A method for producing phosphorus in which a reaction for forming gaseous phosphorus (g) by bringing phosphorus oxide generated by heating a liquid phosphoric acid compound into contact with a carbon material to reduce the phosphorus oxide and for condensing the gaseous phosphorus (g) to obtain liquid phosphorus (L) is conducted by a flow reaction with a nonoxidizing gas flow, wherein the reduction reaction of the phosphorus oxide is conducted in a carbon material-packed bed, and the condensation of the formed gaseous phosphorus (g) is substantially conducted in a condensation accelerator-packed bed which is disposed downstream of the carbon material-packed bed in contact with the carbon material-packed bed.

A method for facilitating the distribution of the flow of one or more streams within a bed vessel is provided. Disposed within the bed vessel are internal materials and structures including multiple operating zones. One type of operating zone can be a processing zone composed of one or more beds of solid processing material. Another type of operating zone can be a treating zone. Treating zones can facilitate the distribution of the one or more streams fed to processing zones. The distribution can facilitate contact between the feed streams and the processing materials contained in the processing zones.

A process for the production of syngas comprising the steps of providing a feed gas comprising a hydrocarbon, carbon dioxide and optionally steam, contacting a flow of said feed gas with a metal oxide to form syngas, wherein the mole fraction of carbon dioxide or in the case the feed gas comprises steam, the sum of the mole fractions of carbon dioxide and steam, in the feed gas is between 0.3 and 0.7; and/or wherein the mole fraction of the hydrocarbon in the feed gas is between 0.3 to 0.5, wherein the feed gas is contacted with the metal oxide at a temperature of between 1050K and 1600K.

The present invention describes an improved catalytic reactor system with an improved catalyst that transforms CO.sub.2 and low carbon H.sub.2 into low-carbon syngas with greater than an 80% CO.sub.2 conversion efficiency, resulting in the reduction of plant capital and operating costs compared to processes described in the current art. The inside surface of the adiabatic catalytic reactors is lined with an insulating, non-reactive surface which does not react with the syngas and effect catalyst performance. The improved catalyst is robust, has a high CO.sub.2 conversion efficiency, and exhibits little or no degradation in performance over long periods of operation. The low-carbon syngas is used to produce low-carbon fuels (e.g., diesel fuel, jet fuel, gasoline, kerosene, others), chemicals, and other products resulting in a significant reduction in greenhouse gas emissions compared to fossil fuel derived products.

A process and system for the conversion of a feedstock comprising C3-C5 light alkanes to a C5+ hydrocarbon product, for example, a BTX-rich hydrocarbon product, by performing the alkane activation (first-stage) and the oligomerization/aromatization (second-stage) in separate stages, which allows each conversion process to occur at optimal reaction conditions thus increasing the overall hydrocarbon product yield. The alkane activation or first-stage is operated at a higher temperature than the second-stage since light alkanes are much less reactive than light olefins. Since aromatization of olefins is more efficient at higher pressure, the second-stage is maintained at a higher pressure than the first-stage. Further, fixed-bed catalysts are used in each of the first-stage and the second-stage.

Spent catalyst (500) is removed from process microchannels (310) of a Fischer-Tropsch reactor by directing a jet of air (4) from an air knife (1) through slots of a protecting member (2). The air knife is traversed across successive rows of process microchannels (310) in direction A. The spacer member (2) protects an internal microchannel architecture (315) of the process microchannels against damage by the air jet (4) which may approach or exceed sonic velocity as it is directed into the process microchannels.

A process for supplying deaerated water to a chemical plant that includes a distillation column for separating a reaction effluent comprising water and a product. The process includes inventorying the distillation column with aerated water (water having an oxygen content of greater than 50 ppbw, such as greater than 1 ppmw). The aerated water in the distillation column may then be distilled to produce an oxygen-containing overheads and a bottoms fraction comprising deaerated water. The deaerated water in the bottoms fraction ma be transported to an upstream or a downstream unit operation, and utilizing the deaerated water in the upstream or downstream unit operation. The reaction effluent is fed to the distillation column, transitioning the distillation column from separating oxygen from water to operations for separating the product from the water.

A method for producing an olefin and a monocyclic aromatic hydrocarbon of the present invention includes a dicyclopentadiene removal treatment step of removing dicyclopentadienes having a dicyclopentadiene skeleton from a feedstock oil which is a thermally-cracked heavy oil obtained from an apparatus for producing ethylene and which has a 90 volume % distillate temperature, as a distillation characteristic, of 390° C. or lower; and a cracking and reforming reaction step of obtaining a product containing an olefin and a monocyclic aromatic hydrocarbon by bringing the feedstock oil having a content of dicyclopentadienes adjusted to 10% by weight or less by treating a part or all of the feedstock oil through the dicyclopentadiene removal step into contact with a catalyst and reacting the feedstock oil.

The present disclosure relates to an apparatus for generating glycol and a method thereof. More particularly, the present disclosure relates to an apparatus for generating glycol including (a) an aldol reactor; (b) an extractor for extracting an aldol product, unsaturated aldehyde, using an organic solvent that is not mixed with water; (c) a distillation column for removing a raw material from a solution extract that is discharged from the extractor; (d) a hydrogenation reactor for hydrogenating a solution extract that is discharged from the distillation column; and (e) a divided-wall distillation column for isolating glycol from a hydrogenated solution product that is discharged from the hydrogenation reactor, wherein the hydrogenation reactor is a fixed-bed catalytic reactor that is filled with a copper-based catalyst, and a method of preparing the same.

In accordance with the present disclosure, an economical apparatus for preparing glycol which reduces loss of a raw material and provides a high glycol yield while inhibiting generation of by-products, and a method of preparing the same are provided.

A trickle bed reactor, comprising a plurality of catalyst beds connected in series and progressively increasing in catalyst mass in a direction from upstream to downstream; and a plurality of heat exchangers, wherein each of the heat exchangers is located between two of the plurality of catalyst beds, and wherein each of the heat exchangers does not exchange heat with an outer surface of a vessel that contains any of the catalyst beds.