B01J2219/00042

UNIT OPERATION AND USE THEREOF

The invention provides a unit operation formed by a device and its use for continuous virus inactivation of a continuous flow of a process fluid. The unit operation formed by a device comprises a single inlet at one end and an outlet at the opposite end and at least one HFI, characterized in that the HFI further comprises at least one installation.

REVERSE ACID AND HYDROCARBON CASCADING IN ALKYLATION

A cascade reactor scheme with acid and hydrocarbon flowing in reverse directions. The systems and processes for alkylation of olefins herein may include providing a first olefin to a first alkylation zone, and a second olefin to a second alkylation zone. Isoparaffin may be provided to the first alkylation zone. The isoparaffin and first olefin may be contacted with a partially spent sulfuric acid in the first alkylation zone to form a spent acid phase and a first hydrocarbon phase including alkylate and unreacted isoparaffin. The first hydrocarbon phase and second olefin may be contacted with a sulfuric acid feed in the second alkylation zone to form a second hydrocarbon phase, also including alkylate and unreacted isoparaffin, and the partially spent sulfuric acid that is fed to the first alkylation zone. Further, the second hydrocarbon phase may be separated, recovering an isoparaffin fraction and an alkylate product fraction.

Processes and Apparatus for Bimodal Slurry Polymerization

Processes and apparatus for preparing bimodal polymers are provided. In some embodiments, processes include introducing a monomer, a first diluent, a catalyst, hydrogen, at a first hydrogen concentration, and optional comonomer, to a first loop reactor to produce, under polymerization conditions, a first slurry of polymer solids. Processes may also include continuously discharging the first slurry of polymer solids from the loop reactor as a first polymerization effluent to a first flash tank; separating the first polymerization effluent in the first flash tank to provide a first concentrated polymer slurry with significantly lower hydrogen concentration; and transferring the first concentrated polymer slurry from the flash tank to a re-slurry mixer. Processes may further include introducing a re-slurry mixer diluent to the first concentrated polymer slurry to form a second concentrated polymer slurry in the re-slurry mixer that can be pumped to a second slurry loop reactor.

Reverse acid and hydrocarbon cascading in alkylation

A cascade reactor scheme with acid and hydrocarbon flowing in reverse directions. The systems and processes for alkylation of olefins herein may include providing a first olefin to a first alkylation zone, and a second olefin to a second alkylation zone. Isoparaffin may be provided to the first alkylation zone. The isoparaffin and first olefin may be contacted with a partially spent sulfuric acid in the first alkylation zone to form a spent acid phase and a first hydrocarbon phase including alkylate and unreacted isoparaffin. The first hydrocarbon phase and second olefin may be contacted with a sulfuric acid feed in the second alkylation zone to form a second hydrocarbon phase, also including alkylate and unreacted isoparaffin, and the partially spent sulfuric acid that is fed to the first alkylation zone. Further, the second hydrocarbon phase may be separated, recovering an isoparaffin fraction and an alkylate product fraction.

METHODS AND APPARATUS FOR INDUCING REACTIONS USING ELECTROSTATICS
20240009647 · 2024-01-11 ·

Method and associated apparatus (1) for bringing together one or more first bodies comprising a first substance with one or more second bodies comprising a second substance for the purpose of the first and second bodies, or the first and second substances contained therein, chemically and/or physically reacting together. the apparatus (1) comprising: a container (48) containing a dielectric medium (50) comprising one or more dielectric materials. especially one or more dielectric fluids or pseudo-fluids: first means (10N; 30, 36, 14, 10T) for forming the said one or more first bodies comprising the first substance and applying thereto an electric charge of a first polarity. and second means (20N; 30, 38, 24, 20T) for forming the said one or more second bodies comprising the second substance and applying thereto an electric charge of a second polarity. the first polarity being opposite to the second polarity: wherein the first and second forming means (10N, 30, 36, 14, 10T; 20N, 30, 38, 24, 20T) are each arranged for forming the respective said one or more charged first bodies and one or more charged second bodies such that each thereof is located in the said dielectric fluid medium (50) contained in the container (48), and such that the one or more charged first bodies and the one or more oppositely charged second bodies each have a size or width of at least about 0.01 mm or greater. especially of at least about 0.02 or 0.03 or 0.04 or 0.05 mm or greater;: whereby, once formed in the said dielectric medium (50), the oppositely polarised electric charges on the said first and second bodies causes or promotes electrostatic attraction between one or more respective pairs of the one or more first bodies and the one or more second bodies.

Process and installation for the conversion of crude oil to petrochemicals having an improved carbon-efficiency

The present invention relates to an integrated process to convert crude oil into petrochemical products comprising crude oil distillation, hydrocracking and olefins synthesis, which process comprises subjecting a hydrocracker feed to hydrocracking to produce LPG and BTX and subjecting the LPG produced in the process to olefins synthesis. Furthermore, the present invention relates to a process installation to convert crude oil into petrochemical products comprising: a crude distillation unit comprising an inlet for crude oil and at least one outlet for one or more of naphtha, kerosene and gasoil; a hydrocracker comprising an inlet for a hydrocracker feed, an outlet for LPG and an outlet for BTX; and a unit for olefins synthesis comprising an inlet for LPG produced by the integrated petrochemical process installation and an outlet for olefins. The hydrocracker feed used in the process and the process installation of the present invention comprises one or more of naphtha, kerosene and gasoil produced by crude oil distillation in the process; and refinery unit-derived light-distillate and/or refinery unit-derived middle-distillate produced in the process. The process and process installation of the present invention have an increased production of petrochemicals at the expense of the production of fuels and an improved carbon efficiency in terms of the conversion of crude oils into petrochemicals.

REVERSE ACID AND HYDROCARBON CASCADING IN ALKYLATION

A cascade reactor scheme with acid and hydrocarbon flowing in reverse directions. The systems and processes for alkylation of olefins herein may include providing a first olefin to a first alkylation zone, and a second olefin to a second alkylation zone. Isoparaffin may be provided to the first alkylation zone. The isoparaffin and first olefin may be contacted with a partially spent sulfuric acid in the first alkylation zone to form a spent acid phase and a first hydrocarbon phase including alkylate and unreacted isoparaffin. The first hydrocarbon phase and second olefin may be contacted with a sulfuric acid feed in the second alkylation zone to form a second hydrocarbon phase, also including alkylate and unreacted isoparaffin, and the partially spent sulfuric acid that is fed to the first alkylation zone. Further, the second hydrocarbon phase may be separated, recovering an isoparaffin fraction and an alkylate product fraction.

Method of forming and using a bisphenol oil stream

In an embodiment, a continuous method of forming a bisphenol A oil comprises forming the bisphenol A oil by mixing a molten bisphenol A and water; wherein the bisphenol A oil comprises 10 to 30 wt % water based on a total weight of the bisphenol A oil and is at a temperature of 100 to 140 C.; flowing at least a portion of the bisphenol A oil through an inline densitometer and measuring a real-time density and a real-time temperature of the bisphenol A oil; determining a real-time concentration of the bisphenol A oil based on said real-time density and said real-time temperature.

Metallocene Catalyst Feed System for Solution Polymerization Process
20190247821 · 2019-08-15 ·

Methods and systems for solution polymerization. The method can include forming a first mixture stream consisting essentially of at least one catalyst and a process solvent, and forming a second mixture stream consisting essentially of at least one activator and the process solvent. The first mixture stream and the second mixture stream can be fed separately to at least one reaction zone comprising one or more monomers dissolved in the process solvent where the at least one monomers can be polymerized within the at least one reaction zone in the presence of the catalyst, activator and process solvent to produce a polymer product.

METHODS FOR DIRECT EPOXIDATION OF PROPYLENE WITH OXYGEN
20190023672 · 2019-01-24 ·

Methods to produce propylene oxide are described. One method can include providing a propene feedstream, an oxygen feed stream and, optionally, a hydrogen feed stream to a reaction zone, and maintaining, in a reaction zone during the reaction, at least 50 vol. % propene and 1 to 15 vol. % O.sub.2 by gradually introducing a feed stream that includes the O.sub.2 over the length of the catalytic bed or the length of the reaction zone and/or a feed stream that includes the H.sub.2 over the length of the catalytic bed or the length of the reaction zone.