A process for the production of syngas comprising the steps of providing a feed gas comprising a hydrocarbon, carbon dioxide and optionally steam, contacting a flow of said feed gas with a metal oxide to form syngas, wherein the mole fraction of carbon dioxide or in the case the feed gas comprises steam, the sum of the mole fractions of carbon dioxide and steam, in the feed gas is between 0.3 and 0.7; and/or wherein the mole fraction of the hydrocarbon in the feed gas is between 0.3 to 0.5, wherein the feed gas is contacted with the metal oxide at a temperature of between 1050K and 1600K.

A structured catalyst for catalyzing an endothermic reaction of a feed gas to convert it to a product gas is provided.

Systems and methods are provided for improving the operation of groups of reverse flow reactors by operating reactors in a regeneration portion of the reaction cycle to have improved flue gas management. The flue gas from reactor(s) at a later portion of the regeneration step can be selectively used for recycle back to the reactors as a diluent/heat transport fluid. The flue gas from a reactor earlier in a regeneration step can be preferentially used as the gas vented from the system to maintain the desired volume of gas within the system. This results in preferential use of higher temperature flue gas for recycle and lower temperature flue gas for venting from the system. This improved use of flue gas within a reaction system including reverse flow reactors can allow for improved reaction performance while reducing or minimizing heat losses during the regeneration portion of the reaction cycle.

Systems and methods are provided for hydrogenation of CO.sub.2 in a reverse flow reactor environment via a reverse water gas shift reaction. A reverse flow reactor environment is suitable for performing endothermic reactions at high temperatures, where a reactant flow is passed into the reactor in a first portion of the cycle in a first flow direction while a combustion or heating flow is passed into the reactor during a second portion of the reaction cycle from the opposite direction. This can allow for efficient heating of surfaces within the reactor to provide heat for the endothermic reverse water gas shift reaction while reducing or minimizing incorporation of combustion products into the desired reaction products.

Structured catalyst arranged for catalyzing an endothermic reaction of a feed gas, said structured catalyst comprising a macroscopic structure of electrically conductive material, said macroscopic structure supporting a ceramic coating, wherein said ceramic coating supports a catalytically active material, wherein the electrically conductive material at least partly is a composite in the form of a homogenous mixture of an electrically conductive metallic material and a ceramic material, wherein the macroscopic structure at least partly is composed of two or more materials with different resistivities.

A silicon carbide flow reactor fluidic module comprises a monolithic closed-porosity silicon carbide body, a tortuous fluid passage extending through the silicon carbide body, the tortuous fluid passage having an interior surface, and one or more thermal control fluid passages also extending through the silicon carbide body, the interior surface having a surface roughness of less than 10 μm Ra. A process for forming such modules is also disclosed.

Methods of heating a reactor system by providing electrical energy are described. A reactor system comprising at least one reactor tube having a catalyst disposed therein and comprises at least one electrically conductive surface is heated by providing electrical energy to the at least one electrically conductive surface on the reactor tube and adjusting a current level of the electrical energy provided to the at least one electrically conductive surface to control the temperature of the reactor tube and the catalyst disposed therein. The reactor tube may be electrically isolated from other electrically conductive components of the reactor system.

A reactor system and a process for carrying out steam cracking of a feed gas comprising hydrocarbons is provided, i where the heat for the reaction is provided by resistance heating by means of electrical power, so that a product stream comprising at least one olefin compound is obtained.

An electrically heating converter includes: a pillar shaped honeycomb structure made of conductive ceramics, including: an outer peripheral wall; and a partition wall disposed on an inner side of the outer peripheral wall, the partition wall defining a plurality of cells, each of the cells penetrating from one end face to other end face to form a flow path; metal electrodes; conductive connecting portions arranged on a surface of the pillar shaped honeycomb structure; and a pressing member configured to press the metal electrodes against the conductive connecting portions, so that the metal electrodes are electrically connected to the pillar shaped honeycomb structure. Each of the conductive connecting portions has an electrical resistivity lower than that of the pillar shaped honeycomb structure.

A reactor system and a process for carrying out the methanol cracking reaction of a feedstock comprising methanol to hydrogen are provided, where the heat for the endothermic methanol cracking reaction is provided by resistance heating.