An object of the present invention is to provide a new frameless catalytic thermal oxidation device capable of treating concentrations of harmful materials including NOx at a low temperature. Further, another object of the present invention is to provide a frameless catalytic thermal oxidation device capable of minimizing the occurrence of THC and minimizing a risk of accidents and environmental pollution which may occur in maintenance operations. According to the objects, the present invention provides a cartridge-type thermal oxidation device capable of being separated for maintenance, wherein a cartridge internal structure is configured so that the time while the material to be treated stays in a zone with the catalyst is increased, and a member capable of dropping and collecting powder generated by thermal oxidation reaction is configured.

The invention relates to a use of a fluorination gas, the elemental fluorine (F.sub.2) is preferably present in a high concentration, e.g. in a concentration of elemental fluorine (F.sub.2), especially of equal to much higher than 15% or even 20% by volume (i.e., at least 15% or even 20% by volume), and to a process for the manufacture of a fluorinated benzene starting from benzoic acid by direct fluorination employing a fluorination gas. The elemental fluorine (F.sub.2) is preferably present in high concentration, and subsequent decarboxylation of the benzoic acid hypofluorite obtained by direct fluorination. The process of the invention is also directed to the manufacture of benzoic acid hypofluorite by direct fluorination of benzoic acid. Especially the invention is of interest in the preparation of fluorinatedbenzene, final products and as well intermediates, for usage in agro-, pharma-, electronics-, catalyst, solvent and other functional chemical applications.

An object of the present invention is to provide a new frameless catalytic thermal oxidation device capable of treating concentrations of harmful materials including NOx at a low temperature. Further, another object of the present invention is to provide a frameless catalytic thermal oxidation device capable of minimizing the occurrence of THC and minimizing a risk of accidents and environmental pollution which may occur in maintenance operations. According to the objects, the present invention provides a cartridge-type thermal oxidation device capable of being separated for maintenance, wherein a cartridge internal structure is configured so that the time while the material to be treated stays in a zone with the catalyst is increased, and a member capable of dropping and collecting powder generated by thermal oxidation reaction is configured.

An object of the present invention is to provide a new frameless catalytic thermal oxidation device capable of treating concentrations of harmful materials including NOx at a low temperature. Further, another object of the present invention is to provide a frameless catalytic thermal oxidation device capable of minimizing the occurrence of THC and minimizing a risk of accidents and environmental pollution which may occur in maintenance operations. According to the objects, the present invention provides a cartridge-type thermal oxidation device capable of being separated for maintenance, wherein a cartridge internal structure is configured so that the time while the material to be treated stays in a zone with the catalyst is increased, and a member capable of dropping and collecting powder generated by thermal oxidation reaction is configured.

The invention relates to a use of a fluorination gas, the elemental fluorine (F2) is preferably present in a high concentration, e.g. in a concentration of elemental fluorine (F2), especially of equal to much higher than 15% or even 20% by volume (i.e., at least 15% or even 20% by volume), and to a process for the manufacture of a fluorinated benzene starting from benzoic acid by direct fluorination employing a fluorination gas. The elemental fluorine (F.sub.2) is preferably present in high concentration, and subsequent decarboxylation of the benzoic acid hypofluorite obtained by direct fluorination. The process of the invention is also directed to the manufacture of benzoic acid hypofluorite by direct fluorination of benzoic acid. Especially the invention is of interest in the preparation of fluorinatedbenzene, final products and as well intermediates, for usage in agro-, pharma-, electronics-, catalyst, solvent and other functional chemical applications.

In one example, a method for converting a first compound into a second compound is provided. The method includes providing the first compound in an entrance of a flow through reactor, wherein the entrance comprises a first catalyst and an oxidant, converting the first compound and the oxidant into the second compound as the first compound and the oxidant contact the first catalyst in the entrance of the flow through reactor while moving towards a tail end of the flow through reactor, and converting the first compound and the oxidant into the second compound via a solid catalyst comprising a white crystalline solid with a titanium content of about 0.5 to about 1.5 weight percent (wt %) in the tail end of the flow through reactor.

In one example, a method for converting a first compound into a second compound is provided. The method includes providing the first compound in an entrance of a flow through reactor, wherein the entrance comprises a first catalyst and an oxidant, converting the first compound and the oxidant into the second compound as the first compound and the oxidant contact the first catalyst in the entrance of the flow through reactor while moving towards a tail end of the flow through reactor, and converting the first compound and the oxidant into the second compound via a solid catalyst comprising a white crystalline solid with a titanium content of about 0.5 to about 1.5 weight percent (wt %) in the tail end of the flow through reactor.

A method for loading pellets into receptacles having an open top end and a bottom end uses a pressurized fluid injected through injector tubing to form virtual blankets at a plurality of elevations inside the receptacle to reduce the acceleration of the falling pellets in order to provide gentle loading of the pellets.

An object of the present invention is to provide a new frameless catalytic thermal oxidation device capable of treating concentrations of harmful materials including NOx at a low temperature. Further, another object of the present invention is to provide a frameless catalytic thermal oxidation device capable of minimizing the occurrence of THC and minimizing a risk of accidents and environmental pollution which may occur in maintenance operations. According to the objects, the present invention provides a cartridge-type thermal oxidation device capable of being separated for maintenance, wherein a cartridge internal structure is configured so that the time while the material to be treated stays in a zone with the catalyst is increased, and a member capable of dropping and collecting powder generated by thermal oxidation reaction is configured.

A method for loading pellets into receptacles uses a pressurized fluid to form virtual blankets at a plurality of elevations inside the receptacle to reduce the acceleration of the falling pellets in order to provide gentle loading of the pellets.