Mesoporous poly (aryl ether ketone) articles are formed from blends of poly (aryl ether ketones) with pore forming additives by melt processing, and can be in the form of a monofilament, disc, film, microcapillary or other complex shapes. The method of formation provides for preparation of poly (aryl ether ketone) articles with high degree of surface area and uniform nanometer pore size. The preferred poly (aryl ether ketone)s are poly (ether ketone) and poly (ether ether ketone). The mesoporous articles formed by the method of the present invention are useful for a broad range of applications, including molecular separations and organic solvent filtration.

The invention provides separation media of substantially monodisperse populations of substantially spherical particles of polyarylketone polymers or of thio-analogues of such polymers, of selected sizes, and further provides containers, such as chromatographic columns and cartridges, containing substantially monodisperse populations of such particles.

The present disclosure concerns systems and sorbents for the removal of carbon dioxide from ambient air. In some aspects, the system includes a wind collector, a body and an outlet. The body has a monolith or platforms dispersed therein, surfaces of which are at least partially coated in a sorbent, such that passing ambient air that contacts the sorbent, thereby allowing for the removal of carbon dioxide therefrom. Sorbents of the present disclosure include substrates that are hybrids of a silica, optionally with a carbonaceous material, and an epoxy-modified aminopolymer.

Methods of passively sampling PFAS in the environment, PFAS sorbents, apparatus and systems (apparatus plus conditions) for sampling groundwater, porewater, and surface water are described.

The present disclosure relates to the recovery of an alkoxide catalyst used in a process depolymerizing a polyester to form a diacid or diester and a diol. The present disclosure also relates to the recovery of an alkoxide catalyst used in a process depolymerizing polyethylene terephthalate to form dimethyl terephthalate and mono ethylene glycol.

Carbon dioxide adsorbents are provided. The carbon dioxide adsorbents include a polymeric amine and a porous support on which the polymeric amine is supported. the polymeric amine consists of a polymer skeleton containing nitrogen atoms and branched chains bonded to the nitrogen atoms of the polymer skeleton. Each of the branched chains contains at least one nitrogen atom. the polymeric amine is modified by substitution of at least one of the nitrogen atoms of the polymer skeleton or the branched chains with a hydroxyl group-containing carbon chain.

A separation membrane, suitably for oil and water separation. The membrane including a porous substrate layer and an active layer arranged over at least a part of the substrate layer. The active layer includes a hydrophilic agent and a superhydrophilic agent. Also described is a method of producing the separation membrane and a drain valve comprising the membrane.

Sorptive gas separators can employ contactors having various sorbents blended together. The various sorbents used to make a blended sorbent contactor can be selected for their various physical and chemical properties, which will allow operators to customize formulations and structural configurations to obtain optimum performance of sorptive gas separators using blended sorbents.

Methods making a metal-organic framework extrudate in an extruder comprising the steps of: (a) mixing a metal-organic framework material with an extrusion aid to form a metal-organic framework extrudate mixture; and (b) extruding the metal-organic framework mixture in the extruder to produce the metal-organic framework extrudate where the pressure within the extruder is reduced between about 10% to about 55% when compared to pressure within the extruder when extruding the metal-organic framework material without the extrusion aid. The extrusion aid can be a liquid extrusion aid, a solid extrusion aid and/or a polymeric extrusion aid.

A gas-absorbing material that contains amino group-having polymer compound particles and fine particles having a primary particle diameter of 1000 nm or less is a gas-absorbing material having a markedly higher gas absorption/desorption speed. Here, as the polymer compound of the amino group-having polymer compound particles, for example, a (meth)acrylamide polymer can be used, and as the fine particles, for example, water-repellent inorganic particles or fluororesin particles can be used.