The present invention relates to the field of solid materials for the adsorption of lithium. In particular, the present invention relates to a novel process for preparing a solid crystalline material formed preferably in extrudate form, of formula (LiCl).sub.x.2Al(OH).sub.3,nH.sub.2O with n being between 0.01 and 10, x being between 0.4 and 1, comprising a step a) to precipitate boehmite under specific conditions of temperature and pH, a step to place the precipitate obtained in contact with a specific quantity of LiCl, at least one forming step preferably via extrusion, said process also comprising a final hydrothermal treatment step, all allowing an increase in lithium adsorption capacity and in the adsorption kinetics of the materials obtained compared to prior art materials, when used in a process to extract lithium from saline solutions.

It is an object of the present invention to provide a filter which remove acidic gas in the atmosphere with high efficiency and has excellent water resistance. A filter comprising: an aluminium substrate; and an adsorption layer on a surface of the aluminium substrate, wherein the adsorption layer contains activated carbon, a manganese oxide, and an acrylic resin having a pH of 3.0 to 6.5.

Structured adsorbent beds comprising a high cell density substrate, such as greater than about 1040 cpsi, and a coating comprising adsorbent particles, such as DDR and a binder, such as SiO.sub.2 are provided herein. Methods of preparing the structured adsorbent bed and gas separation processes using the structured adsorbent bed are also provided herein.

A cylindrical column-shaped honeycomb adsorbent has a plurality of cell passages extending along an axial direction of the honeycomb adsorbent. The plurality of cell passages are configured so that a pitch of adjacent cell passages is within a range of 1.5 mm˜1.8 mm, and so that a thickness of a wall between the cell passages is within a range of 0.45 mm˜0.60 mm. With this configuration, the honeycomb adsorbent exhibits BWC (Butane Working Capacity) of 6.5 g/dL or greater. By mixing fibrous meltable core melting away during baking, the honeycomb adsorbent has macropores configured to have a volume of 0.15 mL/g˜0.35 mL/g with respect to an overall weight of the honeycomb adsorbent and metal oxide particles having a proportion of weight of 150˜250% with respect to the activated carbon.

A method and system for manufacturing and using a self-supporting structure in processing unit for adsorption or catalytic processes. The self-supporting structure has greater than 50% by weight of the active material in the self-supporting structure to provide an open-celled structure providing access to the active material. The self-supporting structures, which may be disposed in a processing unit, may be used in swing adsorption processes and other processes to enhance the recovery of hydrocarbons.

The present disclosure provides a method for preparing a high cohesive energy adsorbent for fluoride removal, which includes the following steps: S1. adding NaHF.sub.2—NiF.Math.6H.sub.2O additive to SiCO ceramic powder, and sintering at a temperature of 310-330° C. for 18-22h to obtain a sintered substance; S2. grinding the sintered substance to obtain particles with a size of 2-3 mm, and mixing the particles with polyacrylonitrile to form a composite polymer; and S3. molding the composite polymer by a vacuum baking process at a temperature of 75-85° C., then performing ball milling and sieving to obtain the high cohesive energy adsorbent for fluoride removal. The high cohesive energy adsorbent for fluoride removal may be used in the adsorption and separation of the C.sub.2F.sub.6—CHF.sub.3—CClF.sub.3 mixture system, and the contents of CHF.sub.3 and CClF.sub.3 are lowered to less than 10ppmv.

A composition is provided that has heat resistance sufficient for use as a hydrocarbon adsorbent and desorbs hydrocarbons slowly with respect to an increase in temperature. The composition includes an alkali metal and a zeolite having a YFI structure. A content of the alkali metal is 1 to 40 mass% based on a total mass of the composition, and a content of the zeolite having a YFI structure is 99 to 60 mass% based on the total mass of the composition.

Methods making a metal-organic framework extrudate in an extruder comprising the steps of: (a) mixing a metal-organic framework material with an extrusion aid to form a metal-organic framework extrudate mixture; and (b) extruding the metal-organic framework mixture in the extruder to produce the metal-organic framework extrudate where the pressure within the extruder is reduced between about 10% to about 55% when compared to pressure within the extruder when extruding the metal-organic framework material without the extrusion aid. The extrusion aid can be a liquid extrusion aid, a solid extrusion aid and/or a polymeric extrusion aid.

The present invention provides a gas adsorbent comprising a number of microspheres formed by agglomeration of zeolite and adhesive. Among the plurality of microspheres, at least some of the microspheres have a porous structure and contain inflatable balls inside. In the present invention, the high molecular polymer expansion ball is added into the zeolite microsphere, and more pore structures are created in the zeolite microsphere by utilizing its characteristics of expansion, solidification and rupture at different temperatures. Thus, the adsorption capacity of the zeolite microsphere to air is increased to achieve a better frequency reduction effect.

The present invention concerns a zeolitic adsorbent agglomerate comprising at least one zeolite of faujasite type comprising sodium and/or lithium and/or calcium, and/or barium and/or potassium, of porosity between 25% and 45%, and having a standard deviation σ of crystal size distribution in said agglomerate of less than 0.30 μm. The invention also concerns the use of the zeolitic adsorbent agglomerate to separate hydrocarbon mixtures, and the process to separate hydrocarbon mixtures using said zeolitic adsorbent agglomerate.