Structured adsorbent beds comprising a high cell density substrate, such as greater than about 1040 cpsi, and a coating comprising adsorbent particles, such as DDR and a binder, such as SiO.sub.2 are provided herein. Methods of preparing the structured adsorbent bed and gas separation processes using the structured adsorbent bed are also provided herein.

A method and system for manufacturing and using a self-supporting structure in processing unit for adsorption or catalytic processes. The self-supporting structure has greater than 50% by weight of the active material in the self-supporting structure to provide an open-celled structure providing access to the active material. The self-supporting structures, which may be disposed in a processing unit, may be used in swing adsorption processes and other processes to enhance the recovery of hydrocarbons.

A process of removing methanol, CO.sub.2, or both from a hydrocarbon stream is described. The process uses an adsorbent comprising binderless type 3A zeolite. The adsorbent has high methanol removal capacity and low olefin co-adsorption capacity, as well as low reactivity in an olefin stream. This allows reduced adsorbent loading while maintaining downstream catalyst performance and product quality. The adsorbent comprises a type 3A zeolite comprising less than 5% of a binder and an ion exchange ratio of 30% to 70%. The adsorption process can obtain an outlet methanol content of 1 ppmw or less.

The present invention relates to a process for the calcination of a zeolitic material, wherein said process comprises the steps of (i) providing a zeolitic material comprising YO.sub.2 and optionally further comprising X.sub.2O.sub.3 in its framework structure in the form of a powder and/or of a suspension of the zeolitic material in a liquid, wherein Y stands for a tetravalent element and X stands for a trivalent element; (ii) atomization of the powder and/or of the suspension of the zeolitic material provided in (i) in a gas stream for obtaining an aerosol; (iii) calcination of the aerosol obtained in (ii) for obtaining a calcined powder; as well as to a zeolitic material obtainable and/or obtained according the inventive process, and to its use as a molecular sieve, as an adsorbent, for ion-exchange, as a catalyst, and/or as a catalyst support.

The present invention relates to a method for modifying the crystalline inorganic framework of an adsorbent with coatings to provide rate selectivity for one gas over others is described. The method described herein narrows the effective pore size of crystalline porous solids with pores less than about 5 Å for rate selective separations. This method of the invention comprises treating the hydrated or partially hydrated zeolite with a silicone derived binding agent followed by subsequent heat treatment. The additive content and treatment are adjusted to match effective pore size to specific separations. The superior adsorbent has the added convenience of bead forming simultaneously with pore modification as well as having the treatment result in the yielding of high crush strength products.

The present technology provides an adsorbent material that includes a silicate composition, wherein the silicate composition includes a crystalline phase; wherein the silicate composition may have an interconnected porous scaffold having a total mercury (Hg) pore volume of about 0.005 cc/g to about 0.25 cc/g for pores having a diameter of about 20-10,000 Å and a total nitrogen (N) pore volume of about 0.02 cc/g to about 0.1 cc/g for pores having a diameter of about 20-600 Å.

A preparation method of a granular adsorbent is provided, including the following: adding a pyrrole monomer to an acidic solution, and adding an oxidant as an initiator to allow a polymerization reaction of the pyrrole monomer to produce polypyrrole (PPy), where an adsorption material powder is added to a reaction system before, during, or immediately after the polymerization reaction, and a resulting mixture is thoroughly stirred; after the polymerization reaction is completed, filtering a resulting reaction system to obtain a filter cake, which is the granular adsorbent; or subjecting the resulting reaction system to centrifugal sedimentation to obtain the monolithic adsorbent. In the present disclosure, the pyrrole monomer is subjected to a polymerization reaction to generate PPy; before being tightly stacked, network structures of PPy wrap the adsorption material powder; and the granular adsorbent is formed through sedimentation and stacking.

Solid material having an open multiple and at least partially interconnected porosity, comprising an inorganic matrix made of a microporous and mesoporous geopolymer, in which at least partially interconnected open macropores delimited by sides or walls made of microporous and mesoporous geopolymer are defined, and particles of at least one solid compound different from the geopolymer being distributed in the macropores and/or in the sides or walls. Method for preparing said material. Method for separating at least one metal or metalloid cation from a liquid medium containing it, wherein said liquid medium is placed in contact with the material.

A sorbent structure that includes a continuous body in the form of a flow-through substrate comprised of at least one cell defined by at least one porous wall. The continuous body comprises a sorbent material carbon substantially dispersed within the body. Further, the temperature of the sorbent structure can be controlled by conduction of an electrical current through the body.

Provided are: a deodorizer that has high VOC-adsorbing performance and can exhibit deodorizing properties even in a case in which the deodorizer is kneaded into resin, a deodorizing processed product produced by using the deodorizer, and a method for producing the deodorizer. The deodorizer of the present invention is characterized by including a zeolite represented by the following Formula [1], in which the zeolite is obtained by producing a zeolite and then heating the produced zeolite at a temperature of from 120° C. to 250° C.: xNa.sub.2O.Al.sub.2O.sub.3.ySiO.sub.2.zH.sub.2O [1]. In Formula [1], x represents a positive number of from 0.5 to 5.0, y represents a positive number of from 80 to 150, and z represents a positive number of from 1 to 20.