Hydrogen is a useful carbon-neutral fuel that can be used in many applications. Unfortunately, hydrogen is hard to produce cost effectively without additional pollution from the production process. This invention solves the problem of producing hydrogen using a renewable low carbon source. This method uses high temperature heat from a concentrated solar power plant to generate steam from water. The steam can then be used with methane or another starter fuel to produce low carbon hydrogen. Additional steam can be added to boost the hydrogen to carbon ratios.

A hybrid dehydrogenation reaction system includes: an acid aqueous solution tank having an acid aqueous solution; an exothermic dehydrogenation reactor including a chemical hydride of a solid state and receiving the acid aqueous solution from the acid aqueous solution tank for an exothermic dehydrogenation reaction of the chemical hydride and the acid aqueous solution to generate hydrogen; an LOHC tank including a liquid organic hydrogen carrier (LOHC); and an endothermic dehydrogenation reactor receiving the liquid organic hydrogen carrier from the LOHC tank and generating hydrogen through an endothermic dehydrogenation reaction of the liquid organic hydrogen carrier by using heat generated from the exothermic dehydrogenation reactor.

The present invention relates to a hydrogen production reactor comprising a high-efficiency composite having a high thermal conductivity and an antioxidant property. Specifically, the hydrogen production reactor comprises: a first region in which a combustion reaction of fuel occurs; a second region in which a hydrogen extraction reaction occurs; a metal substrate that partitions the first region and the second region; and a coating layer that comprises boron nitride (BN) and is formed on at least one surface of the metal substrate, wherein heat generated in the first region is transferred to the second region through the metal substrate.

Disclosed is a thermochemical reactor system and method for a temperature swing cyclic process with integrated heat recovery having at least two modules, wherein each module includes at least one chemical reaction zone and at least one thermal energy storage unit. The at least two modules are operationally connected for at least one heat transfer fluid for transporting heat between the two modules. Each chemical reaction zone includes at least one reacting material that undergoes in a reversible manner an endothermic reaction at temperature T.sub.endo and an exothermic reaction at temperature T.sub.exo, wherein T.sub.endo and T.sub.exo differ from each other. The at least one reacting material is provided in at least one encapsulation within each of the chemical reaction zones such that a contact of the reacting material and the at least one heat transfer fluid is avoided.

Systems and methods are provided for hydrogenation of CO.sub.2 in a reverse flow reactor environment via a reverse water gas shift reaction. A reverse flow reactor environment is suitable for performing endothermic reactions at high temperatures, where a reactant flow is passed into the reactor in a first portion of the cycle in a first flow direction while a combustion or heating flow is passed into the reactor during a second portion of the reaction cycle from the opposite direction. This can allow for efficient heating of surfaces within the reactor to provide heat for the endothermic reverse water gas shift reaction while reducing or minimizing incorporation of combustion products into the desired reaction products.

Hydrogen generation assemblies, hydrogen purification devices, and their components, and methods of manufacturing those assemblies, devices, and components are disclosed. In some embodiments, the devices may include an insulation base having insulating material and at least one passage that extends through the insulating material. In some embodiments, the at least one passage may be in fluid communication with a combustion region.

The invention is directed to a process for the purification of a raw hydrogen gas stream comprising hydrogen gas in an amount of 85-99%, said process comprising the step of contacting said raw hydrogen gas stream with an oxidized bed comprising an oxidized metal resulting in a waste gas stream comprising water and less than 5% hydrogen gas, and in a reduction of said oxidized metal; and a step of contacting a bed comprising a reduced metal with water to produce a purified hydrogen gas stream comprising more than 99% hydrogen gas, preferably comprising 99.97% or more hydrogen gas, and the oxidized metal. In a further aspect, the invention is directed to an apparatus suitable to carry out said process.

A steam methane reformer (SMR) system includes an outer tube, wherein a first end of the outer tube is closed; an inner tube disposed in the outer tube, wherein a first end of the inner tube is open. A flow channel is defined within the inner tube and an annular space is defined between the outer tube and the inner tube, the flow channel being in fluid communication with the annular space. The SMR system includes a catalytic foam disposed in the annular space between the outer tube and the inner tube, the catalytic foam comprising a catalyst.

The present invention relates to a combustion heater (100) for providing controlled heat (H) to an endothermic reaction process. The combustion heater comprises an integrated burner (20) to yield a hot burner exhaust gas (35) flow from burning a first fuel. The burner exhaust gas mixed with oxidant flows to a flue gas outlet along a flue gas flow path (FGP). Provided to the combustion chamber at a position outside a direct reach of flames from the burner is a secondary fuel conduit (30) with a plurality of nozzles (31) from which a second fuel (32) is transferred into a flow along the said flue gas flow path (FGP). The resulting combustion of the second fuel can be used to provide controlled heat to the to endothermic reaction operated in a reaction conduit (40) that is in thermal heat exchange with the combustion chamber.

Methods and systems for heating a reactor feed in a multi reactor hydrocarbon dehydrogenation process. The methods and systems are advantageously employed for the production of styrene by the catalytic dehydrogenation of ethylbenzene. The catalytic dehydrogenation process employs heating steam operating at a steam to oil ratio of about 1.0 or less and relatively low steam superheater furnace temperature, such that all components exposed to steam in the process (outside of the fired heaters) can be constructed with standard metallurgy.