Patent classifications
B01J23/885
PROCESSING OF HEAVY HYDROCARBON FEEDS
Systems and methods are provided for hydroconversion of a heavy oil feed under slurry hydroprocessing conditions and/or solvent assisted hydroprocessing conditions. The systems and methods for slurry hydroconversion can include the use of a configuration that can allow for improved separation of catalyst particles from the slurry hydroprocessing effluent. In addition to allowing for improved catalyst recycle, an amount of fines in the slurry hydroconversion effluent can be reduced or minimized. This can facilitate further processing or handling of any “pitch” generated during the slurry hydroconversion. The systems and methods for solvent assisted hydroprocessing can include processing of a heavy oil feed in conjunction with a high solvency dispersive power crude.
PROCESSING OF HEAVY HYDROCARBON FEEDS
Systems and methods are provided for hydroconversion of a heavy oil feed under slurry hydroprocessing conditions and/or solvent assisted hydroprocessing conditions. The systems and methods for slurry hydroconversion can include the use of a configuration that can allow for improved separation of catalyst particles from the slurry hydroprocessing effluent. In addition to allowing for improved catalyst recycle, an amount of fines in the slurry hydroconversion effluent can be reduced or minimized. This can facilitate further processing or handling of any “pitch” generated during the slurry hydroconversion. The systems and methods for solvent assisted hydroprocessing can include processing of a heavy oil feed in conjunction with a high solvency dispersive power crude.
METHOD FOR PRODUCING ISOBUTYLENE, METHOD FOR PRODUCING METHACRYLIC ACID, AND METHOD FOR PRODUCING METHYL METHACRYLATE
There is provided a method for producing isobutylene, in which isobutylene is produced from isobutanol with a high selectivity while suppressing a decrease in the isobutanol conversion rate under pressure. In the method for producing isobutylene according to the present invention, a raw material gas containing isobutanol is brought into contact with a catalyst to produce isobutylene from isobutanol, the method including bringing the raw material gas containing isobutanol into contact with a catalyst at a linear velocity of 1.20 cm/s or more under a pressure of 120 kPa or more in terms of absolute pressure to produce isobutylene from isobutanol.
Catalyst for preparing synthetic gas, method for preparing the same, and method for preparing synthetic gas using the same
Disclosed are a catalyst for preparing a synthetic gas through dry reforming, a method preparing the catalyst, and a method using the catalyst for preparing the synthetic gas. The catalyst may include: a support including regularly distributed mesopores; metal nanoparticles supported on the support; and a metal oxide coating layer coated on a surface of the support.
Acid-resistant catalyst supports and catalysts
A process for preparing a catalyst comprises coating substantial internal surfaces of porous inorganic powders with titanium oxide to form titanium oxide-coated inorganic powders. After the coating, an extrudate comprising the titanium oxide-coated inorganic powders is formed and calcined to form a catalyst support. Then, the catalyst support is impregnated with a solution containing one or more salts of metal selected from the group consisting of molybdenum, cobalt, and nickel.
Acid-resistant catalyst supports and catalysts
A process for preparing a catalyst comprises coating substantial internal surfaces of porous inorganic powders with titanium oxide to form titanium oxide-coated inorganic powders. After the coating, an extrudate comprising the titanium oxide-coated inorganic powders is formed and calcined to form a catalyst support. Then, the catalyst support is impregnated with a solution containing one or more salts of metal selected from the group consisting of molybdenum, cobalt, and nickel.
METHOD FOR PRODUCING ACRYLIC ACID
A method includes supplying a gas containing acrolein to a fixed bed reactor including a reaction tube to produce acrylic acid by vapor phase catalytic oxidation of acrolein. The reaction tube is packed with catalysts having different activities in such a way that catalyst layers are formed in a tube axis direction. A catalyst X having the highest activity among the catalysts contained in all the catalyst layers is placed in the whole or a part of a section up to 30% of a length of all the catalyst layers from a rearmost portion on a gas outlet side toward a gas inlet side. A catalytically active component x in the catalyst X has Mo, V, and optionally Cu. When Cu is included, its amount is 0.8 mol or less per 12 mol of Mo. A specific surface area of the catalytically active component x is 15-40 m.sup.2/g.
RANEY COPPER CATALYST AS WELL AS PREPARATION METHOD AND USE THEREOF
A Raney copper catalyst, a preparation method and use thereof are provided. The Raney copper catalyst includes aluminum, copper and a metal promoter, wherein the metal promoter comprises a combination of one or more of Ni, Fe, Mo, Co, Ag, Pd, Pt, Au and other elements. The preparation method includes performing high-temperature melting on a mixture containing a copper/aluminum alloy and the metal promoter to obtain a mixed metal cured compound, then smashing the mixed metal cured compound to obtain a catalyst precursor, and subsequently activating to obtain the Raney copper catalyst. The Raney copper catalyst exhibits a capability on hydrogenation reaction based on synergistic effects between metal copper and different promoter metals. Compared with the Raney copper catalyst without metal promoters, when used for preparing 1,3-propanediol through hydrogenation of 3-hydroxypropionaldehyde aqueous solution, the Raney copper catalyst is higher in activity and better in stability.
METHOD FOR PRODUCING GUERBET ALCOHOL
A method for producing a Guerbet alcohol, including reacting a raw material alcohol having 8 or more and 22 or less carbon atoms, in the presence of a catalyst (A) containing a first component, a second component, and a third component below: first component: copper, second component: one kind selected from the group consisting of cobalt, nickel, molybdenum, and rhenium, and third component: at least one kind selected from the group consisting of elements that are elements belonging to Groups 3 to 10 and 12 of the fourth period of the periodic table and elements belonging to Groups 3 to 7, 11, and 12 of the fifth and sixth periods of the periodic table, and are different from the element selected as the second component.
METHOD FOR PRODUCING GUERBET ALCOHOL
A method for producing a Guerbet alcohol, including reacting a raw material alcohol having 8 or more and 22 or less carbon atoms, in the presence of a catalyst (A) containing a first component, a second component, and a third component below: first component: copper, second component: one kind selected from the group consisting of cobalt, nickel, molybdenum, and rhenium, and third component: at least one kind selected from the group consisting of elements that are elements belonging to Groups 3 to 10 and 12 of the fourth period of the periodic table and elements belonging to Groups 3 to 7, 11, and 12 of the fifth and sixth periods of the periodic table, and are different from the element selected as the second component.