The present invention relates to a triphasic single reactor comprising a solid, a liquid and a gaseous component, wherein the (i) the solid component is (a) a catalytically active composite based on (b) at least one perforated and permeable support, wherein the catalytically active composite is on at least one side of the support and inside the support and (a) the catalytically active composite is obtained by applying a suspension comprising at least one inorganic component of a compound of at least one of the elements Ce, La Sc, Y, Ti, Zr, Hf, Rf, V, Nb, Ta, Db, Cr, Mo, W, Sg, Mn, Tc, Re, Bh, Fe, Co, B, Al, In, Tl, Si, Ge, Sn, Pb, Sb and Bi with at least one of the elements Te, Se, S, O, Sb, As, P, N, Ge, Si, C and Ga and/or a compound of one of the elements Ti, Zr, Al, Ce and Si with oxygen, and/or a metal selected from Pt, Rh, Ru, Ir, Cu, Ni, Co, Mg, Zn, Al and Pd, in suspension in a sol, and (b) the support comprises fibers of at least one material selected from the group consisting of carbon, metal, alloy, ceramic, glass, mineral, plastic, amorphous substance, composite, natural product, and a combination thereof and heating the support at least once to a temperature of between 100 to 800° C. for 10 minutes to 5 hours, during which the suspension comprising the inorganic component is solidified on and inside the support.

The present invention relates to a method of oxidising at least one aqueous organic compound in a triphasic reaction mixture, wherein the reaction mixture comprises at least one solid, at least one liquid and at least one gaseous constituent, wherein (i) the solid component is (a) a catalytically active composite based on (b) at least one perforated and permeable support, wherein the composite is on at least one side of the support and inside the support and (a) the composite is obtained by applying a suspension comprising at least one inorganic component having a particle size from 1 to 10 000 nm and at least one compound of at least one of the elements La, Ce, Mg, Sc, Y, Ti, Zr, Nb, V, Cr, Mo, W, Mn, Fe, B, Al, In, Tl, Si, Ge, Sn, Pb, Sb, Pd, Ru, Re, Hf, Gd, Ag, Cu, Li, K, Na, Be, Mg, Ca, Sr and Ba and Bi with at least one of the elements Zn, Al, Te, Se, S, O, Sb, As, P, N, Ge, Si, C and Ga, in suspension in a sol, and (b) the support comprises fibers of at least one material selected from the group consisting of carbon, metal, alloy, ceramic, glass, mineral, plastic, amorphous substance, composite, natural product, and a combination thereof and heating the support at least once to a temperature of between 100 to 800° C. for 10 minutes to 5 hours, during which the suspension comprising the inorganic component is solidified on and inside the support.

An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.

An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.

An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.

An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.

An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.

An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.

An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.

An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.