Patent classifications
B01J21/16
Layered catalyst reactor systems and processes for hydrotreatment of hydrocarbon feedstocks
A layered catalyst reactor system and process for hydrotreatment of hydrocarbon feedstocks. The layered catalyst system reactors comprise vertical bed layers including a demetallization catalyst layer, multiple layers of supported hydrotreating catalyst layer, and multiple alternating layers of supported hydrocracking catalysts and self-supported hydrotreating catalysts. The arrangement of the catalyst layers mitigates the risk of temperature run-aways, with improvements in hydrotreatment performance.
Layered catalyst reactor systems and processes for hydrotreatment of hydrocarbon feedstocks
A layered catalyst reactor system and process for hydrotreatment of hydrocarbon feedstocks. The layered catalyst system reactors comprise vertical bed layers including a demetallization catalyst layer, multiple layers of supported hydrotreating catalyst layer, and multiple alternating layers of supported hydrocracking catalysts and self-supported hydrotreating catalysts. The arrangement of the catalyst layers mitigates the risk of temperature run-aways, with improvements in hydrotreatment performance.
Selective catalytic reduction catalyst composition
A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).
Selective catalytic reduction catalyst composition
A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).
Method of manufacturing micronized sandstone obtained from ceramics or industrial wastes of ceramic manufacturing containing TiO2 bio-additive, and product thereof
The present invention discloses a method of manufacturing micronized sandstone obtained from ceramics or industrial wastes of ceramic manufacturing, such as white paste, natural stones or clinker, including TiO.sub.2 as bio-additive, and product obtained by the micronized sandstone thereof. The ceramics and industrial wastes of ceramic are grinded in several steps and the resultant powders are collected by means of individual filters and further combined in a nanopowder micronizer for posterior treatment, where TiO.sub.2 hydrolyzed can be optionally added. This micronized sandstone comprising the bio-additive TiO.sub.2 is used in the production of plasters, mortars, grouts and/or as additive for paints and/or epoxy enriched with TiO.sub.2. The micronized sandstone bio-additive with TiO.sub.2 can be additionally subjected to two optional embodiments of the invention: treatment with or without the use of a pigment. In order to obtain the final product that can be used in the production of blocks, floors and other products of various sizes, an agglomerating agent combined with TiO.sub.2 is added to the micronized sandstone comprising the bio-additive TiO.sub.2, either in an aqueous solution or as a dry product, optionally including colored oxides.
Method of manufacturing micronized sandstone obtained from ceramics or industrial wastes of ceramic manufacturing containing TiO2 bio-additive, and product thereof
The present invention discloses a method of manufacturing micronized sandstone obtained from ceramics or industrial wastes of ceramic manufacturing, such as white paste, natural stones or clinker, including TiO.sub.2 as bio-additive, and product obtained by the micronized sandstone thereof. The ceramics and industrial wastes of ceramic are grinded in several steps and the resultant powders are collected by means of individual filters and further combined in a nanopowder micronizer for posterior treatment, where TiO.sub.2 hydrolyzed can be optionally added. This micronized sandstone comprising the bio-additive TiO.sub.2 is used in the production of plasters, mortars, grouts and/or as additive for paints and/or epoxy enriched with TiO.sub.2. The micronized sandstone bio-additive with TiO.sub.2 can be additionally subjected to two optional embodiments of the invention: treatment with or without the use of a pigment. In order to obtain the final product that can be used in the production of blocks, floors and other products of various sizes, an agglomerating agent combined with TiO.sub.2 is added to the micronized sandstone comprising the bio-additive TiO.sub.2, either in an aqueous solution or as a dry product, optionally including colored oxides.
FCC CATALYST COMPOSITIONS CONTAINING BORON OXIDE AND PHOSPHORUS
A method of cracking a hydrocarbon feed under fluid catalytic cracking conditions includes adding FCC compatible inorganic particles having a first particle type including one or more boron oxide components and a first matrix component into a FCC unit and adding cracking microspheres having a second particle type including a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component into the FCC unit.
FCC CATALYST COMPOSITIONS CONTAINING BORON OXIDE AND PHOSPHORUS
A method of cracking a hydrocarbon feed under fluid catalytic cracking conditions includes adding FCC compatible inorganic particles having a first particle type including one or more boron oxide components and a first matrix component into a FCC unit and adding cracking microspheres having a second particle type including a second matrix component, a phosphorus component and 20% to 95% by weight of a zeolite component into the FCC unit.
ELECTRODE CATALYST INK OF WATER ELECTROLYSIS CELL, ELECTRODE CATALYST, WATER ELECTROLYSIS CELL, AND WATER ELECTROLYZER
The electrode catalyst ink for a water electrolysis cell includes a catalyst including a layered double hydroxide, an organic polymer, and a solvent. The Hansen solubility parameter distance R.sub.a1 between the solvent and the catalyst is 15.0 MPa.sup.½ or more and less than 20.5 MPa.sup.½. The Hansen solubility parameter distance R.sub.a2 between the solvent and the organic polymer is 10.0 MPa.sup.½ or more and 14.0 MPa.sup.½ or less.
Alkyl-Demethylation Processes and Catalyst Compositions Therefor
Catalyst compositions to perform selective alkyl-demethylation of C2+-hydrocarbyl-substituted aromatic hydrocarbon may exhibit a hydrogen chemisorption of at least 15% and comprise an oxide support material selected from the group consisting of an alkaline earth metal oxide, silica, a composite of an alkaline earth metal oxide and Al.sub.2O.sub.3, a composite of ZnO and Al.sub.2O.sub.3, a lanthanide oxide, a composite of a lanthanide oxide and Al.sub.2O.sub.3, and combinations and mixtures of two or more thereof; and a transition metal element dispersed upon the oxide support material. Alkyl-demethylation processes of a C6+ aromatic hydrocarbon-containing stream comprising C2+-hydrocarbyl-substituted aromatic hydrocarbons may comprise contacting the catalyst compositions in an alkyl-demethylation zone under alkyl-demethylation conditions to form an alkyl-demethylated aromatic hydrocarbon as an effluent exiting the alkyl-demethylation zone.