymerization processes and reactor systems for the production of multimodal polymers using combinations of a loop reactor and a fluidized bed reactor
Polymerization processes and reactor systems for producing multimodal ethylene polymers are disclosed in which at least one loop reactor and at least one fluidized bed reactor are utilized. Configurations include a loop reactor in series with a fluidized bed reactor and two loop reactors in series with a fluidized bed reactor.
OPTIMIZED AGITATOR SYSTEM FOR PRODUCTION OF POLYOLEFIN
The various embodiments of the present invention relate to a polymerization reactor where the agitator mixing performance is optimized for use with a high activity catalyst and methods for developing the same.
Pressure relief for multiple polyolefin polymerization reactors
A polyolefin manufacturing system and method including polymerizing olefin in a first reactor to form a polyolefin, transferring the polyolefin to a second reactor, polymerizing olefin in the second reactor, and discharging a product polyolefin from the second reactor. The system and method including operating the first reactor with a first reactor pressure relief system and the second reactor with a second reactor pressure relief system, both pressure relief systems to discharge to a flare system, and wherein a relief instrumented system (RIS) is configured to direct at least one process interlock that mitigates an excess reaction scenario as an overpressure relief scenario.
System and method for seal flush
Techniques are provided for seal flush systems. A system may include a reactor circulation pump configured to circulate a slurry through a polymerization reactor. The slurry may include an olefin monomer, a catalyst, and a diluent. The system may also include a catalyst-inhibiting additive system configured to supply a catalyst-inhibiting additive to a seal of the reactor circulation pump and a seal flush system configured to generate a seal flush mixture and supply the seal flush mixture to the seal of the reactor circulation pump.
Continuous preparation of an optically active carbonyl compound by asymmetric hydrogenation
Process for the continuous production of an optically active carbonyl compound by asymmetric hydrogenation of a prochiral α,β-unsaturated carbonyl compound with hydrogen in the presence of a homogeneous rhodium catalyst that has at least one chiral ligand, wherein a liquid reaction mixture comprising the prochiral α,β-unsaturated carbonyl compound is subjected in a first, backmixed reactor to a gas/liquid two-phase hydrogenation, and the liquid reaction mixture is then further hydrogenated in a second reactor, wherein the prochiral α,β-unsaturated carbonyl compound is employed in the first reactor in a concentration from 3% to 20% by weight. The process allows a high total conversion to the prochiral α,β-unsaturated carbonyl compound.
System and method for closed relief of a polyolefin loop reactor system
A reactor system including an enclosed pressure relief system and/or a control system. The enclosed pressure relief system including a slurry separation system communicatively coupled with a pressure relief valve coupled to a loop reactor such that activation of the pressure relief valve results in discharge of a slurry from the loop reactor to the slurry separation system, wherein the slurry separation system is capable of separating solid and liquid components from gas components of the slurry and transmitting the gas components to a flare via a flare header.