Patent classifications
B01J29/048
Methods to produce zeolites with the GME topology and compositions derived therefrom
The present disclosure is directed to microporous crystalline aluminosilicate structures with GME topologies having pores containing organic structure directing agents (OSDAs) comprising at least one piperidinium cation, the compositions useful for making these structures, and methods of using these structures. In some embodiments, the crystalline zeolite structures have a molar ratio of Si:Al that is greater than 3.5.
Zincoaluminosilicates with GME topologies and methods of making and using the same
The present disclosure is directed to methods of producing zincoaluminosilicate structures with AEI, CHA, and GME topologies using organic structure directing agents (OSDAs), and the compositions and structures resulting from these methods.
ZEOLITES THAT INCLUDE TRANSITION METALS AND METHODS FOR MAKING SUCH
Embodiments of the present disclosure relate to zeolites and method for making such zeolites. According to embodiments disclosed herein, a zeolite may have a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm and a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm. The microporous framework may include an MFI framework type. The microporous framework may include silicon atoms, aluminum atoms, oxygen atoms, and transition metal atoms. The transition metal atoms may be dispersed throughout the entire microporous framework.
SMALL CRYSTAL SSZ-41, ITS SYNTHESIS AND USE
A method is disclosed for producing small crystal, high aluminum content zincoaluminosilicate crystalline materials having the SSZ-41 framework structure. The compositions made according to that method, as well as uses of the same, are also disclosed.
Use of SSZ-41X and MTW zeolites for the production of jet and diesel fuels
A process is disclosed for producing distillate range hydrocarbons using MTW and/or SSZ-41x catalysts.
Delamination of borosilicate layered zeolite
Provided is a surfactant-free, single-step synthesis of delaminated aluminosilicate zeolites. The process comprises the step of heating a borosilicate zeolite precursor in a metal salt solution, e.g., an aluminum nitrate solution, zinc nitrate solution or manganese nitrate solution. The delaminated aluminosilicate zeolite product is then recovered from the solution.
Zincoaluminosilicates with CHA topologies and methods of making and using the same
The present disclosure is directed to methods of producing zincoaluminosilicate structures with AEI, CHA, and GME topologies using organic structure directing agents (OSDAs), and the compositions and structures resulting from these methods.
Small crystal SSZ-41, its synthesis and use
A method is disclosed for producing small crystal, high aluminum content zincoaluminosilicate crystalline materials having the SSZ-41 framework structure. The compositions made according to that method, as well as uses of the same, are also disclosed.
JMZ-12, A DISORDERED AEI/CHA FAMILY OF ZEOLITES, ITS SYNTHESIS AND USE
The present invention is directed to a method of preparing a synthetic crystalline material, designated as JMZ-12, with a framework built up by the disorder AEI and CHA structures, substantially free of framework phosphorous and prepared preferably in the absence of halides such as fluoride ions. Such method comprises the step of heating a reaction mixture under crystallization conditions for a sufficient period to form a disordered zeolite having both CHA and AEI topologies, wherein the reaction mixture comprises at least one source of aluminum, at least one source of silicon, a source of alkaline or alkaline-earth cations, and a structure directing agent containing at least one source of quaternary ammonium cations and at least one source of alkyl-substituted piperidinium cations in a molar ratio of 0.20 to about 1.4. The resulting zeolites are useful as catalysts, particularly when used in combination with exchanged transition metal(s) and, optionally, rare earth metal(s).
SMALL CRYSTAL SSZ-41, ITS SYNTHESIS AND USE
A method is disclosed for producing small crystal, high aluminum content zincoaluminosilicate crystalline materials having the SSZ-41 framework structure. The compositions made according to that method, as well as uses of the same, are also disclosed.