Patent classifications
B01J2219/00029
System for Producing Polyolefin and Process for Recovering Polymerization Product from Gas Phase Reactor
The invention relates to a system for producing polyolefin. The system comprises a gas phase reactor (1) for polymerizing an olefin to obtain polymerization product. The gas phase reactor (1) comprises a gas distribution plate (11) arranged inside the gas phase reactor (1); a first outlet (12) for continuously withdrawing polymerization product from the gas phase reactor (1) as a first product stream, the first outlet (12) being arranged above the gas distribution plate (11); and a second outlet (13) for continuously withdrawing polymerization product from the gas phase reactor (1) as a second product stream, the second outlet (13) being arranged above the gas distribution plate (11). The system further comprises a first outlet tank (2) in fluid communication with the first outlet (12) via a first passage (22), wherein the first passage (22) comprises a first valve means (221) for controlling the flow of the first product stream in the first passage (22) and wherein the first outlet tank (2) is arranged to receive the first product stream and to concentrate the first product stream; a product receiver tank (3) in fluid communication with the second outlet (13) via a second passage (31), wherein the second passage (31) comprises a second valve means (311) for controlling the flow of the second product stream in the second passage (31), and wherein the product receiver tank (3) is arranged to receive the second product stream; and a control means in communication with the first valve means (221) and the second valve means (311) and arranged to control the operation of the first valve means (221) and the second valve means (311) so that flow in only one of the first passage (22) and the second passage (31) is allowed at a time.
The invention relates also to a process for recovering polymerization product from a gas phase reactor (1). The gas phase reactor (1) is suitable for polymerizing an olefin to obtain polymerization product and comprises a gas distribution plate (11) arranged inside the gas phase reactor (1); a first outlet (12) for continuously withdrawing polymerization product from the gas phase reactor (1), the first outlet (12) being arranged above the gas distribution plate (11); and a second outlet (13) for continuously withdrawing polymerization product from the gas phase reactor (1), the second outlet (13) being arranged above the gas distribut
Processes for the manufacture of secondary fatty alcohols, internal olefins and internal olefin sulfonates
Process P.sup.1 for the manufacture of a secondary fatty alcohol, said process P.sup.1 comprising synthesizing an internal ketone K1 by a process P.sup.0 comprising the decarboxylative ketonization reaction of a fatty acid or the like in a liquid phase with a metal compound as catalyst in a reaction medium, wherein a ketone K.sup.2 at liquid state, which is identical or similar to the internal ketone K.sup.1, is introduced into the reaction medium, and subjecting the internal ketone K.sup.1 to a hydrogenation reaction with hydrogen gas as hydrogenating agent to form the secondary fatty alcohol. Use of the secondary fatty alcohol manufactured by the process P.sup.1 for the manufacture of an internal olefin or of an internal olefin sulfonate.
Equipment and method for preparing an aldehyde-functionalised polymer
Equipment for preparing a polymer solution of a non-ionic, cationic, anionic or amphoteric polymer by reaction between a compound including at least one aldehyde function and at least one base polymer aqueous solution having at least one non-ionic monomer includes a reactor provided with a stirring system, as well as a recirculation loop including between the outlet of the reactor and the inlet of the reactor, a recirculation pump, a pH measuring probe, and a pressure differential in-line measuring device in the form of a calibrated tube configured to measure the pressure difference of the polymer solution between the inlet and the outlet of the calibrated tube, the calibrated tube being branched on the recirculation loop.
PREPARATION OF EXPANDED GRAPHITE BY PHYSICAL SHEARING
Provided herein are high throughput continuous or semi-continuous reactors and processes for manufacturing expanded graphite materials. Such processes are suitable for manufacturing expanded graphite materials with little batch-to-batch variation.
Post polymerization modification in flow
Techniques regarding post polymerization modifications to polycarbonate polymers via a flow reactor are provided. For example, one or more embodiments described herein can comprise a cyclic carbonate monomer that can be employed to facilitate polymerization of one or more polycarbonate platforms susceptible to post polymerization modification. For instance, one or more embodiments can regard a cyclic carbonate molecular backbone covalently bonded to an aryl halide functional group via in accordance with a chemical structure selected from the group consisting of: ##STR00001##
In the chemical structures, “R.sub.1” can be selected from the group consisting of a hydrogen atom and a functional group comprising a first alkyl group; “L” can represent a linkage group, comprising: a second alkyl group and an end group having at least one member selected from the group consisting of an oxygen atom and a nitrogen atom; and “A” can represent the aryl halide functional group.
Hydrogen generator
A hydrogen generator includes a reaction vessel, a water supply, a temperature adjustor, and a controller. The reaction vessel houses a hydrogen generating material having hydrogen generating ability. The hydrogen generating material includes a two-dimensional hydrogen boride sheet having a two-dimensional network and containing multiple negatively charged boron atoms. The controller is configured to execute a hydrogen generating mode to generate hydrogen from the hydrogen generating material and a regenerating mode to recover the hydrogen generating ability of the hydrogen generating material. The controller controls the temperature adjustor to heat the hydrogen generating material at a first predetermined temperature during the hydrogen generating mode. The controller controls the temperature adjustor to adjust the temperature of the hydrogen generating material to a second predetermined temperature and controls the water supply to supply water during the regenerating mode.
POST POLYMERIZATION MODIFICATION IN FLOW
Techniques regarding post polymerization modifications to polycarbonate polymers via a flow reactor are provided. For example, one or more embodiments described herein can comprise a cyclic carbonate monomer that can be employed to facilitate polymerization of one or more polycarbonate platforms susceptible to post polymerization modification. For instance, one or more embodiments can regard a cyclic carbonate molecular backbone covalently bonded to an aryl halide functional group via in accordance with a chemical structure selected from the group consisting of:
##STR00001##
In the chemical structures, “R.sub.1” can be selected from the group consisting of a hydrogen atom and a functional group comprising a first alkyl group; “L” can represent a linkage group, comprising: a second alkyl group and an end group having at least one member selected from the group consisting of an oxygen atom and a nitrogen atom; and “A” can represent the aryl halide functional group.
Method and reactor for separating and removing heavy metals from wastewater using sulfhydryl-modified nano-magnetized activated carbon
A method and reactor are disclosed for separating and removing heavy metals from wastewater using a sulfhydryl-modified nano-magnetized activated carbon. The method includes the steps of preparing a sulfhydryl-modified nano-magnetized activated carbon first; introducing heavy-metal-containing wastewater into a reactor which is equipped with a stirrer and keeping stirring, and then adding the sulfhydryl-modified nano-magnetized activated carbon, continuously stirring for a reaction; after reacting for a period, precipitating under a magnetic field generated by a magnet separator, discharging the resulting supernate, and then discharging the precipitated sludge.
Method and Apparatus for Producing Carbon Monoxide
A method for producing carbon monoxide includes decomposing formic acid, in the presence of water, by hydrothermal reaction under conditions with a temperature T of 350° C. or less and a pressure P being equal to or more than the saturated vapor pressure of water at the temperature T.
Microwave-based thermal coupling chemical looping gasification method employing two sources, and device for same
A microwave-based thermal coupling chemical looping gasification method and device. The device includes: a microwave radiation cavity; a loading recess of a microwave absorbing material; and a quartz pipe reaction cavity between the microwave radiation cavity and the loading recess of a microwave absorbing material. A microwave generator consisting of magnetrons is provided at a central portion of the microwave radiation cavity and below the loading recess. An infrared temperature-measuring probe group is arranged at two ends of the magnetrons. Two ends of the microwave radiation cavity are connected to a first and second three-way valves, in communication with the ambient atmosphere and a protection gas charging device. A protection gas cooling device and a protection gas circulating fan are sequentially connected in series on a pipeline between the valves.