Patent classifications
B01J20/265
GRAFTED CROSSLINKED CELLULOSE
Grafted, crosslinked cellulosic materials include cellulose fibers and polymer chains composed of at least one monoethylenically unsaturated acid group-containing monomer (such as acrylic acid) grafted thereto, in which one or more of said cellulose fibers and said polymer chains are crosslinked (such as by intra-fiber chain-to-chain crosslinks). Some of such materials are characterized by a wet bulk of about 10.0-17.0 cm3/g, an IPRP value of about 1000 to 7700 cm2/MPa.Math.sec, and/or a MAP value of about 7.0 to 38 cm H2O. Methods for producing such materials may include grafting polymer chains from a cellulosic substrate, followed by treating the grafted material with a crosslinking agent adapted to effect crosslinking of one or more of the cellulosic substrate or the polymer chains. Example crosslinking mechanisms include esterfication reactions, ionic reactions, and radical reactions, and example crosslinking agents include pentaerythritol, homopolymers of the graft species monomer, and hyperbranched polymers.
Preparation method and application for a resin-based iron oxide-containing composite phosphate removal adsorbent
A preparation method of a resin-based iron oxide-containing composite phosphate removal adsorbent is provided. An alkaline anion resin is taken as a base, a potassium ferrate is used as an iron source, and a characteristics of ferrate ions easily adsorbed on a surface of the anion resin are utilized to prepare resin-based iron oxide-containing composite phosphate removal adsorbent by one-step in-situ hydrolysis precipitation, compared with the related art, a preparation process of the disclosure is relatively simpler, a time period is shorter, and a production cost is lower. It has a strong ability to eliminate interference from other anions in the waste effluents, and it has a strong adsorption capacity, fast adsorption speed and large adsorption capacity for the phosphate. Moreover, it has the advantages of strong regeneration ability and multiple repeated use times.
SUPERABSORBENT MATERIAL ABSORBENT CAPACITY INCREASE WITH USE OF SELECTED SALTS
The present invention discloses a method for increasing absorbent capacity of a superabsorbent material (SAM) by treating the SAM with a selected salt or a combination of such salts. The selected salt(s) may interact with the polymer chain of the SAM through one or more absorbent capacity enhancement mechanisms. The absorbent capacity enhancement mechanism(s) between selected salt(s) and the SAM may lead to greater absorbent capacity of the SAM.
Grafted crosslinked cellulose
Grafted, crosslinked cellulosic materials include cellulose fibers and polymer chains composed of at least one monoethylenically unsaturated acid group-containing monomer (such as acrylic acid) grafted thereto, in which one or more of said cellulose fibers and said polymer chains are crosslinked (such as by intra-fiber chain-to-chain crosslinks). Some of such materials are characterized by a wet bulk of about 10.0-17.0 cm3/g, an IPRP value of about 1000 to 7700 cm2/MPa.Math.sec, and/or a MAP value of about 7.0 to 38 cm H2O. Methods for producing such materials may include grafting polymer chains from a cellulosic substrate, followed by treating the grafted material with a crosslinking agent adapted to effect crosslinking of one or more of the cellulosic substrate or the polymer chains. Example crosslinking mechanisms include esterfication reactions, ionic reactions, and radical reactions, and example crosslinking agents include pentaerythritol, homopolymers of the graft species monomer, and hyperbranched polymers.
Solid extracting agent with high dynamic exchange capacity for extraction of scandium and method of its production
- Dmitrii Alekseevich Kondrutskii ,
- Vladimir Nikolaevich Rychkov ,
- Evgenii Vladimirovich Kirillov ,
- Sergey Vladimirovich Kirillov ,
- Grigory Mikhailovich Bunkov ,
- Evgenii Sergeevich Vostrov ,
- Vitalii Aleksandrovich Tretiakov ,
- Gadzhi Rabadanovich Gadzhiev ,
- Nikolai Anatolevich Poponin ,
- Denis Valerevich Smyshliaev
The invention relates to a composition and method for producing a solid extracting agent for extraction of scandium from sulfuric acid solutions. There is provided a solid extracting agent (Solex) for extraction of scandium from scandium-containing solutions comprising a styrene-divinylbenzene matrix with di-(2-ethylhexyl) phosphoric acid. The extracting agent further comprises tri-n-octylphosphine oxide, tributyl phosphate, isododecane, in the following ratio of components, wt. %: di-(2-ethylhexyl) phosphoric acid 32.0-37.5, tri-n-octylphosphine oxide 4.2-8.0, tributyl phosphate 0.8-1.7, isododecane 16.7-20.0, the remainder styrene-divinylbenzene, with the styrene/divinylbenzene ratio in the matrix equal to 75-80 to 20-25 wt. %. There is also provided a method of producing the Solex. The technical result is the production of a scandium-selective Solex with a high dynamic exchange capacity.
Amidoxime Functionalized Polymers Loaded with Alkyl Amines, Methods of Making, And CO2 Capture Using Same
A novel adsorbent and contactor material based on polymer functionalized with amidoxime and alkylamines moieties. Methods of making the material are also described. The material can be easily processed into any desired sorbent geometry such as solid fibers, electrospun fibers, hollow fibers, monoliths, etc. The adsorbent exhibits a very high affinity toward acidic gases such CO.sub.2 and can be used in direct air capture, power plant-based CO.sub.2 capture, and industrial CO.sub.2 capture applications. The material can also serve as a contactor that accommodates other adsorbents within its structure.
BLOOD TREATMENT MATERIAL
A blood treatment material adsorbs and removes blood components such as activated leukocytes and inflammatory cytokines with a high efficiency. The blood treatment material includes a water-insoluble material in the form of fibers or particles, wherein the difference between the maximum value (RaA) and the minimum value (RaB) of the arithmetic average roughness (Ra) of the surface of the water-insoluble material, as calculated using a laser microscope, is from 0.30 to 1.50 μm.
Sea-island composite fiber, carrier for adsorption, and medical column provided with carrier for adsorption
An object of the present invention is to provide a ligand-immobilized sea-island composite fiber in which generation of fine particles due to peeling of a sea component from an island component and generation of fine particles due to destruction of a fragile sea component are both suppressed. The present invention provides a sea-island composite fiber comprising a sea component and island components, in which a value (L/S) obtained by dividing the average total length (L) of the perimeter of all island components in a cross section perpendicular to the fiber axis by the average cross-sectional area (S) of the cross section is from 1.0 to 50.0 μm.sup.−1, a distance from the surface to the outermost island component is 1.9 μm or less, and an amino group-containing compound is covalently bonded to a polymer constituting the sea component at a charge density of 0.1 μmol or more and less than 500 μmol per 1 gram dry weight.
NANONETS FOR REMOVAL OF CONTAMINANTS FROM AQUEOUS SOLUTIONS, KITS THEREFOR AND METHODS OF THEIR USE
Provided are nanonets comprising a) a surfactant aggregate having an average aggregate diameter; and b) a polymer having an average particle diameter which average particle diameter is the same or smaller than the average aggregate diameter, wherein the nanonet has a diameter larger than the average particle diameter. Also provided are kits therefor and methods for sequestering non-water moieties from aqueous solutions using nanonets.
ABSORBENT RESIN PARTICLES AND ABSORBENT
The present disclosure relates to water-absorbent resin particles in which a contact angle of 0.9% by mass saline at 25° C.±2° C. is 100 degrees or larger, and an absorbent material containing the water-absorbent resin particles.