The present disclosure concerns systems and sorbents for the removal of carbon dioxide from ambient air. In some aspects, the system includes a wind collector, a body and an outlet. The body has a monolith or platforms dispersed therein, surfaces of which are at least partially coated in a sorbent, such that passing ambient air that contacts the sorbent, thereby allowing for the removal of carbon dioxide therefrom. Sorbents of the present disclosure include substrates that are hybrids of a silica, optionally with a carbonaceous material, and an epoxy-modified aminopolymer.

Sorptive gas separators can employ contactors having various sorbents blended together. The various sorbents used to make a blended sorbent contactor can be selected for their various physical and chemical properties, which will allow operators to customize formulations and structural configurations to obtain optimum performance of sorptive gas separators using blended sorbents.

A DAC method as well as a unit containing an adsorber structure having an array of adsorber elements with a support layer and on both sides thereof a sorbent layer (1, 2), wherein the adsorber elements are parallel and spaced apart forming parallel fluid passages for flow-through of ambient atmospheric air and steam. The method involves the following sequential and repeating steps: (a) adsorption by flow-through; (b) isolating the sorbent; (c) injecting a stream of saturated steam through the parallel fluid passages and inducing an increase of the temperature; (d) extracting desorbed carbon dioxide from the unit and separating it from steam; (e) bringing the sorbent material to ambient temperature conditions wherein in step (a) the speed of the air is in the range of 2-8 m/s, and wherein at least in step (d) the speed of the steam is at least 0.2 m/s.

A system and a method for continuously separating carbon dioxide from gas mixtures, utilizing a continuous loop of porous monoliths which support a sorbent within its pores. Continuously exposing a portion of the continuous loop of monoliths to a flow of gas mixture containing a minor proportion of carbon dioxide, to adsorb carbon dioxide from the flow. The loop passes through a sealed regeneration and carbon dioxide capture assembly located astride a portion of the loop, and which is capable of sealingly containing a monolith in relative movement through the assembly. The assembly chamber comprises a plurality of separately sealed zones, including at least one zone for purging oxygen from the monoliths, -a subsequent zone for heating the monolith to release the adsorbed carbon dioxide, and another cooling zone for cooling the monolith prior to reentering the adsorption portion of the loop where it is exposed to oxygen.

A method for reducing the concentration of amines in a wash liquid stream exiting a wash section in an acid gas scrubbing process includes introducing the wash liquid stream exiting the wash section of the acid gas scrubbing process to an adsorbent material, wherein the wash liquid stream has a first concentration of amines. The wash liquid stream having the first concentration of amines is flowed through the adsorbent material, and the adsorbent material retains at least a portion of the amines thereby providing a wash liquid stream having a second, reduced concentration of amines. The wash stream with reduced concentration of amines is recycled back to the wash section to remove amines more effectively from the acid gas being scrubbed. The adsorbent material can be regenerated for reuse. Amine recovered from the regenerated adsorbent material can be recycled to the process for reuse.

An adsorption material is disclosed that comprises a metal-organic framework and a plurality of ligands. The metal-organic framework comprising a plurality of metal ions. Each respective ligand in the plurality of ligands is amine appended to a respective metal ion in the plurality of metal ions of the metal-organic framework. Each respective ligand in the plurality of ligands comprises a substituted 1,3-propanediamine. The adsorbent has a CO.sub.2 adsorption capacity of greater than 2.50 mmol/g at 150 mbar CO.sub.2 at 40° C. Moreover, the adsorbent is configured to regenerate at less than 120° C. An example ligand is diamine 2,2-dimethyl-1,3-propanediamine. An example of the metal-organic framework is Mg.sub.2(dobpdc), where dobpdc.sup.4− is 4,4′-dioxidobiphenyl-3,3′-dicarboxylate. Example applications for the adsorption material are removal of carbon dioxide from flue gas and biogasses.

A process for altering the composition of a feed gas containing H.sub.2S equivalents is disclosed. The process comprises (a) contacting the feed gas with a solid adsorbent at a temperature of 250-500° C., to obtain a loaded adsorbent, (b) purging the loaded adsorbent with a purge gas comprising steam, thus producing a product stream which typically contains substantially equal levels of CO.sub.2 and H.sub.2S. The process further comprises a step (c) of regenerating the purged adsorbent by removal of water. The adsorbent comprises alumina and one or more alkali metals, such as potassium oxides, hydroxide or the like.

A carbon dioxide adsorbent including silica gel and an amine compound carried by the silica gel. The silica gel has a spherical shape, a particle size ranging from 1 mm to 5 mm inclusive, an average pore diameter ranging from 10 nm to 100 nm inclusive, a pore volume ranging from 0.1 cm.sup.3/g to 1.3 cm.sup.3/g inclusive, and a waterproof property N that is defined by an expression (1) and that is not lower than 45%,

N=(W/W.sub.0)×100  (1) where N is the waterproof property in percentage (%) of the silica gel, W.sub.0 is a total number of particles of the silica gel immersed in water, W is a number of particles of the silica gel not subjected to breakage out of W.sub.0.

The disclosure generally relates to CCS sorbents, particularly for CO.sub.2/H.sub.2O displacement desorption process. The sorbents include an aluminum oxide support that includes two alkali metal salts impregnated on the support. The two alkali metals include a potassium metal salts and a second alkali metal salt which is not potassium. The second metal salt disrupts poisoning effects that degrade sorbent lifetime. The sorbents demonstrate improved CO.sub.2 loadings and better H.sub.2O/CO.sub.2 ratios, as well as improved stability. Compositions and methods of making are disclosed.

Disclosed is a fire suppressant material for controlling or extinguishing a combustion process, the fire suppressant material comprising zeolite particles with an internal porous structure, wherein molecules of a fire extinguishing substance are contained within the internal porous structure of the zeolite material.